A resin nodule in the Cretaceous Garschella Formation from Langer Köchel (Bavaria, S Germany): possible origin and palaeogeographic provenance

A resin nodule was found in glauconite-rich detrital sediments of the Cretaceous Garschella Formation (Aptian to Albian) outcropping at Langer Köchel (Bavaria, S Germany). Gas chromatographic and mass spectrometric analyses of the fossil resin revealed dealkylation and the total defunctionalisation of its polycyclic constituents. Besides many unspecific components a specific one, agathalene, has survived. Agathalene also presents a strongly degraded product, but may have been derived from its natural precursor agathic acid, which is a very specific constituent (biomarker) of recent and fossil kauri resin. Although agathalene is a far less specific secondary biomarker, it indicates the botanic origin of the fossil resin nodule. Besides other potential producers of agathic acid, precursors of the present-day conifer species Agathis dammara and A. australis were distributed in a wider palaeophytogeographic range than today and might have been the botanical source of kauri resin. In view of the east–west directed Early Cretaceous surface current system of the Tethys ocean, the palaeogeographic provenance of the Werdenfels resin nodule probably was a mainland positioned further to the east or southeast of the Helvetic shelf, to where it was transported probably by driftwood of the resin-producing Agathis sp.     

The future of industrial cities and regions in central and eastern Europe

Economic transition in central and eastern Europe (CEE) has had a particularly strong impact on industrial cities and regions. Following their economic collapse, most of them are now confronted with serious problems such as high unemployment and vast ecological damage. The paper presents findings from a pan European research project that investigated the problems of these cities and regions as well as the strategies being adopted to cope with structural change. It examines the differences in approaches and addresses the question whether existing EU policy is suitable for supporting the redevelopment of old industrial cities and regions in CEE countries. The paper concludes with recommendations for future directions in policy making.     

A method to determine crystallization temperatures of hydrated crystals by intracrystalline oxygen isotope effects

The fractionation of the oxygen isotopes between water molecules from different sites in CuSO₄ · 5H₂O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed.     

Sr-gorceixite,a weathering product in rich iron ores from the Córrego do Feijão Mine,Minas Gerais,Brazil

A sulfate-bearing Sr-Ba phosphate (Sr-gorceixite) formed by supergene alteration in rich iron ores from Minas Gerais, Brazil, has been studied by means of microprobe techniques. Analytical data and the structural formula are presented.     

Multivariate statistische Auswertung von Schwermineraldaten der alpinen Gosau und Bezüge zur plattentektonischen Entwicklung der Ostalpen während der Oberkreide

Zusammenfassung Aus Schwermineraldaten verschiedener Oberkreidevorkommen der alpinen Gosau werden mit einer speziellen Variante der Q-Modus Faktorenanalyse lithologische Endglieder zur Rekonstruktion der Liefergebiete modelliert. Dabei zeigt sich, daß zeitlich zwischen der bekannten Chromspinell-Schüttung aus Ophiolithen im Norden und der Zufuhr von Granat aus dem Kristallin der Ostalpen im Süden während des Campan ein kratonisches Hinterland vorhanden ist, das sowohl reifen (Zirkon, Turmalin, Rutil) als auch sauer plutonischen Detritus (Zirkon, Apatit) in die Gosaubecken einbringt.Diese Befunde bestätigen und präzisieren das vonFrisch (1979) vorgelegte plattentektonische Konzept: Als Folge der Subduktion des südpenninischen Piedmont Ozeans und gleichzeitiger Öffnung des nordpenninischen Valais Ozeans kollidiert im Campan die mittelpenninische Briançonnais-Mikroplatte mit dem Austroalpin der adriatischen Platte. Dem entspricht die Abnahme der Chromspinellzufuhr und die Zunahme von Detritus aus einem kratonischen Liefergebiet in den Gosau Sedimenten des Untercampan. Nach der intragosauischen Gebirgsbildungsphase hält die Zufuhr von kratonischem Material aus dem Mittelpenninikum während dessen Überschiebung im Obercampan an. Gleichzeitig beginnt die Freilegung von austroalpinen Kristallinarealen, die generell ab dem Maastricht zur Vorherrschaft eines metamorphen Schwermineralspektrums führt.

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Heavy mineral data from the Late Cretaceous clastic sediments of the Alpine Gosau formation were processed using extended Q-mode factor analysis in order to model in detail end members of lithological associations in search of provenance. The results show clearly a cratonic source area which furnished both mature (zircon, tourmaline, rutile) and acid plutomc (zircon, apatite) detritus into the Gosau basins during Campanian time. Stratigraphically, the mature-plutonic detritus ranges between the well known chromspinel supply from ophiolites in the north and the influx of garnet from metamorphic rocks of the Eastern Alps in the south.This confirms and clarifies the plate tectonic model proposed byFrisch (1979): The Middle Penninic Briançonian microplate collided with the Austroalpine unit of the Adriatic plate as result of both the subduction of the South Penninic Piedmont ocean and the contemporaneous opening of the North Penninic Valais ocean. The sedimentological response was a decrease in chromspinel and an increase in the minerals of cratonic provenance in the Gosau sediments of Early Campanian age. The cratonic detritus continued to dominate in the Late Campanian after the intragosauic orogenic movements as the Briançonian plate was beeing overthrust. At this time the erosion of Austroalpine metamorphic areas started, leading to the predominance of heavy minerals of metamorphic source from the Latest Cretaceous (Maastrichtian) onwards.

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Résumé Une forme particulière d'analyse factorielle en mode.Q a été appliquée aux minéraux lourdes provenant de divers sites du Crétacé supérieur du Gosau (Alpes orientales), en vue de rechercher l'origine des sédiments. Cette méthode montre clairement l'existence au Campanien d'une source cratonique qui alimenterait le bassin du Gosau à la fois en éléments matures (zircon, tourmaline, rutile) et en éléments plutoniques acides (zircon, apatite). Cet apport se situe stratigraphiquement entre les arrivées de spinelle chromifère provenant des ophiolites au Nord et de grenat provenant des métamorphites des Alpes occidentales au Sud.Ces résultats confiment et précisent le modèle géodynamique proposé par Frisch (1979): à la suite de la subduction de l'océan sud-pennique piémontais et de l'ouverture de l'océan nord-pennique valaisan, une collision se produisit au Campanien entre la microplaque méso-pennique brianonnaise et l-Austro-alpin de la plaque adriatique. La réponse sédimentologique à cet événement a été, dans les sédiments companiens infeérieurs du Gosau, une diminution de l'afflux de spinelles chromifères et un accroissement des minéraux de provenance cratonique. Au Campanien supérieur, après la phase tectonique intro-gosauienne, l'apport des matériaux cratoniques a continué pendant le charriage de la plaque briançonnaise. En même temps commençait l'érosion de l'aire métamorphique austroalpine amenant, à partir du Maastrichtien une prédominance de minéraux lourdes d'órigine métamorphique.

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Development and changes in the Eastern Province of Saudi Arabia

Due to a particularly favourable geologic and tectonic setting in the Eastern Province, Saudi Arabia has the world largest oil reserves and is the third largest oil-producing nation in the world. Based on oil and gas revenues, the Kingdom experienced an overwhelming development during the last few decades, changing a desert country into a modern industrialized nation. Main characteristics of spatial changes are based on processes of urbanization and industrialization, on agricultural reclamations and infra-structural developments. Since the natural environment of deserts and semi-deserts in the Eastern Province is determined by an extremely sensitive equilibrium, environmental impacts, shortages in water resources, as well as limited human resources are causing basic problems, which will influence future developments.     

Seasonal δS variations in two high elevation snow pits measured by S-S double spike thermal ionization mass spectrometry

δ³⁴S and sulfate concentrations were determined in snow pit samples using a thermal ionization mass spectrometric technique capable of 0.2‰ accuracy and requires ≈5 μg (0.16 μmol) natural S. The technique utilizes a ³³S-³⁶S double spike for instrumental mass fractionation correction, and has been applied to snow pit samples collected from the Inilchek Glacier, Kyrgyzstan and from Summit, Greenland. These δ³⁴S determinations provide the first high-resolution seasonal data for these sites, and are used to estimate seasonal sulfate sources. Deuterium (δD) and oxygen (δ¹⁸O) isotope data show that the Inilchek and Summit snow pit samples represent precipitation over ≈20 months.The δ³⁴S values for the Inilchek ranged from +2.6 ± 0.4‰ to +7.6 ± 0.4‰ on sample sizes ranging from 0.3 to 1.8 μmol S. δ³⁴S values for Greenland ranged from +3.6 ± 0.7‰ to +13.3 ± 5‰ for sample sizes ranging from 0.05 to 0.29 μmol S. The concentration ranged from 92.6 ± 0.4 to 1049 ± 4 ng/g for the Inilchek and 18 ± 9 to 93 ± 6 ng/g for the Greenland snow pit. Anthropogenic sulfate dominates throughout the sampled time interval for both sites based on mass balance considerations. Additionally, both sites exhibit a seasonal signature in both δ³⁴S and concentration. The thermal ionization mass spectrometric technique has three advantages compared to gas source isotopic methods: (1) sample size requirements of this technique are 10-fold less permitting access to the higher resolution S isotope record of low concentration snow and ice, (2) the double spike technique permits δ³⁴S and S concentration to be determined simultaneously, and (3) the double spike is an internal standard.     

Rubidium-Strontium-Altersbestimmungen an Biotit-Muskowit-Granitgneisen (Typus Augen- und Flasergneise) aus dem nördlichen Großvenedigerbereich (Hohe Tauern)

Zusammenfassung An vier Proben aus dem Augen- und Flasergneiskomplex in Großvenedigergebiet (Hohe Tauern) wurden Rb–Sr-Altersbestimmungen durchgeführt. Die Biotit-Alterswerte lagen bei zirka 20 M. J. Sie sind der alpidischen Tauernkristallisation zuzuordnen. Eine Gesamtgesteinsisochrone von drei typischen Augen- und Flasergranitgneisen ergab 246 M. J. und wird als Bildungsalter eines magmatischen Granitkörpers interpretiert. Es muß daher zur Perm-Zeit in den westlichen Hohen Tauern ein ausgedehnter Granitmagmatismus angenommen werden. Auf die Schwierigkeiten, dieses Ereignis in das derzeitige geologische-Entstehungsbild einzuordnen, wurde hingewiesen.

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Rubidium-strontium age determinations on biotite-muscovite-gneisses (Augen-and Flaser-gneisses) from the Northern Grossvenediger region (Tauern, Austrian Alps)

Summary Rb–Sr ages were determined for 4 samples from the Augen- and Flaser-gneiss complex of the Grossvenediger region, Hohe Tauern, Austria. The biotite ages of 20 m. y. may be attributed to the Tauern-crystallization of Alpidic age. A total rock isochrone of 246 m. y. based on 3 typical Augen- and Flaser-granite gneisses is interpreted as the age of a granite body. Thus extensive granite magmatism is assumed to have prevailed in the western part of the Hohe Tauern during the Permian. There are, however, difficulties in correlating this event with the present picture of the geologic evolution in this region.

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Mit 2 Abbildungen     

Polymetamorphose und Deckenbau der Strand-Halbinsel/SW-Norwegen

Zusammenfassung Die Metamorphite der Halbinsel Strand / SW-Norwegen gehören zu einem Deckensystem präkambrischer Gesteine, das während der kaledonischen Orogenese von NNW her auf den Baltischen Schild geschoben worden ist (Sigmond Kildal 1978). Eine hangende Deckeneinheit umfa\t Metagranite, Melagabbroide und Gneise. Ihr granulitfazieller Mineralbestand (Metamorphosealter 1,5 Milliarden Jahre) wurde wahrscheinlich vor 1,18 Milliarden Jahren grünschieferfaziell retrograd überprägt. Die Decke ist nur noch in kleinen Erosionsinseln vorhanden. Eine liegende Dekkeneinheit besteht aus metasedimentären Gesteinen. Sie weist Mineralbestände der höheren Amphibolitfazies auf, die ebenfalls grünschieferfaziell überprägt wurden. Die Al^VI-Gehalte der bei beiden metamorphen Prozessen gebildeten Amphibole deuten bei Anwendung eines Diagramms vonRaase (1974) an, da\ die retrograde Metamorphose hier bei höheren Drücken ablief als die ältere Metamorphose. Ein Gesamtgesteinsalter von 1,16 Milliarden Jahren scheint für diese grünschieferfazielle Metamorphose das gleiche orogene Ereignis anzuzeigen wie für die hangende Einheit. Produkt der schwachen kaledonischen Metamorphose (400 Millionen Jahre) ist Stilpnomelan, der auch im Grundgebirge des Baltischen Schildes auftritt.

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The Strand Peninsula, Stavanger district, Southwestern Norway, has become well known, when V. M.Goldschmidt (1920) published his hypothesis of regional metasomatism. All rocks of the Strand area were assumed to be situated in autochthonous position. The main point ofGoldschmidt's hypothesis was progarde metamorphism of argillaceous sediments and their transformation to albite schists and plagioclase gneisses by metasomatic solutions given off from intruded trondhjemitic magmas.However, in contrast toGoldschmidt's ideas, the granitoid sill of the Ormakam-Moldhesten area, Strand Peninsula, and its wall rocks, which played an important role inGoldschmidt's discussion, are now found to be parts of a polymetamorphous thrust unit.Granulite facies assemblages, mainly consisting of orthopyroxene +clinopyroxene+plagioclase+hastingsite±orthoclase and quartz, have been partially replaced by lowgrade assemblages. Probably, the high-grade metamorphism has an age of about 1.5 Ga (Andresen &Heier 1975) whereas the age of the greenschist facies event may be conform to an orogenic cycle at about 1.15 Ga (Sigmond Kildal 1978).A lower nappe, covering the Strand Peninsula for its most parts, was subject of a petrologic re-examination using the microscope and the microprobe analyser. Its contacts with the hanging nappe as well as those with the underlying gneissic basement are characterized by thrust planes and horizons of phyllonites and cataclasites inside of the nappe and by local brecciation in the uppermost zones of the basement.The rocks of the lower nappe have been formed a long with the upper amphibolite facies as indicated by the following mineral assemblage: andesine + hastingsite and Mg-hornblende + quartz +biotite.Obviously, an inverse order of temperature regimes is recognizable in the allochthonous units. Maximum temperature of the upper nappe reached 800C (Müller &Herbert 1984) whereas T_max of the lower nappe did not exceed 750C.Using a diagram ofRaase (1974) the Al^VI-contents of the primary hastingsitic hornblendes of the lower nappe rocks indicate pressures which range distinctly below 5 kbars, whereas the secondary pargasitic hornblendes were formed at pressures of about 5 kbars. Probably the thrusting happened before the formation of secondary hornblendes took place. The load pressure in the lower nappe (< 5 kbars) was distinctly increased when the upper nappe was thrusted upon the lower one. Consequently the Al^VI-contents of secondary hornblendes indicate increased pressure ( 5 kbars).In the gneisses of the lower nappe late fractures were filled by stilpnomelane, chlorite and quartz. Very probably this depends on thrust movements during the Caledonian orogeny.Verschure et al. (1980) found a similar stilpnomelane formation in adjacent terrains of the basement and proposed a weak Caledonian metamorphism of about 400 my.

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Résumé Les roches métamorphiques de la presqu'Île de Strand (sud-ouest de la Norvège) appartiennent à un empilement de nappes formées de roches pré-cambriennes et charriées vers le SSE sur le bouclier baltique au cours de l'orogenèse calédonienne (Sigmond Kildal 1978).Une nappe supérieure comprend des métagranites, des mélagabbroÏdes et des gneiss. Leurs paragenèses, du facies des granulites (âge du métamorphisme: 1,5 Ga) ont été rétromorphosées dans le facies des schistes verts il y a probablement 1,18 Ga. Cette nappe ne subsiste qu'en petits fragments épargnés par l'érosion.Une nappe inférieure est composée de roches métasédimentaires. Ces roches présentent des paragenèses du faciès supérieur des amphibolites, également rétromorphosées dans le facies des schistes verts. L'application du diagramme de Raase (1974) aux teneurs en Al^VI des amphiboles formées lors des deux processus métamorphiques indique que la rétromorphose s'est déroulée à une pression supérieure à celle du métamorphisme ancien. Un âge de 1,16 Ga sur roche totale semble indiquer que le mÊme processus orogénique a servi de cadre à la rétromorphose en facies des schistes verts dans les deux nappes.Du stilpnomélane, présent tant dans la nappe inférieure que dans le bouclier baltique autochtone, témoigne d'un métamorphisme calédonien (400 Ma) de faible degré.

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Strand ( ) , NNW (Sigmond KILDAL, 1978). , . - 1,5 , 118 , . . . , . Al^VI , , RAASE (1974) , , . 1,6 , , , . (400 ) , .

     

Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).