Organic matter heterogeneities in 2.72 Ga stromatolites: Alteration versus preservation by sulfur incorporation

The stromatolites of the weakly metamorphosed 2.72 Ga Tumbiana Formation present abundant organic globules that resemble in size, shape and distribution the microorganisms observed in modern stromatolites. In order to evaluate the significance of these cell-like organic materials, we characterized organic matter in-situ down to the nanoscale using a combination of Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Raman microspectroscopy, scanning transmission X-ray microscopy (STXM) and transmission electron microscopy (TEM).These analyses revealed the occurrence of two distinct types of organic matter forming μm-scale textural and chemical heterogeneities distributed in distinct mineralogical laminae of the stromatolites. Type A organic matter, which is by far the most abundant, consists of sulfur-poor organic matter that is located in mud-type laminae at grain boundaries, mostly in association with silicate minerals. In contrast, Type B organic matter is rare and preserved as inclusions in the core of calcite grains forming laminates. It occurs as micrometer-sized cell-like globules containing variable amounts of organic sulfur likely in the form of thiophenes.Different scenarios may account for these compositional heterogeneities in the kerogen. Based on textural and compositional analogies with modern stromatolites, it is argued that Type B sulfur-rich globules may represent microbial cells protected by mineral encapsulation and selectively preserved through polymerization by early diagenetic sulfurization. In modern sediments, this reaction is fuelled by bacterial sulfate reduction (BSR). This metabolism has been widely considered as a major driver in modern stromatolites calcification and could thus have played an important role in the formation of the Tumbiana Formation stromatolites. In contrast, Type A sulfur-poor organic matter corresponds to either fossil extracellular polymer substances (EPS) or recondensed kerogen. This pool was likely not sulfurized due to either local and/or timely variations in the concentrations of H₂S or adverse pyritization driven by the availability of iron. Our observations thus show the need to use spatially-resolved techniques to complement organic geochemistry analyses and provide a detailed analysis of the organic carbon pools composing Archean stromatolites.     

Modeling wetting-phase relative permeability hysteresis based on subphase evolution

A recently introduced subphase framework for modeling the nonwetting phase relative permeability is extended to the wetting phase. Within this framework, the wetting phase is divided into four subphases, which are distinguished by their connectivity; backbone, dendritic, isolated and corner-film subphases. The subphase saturations evolve according to inter-subphase volume transfer terms, which require modeling. An advantage of distinguishing the subphases is that wetting phase relative permeability relations as functions of these constituent subphases can be developed. In order to develop models for the inter-subphase volume transfer and the wetting phase relative permeability in a strongly wetted system, quasi-static flow simulations in pore networks were conducted to analyze the evolution of the wetting subphases during drainage and imbibition. The simulation results suggest that hysteresis trends apparent in experimentally obtained wetting phase relative permeability curves for Berea sandstone may be explained by accounting for corner-film flow.     

Salinization and arsenic contamination of surface water in southwest Bangladesh

To identify the causes of salinization and arsenic contamination of surface water on an embanked island (i.e., polder) in the tidal delta plain of SW Bangladesh we collected and analyzed water samples in the dry (May) and wet (October) seasons in 2012–2013. Samples were collected from rice paddies (wet season), saltwater ponds used for brine shrimp aquaculture (dry season), freshwater ponds and tidal channels (both wet and dry season), and rainwater collectors. Continuous measurements of salinity from March 2012 to February 2013 show that tidal channel water increases from ~0.15 ppt in the wet season up to ~20 ppt in the dry season. On the polder, surface water exceeds the World Health Organization drinking water guideline of 10 μg As/L in 78% of shrimp ponds and 27% of rice paddies, raising concerns that produced shrimp and rice could have unsafe levels of As. Drinking water sources also often have unsafe As levels, with 83% of tubewell and 43% of freshwater pond samples having >10 μg As/L. Water compositions and field observations are consistent with shrimp pond water being sourced from tidal channels during the dry season, rather than the locally saline groundwater from tubewells. Irrigation water for rice paddies is also obtained from the tidal channels, but during the wet season when surface waters are fresh. Salts become concentrated in irrigation water through evaporation, with average salinity increasing from 0.43 ppt in the tidal channel source to 0.91 ppt in the rice paddies. Our observations suggest that the practice of seasonally alternating rice and shrimp farming in a field has a negligible effect on rice paddy water salinity. Also, shrimp ponds do not significantly affect the salinity of adjacent surface water bodies or subjacent groundwater because impermeable shallow surface deposits of silt and clay mostly isolate surface water bodies from each other and from the shallow groundwater aquifer. Bivariate plots of conservative element concentrations show that all surface water types lie on mixing lines between dry season tidal channel water and rainwater, i.e., all are related by varying degrees of salinization. High As concentrations in dry season tidal channel water and shrimp ponds likely result from groundwater exfiltration and upstream irrigation in the dry season. Arsenic is transferred from tidal channels to rice paddies through irrigation. Including groundwater samples from the same area (Ayers et al. in Geochem Trans 17:1–22, 2016), principal components analysis and correlation analysis reveal that salinization explains most variation in surface water compositions, whereas progressive reduction of buried surface water by dissolved organic carbon is responsible for the nonconservative behavior of S, Fe, and As and changes in Eh and alkalinity of groundwater.     

Exploration and decision-making in geotechnical engineering – a case study

ABSTRACT

The paper presents methodologies for exploration planning under uncertain conditions based on virtual exploration and Bayesian updating. The process starts with site characterization using existing information to produce geologic profiles. Initial distributions of cost and time are obtained with a Bayesian network model that optimizes the construction strategy for particular geologic conditions. This is followed by the unique step to determine with a “virtual exploration” if additional exploration (e.g. borings) is warranted, and if so, where it should be best done. All this is then applied to the planned Abu Dhabi subway tunnels providing the transportation planners with necessary information for planning and design.     

Multiscale characterization of pyritized plant tissues in blueschist facies metamorphic rocks

Pyritized plant tissues with well-preserved morphology were studied in rocks from Vanoise (western Alps, France) that experienced high-pressure, low-temperature metamorphic conditions in the blueschist facies during the Alpine orogeny. Organic and inorganic phases composing these fossils were characterized down to the nanometer scale by Raman microspectroscopy, scanning transmission X-ray microscopy and transmission electron microscopy. The graphitic but disordered organic matter composing these fossils is chemically and structurally homogeneous and mostly contains aromatic functional groups. Its original chemistry remains undefined likely because it was significantly transformed by diagenetic processes and/or thermal degradation during metamorphism. Various mineral phases are closely associated with this organic matter, including sulphides such as pyrite and pyrrhotite, carbonates such as ankerite and calcite, and iron oxides. A tentative time sequence of formation of these diverse mineral phases relative to organic matter decay is proposed. The absence of traces of organic matter sulphurization, the pervasive pyritization of the vascular tissues and the presence of ankerite suggest that the depositional/diagenetic environment of these metasediments was likely rich in reactive iron. Fe-sulphides and ankerite likely precipitated early and might have promoted the preservation of the fossilized biological soft tissues by providing mechanical resistance to compaction during diagenesis and subsequent metamorphism. In contrast, iron oxides which form rims of 100-nm in thickness at the interface between organic matter and Fe-sulphides may result from metamorphic processes. This study illustrates that it may be possible in some instances to deconvolve metamorphic from diagenetic imprints and opens new avenues to better constrain processes that may allow the preservation of organic fossils during diagenesis and metamorphism.     

Impact of Saharan dust on PM10 concentration in the Mediterranean Tunisian coasts

This paper presents samples of Saharan dust outbreak affecting the Mediterranean Tunisian coasts and its impact on PM10 (Particles with an aerodynamic diameter below 10 µm) surface concentrations measured at seven monitoring stations during summer 2006. During the events, the daily PM10 levels at all stations exceeded EU and Tunisian air quality standard limits which are equal to 50 µg/m³. The maximum values ranged from 200 µg/m³ to 300 µg/m³ depending on the monitoring station. The impact is even more dramatic on PM10 hourly concentrations leading to maximum hourly peaks ranging from 400 µg/m³ to 850 µg/m³ again depending on the monitoring station (industrial or residential, traffic and commercial). Comparison between backward air masses trajectories reaching Tunisian coasts and satellite imageries vis-à-vis the PM10 hourly concentrations measured at the monitoring stations during 2006 evidenced the influence of the Saharan dust outbreaks on surface concentrations. The origin of the air masses is found to be from South-West direction under the influence of air masses from the Algerian Saharan desert.     

Simulation of eutrophication and associated occurrence of hypoxic and anoxic condition in a coastal bay in Japan

A probabilistic method of calculating the occurrence of oxygen-depleted water within a combined hydrothermal and water quality model was presented in this paper to investigate the environmental impact of eutrophication on the living resources. The method was applied to an eutrophicated shallow coastal bay in western Japan, where the occurrence of red tides at the water surface and the onset of bottom hypoxic waters are observed every summer. Both meteorology and freshwater inflow contribute to the development of stratification of the bay, thus limiting the dissolved oxygen supply to bottom waters. The resulting hydrodynamics enhances the development of oxygen-depleted bottom waters by transporting organic matter produced by algal blooms to the inner bay, where it decomposes and exerts high SOD. During August, about 60% of the inner bay is hypoxic for prolonged durations and as a result most of the benthic biota and fish die. The method used here is a very useful and informative way to evaluate the spatial and temporal damage and severity caused by hypoxia on living resources. Moreover, the model results agreed very well with the observed hydrodynamics, thermal structure and water quality data of the stratified bay. The model can be used for other lakes and bays where knowledge of temperature and density stratification is important for assessing water quality.     

A nonlinear polar coordinate shallow water model for tsunami computation along North Sumatra and Penang Island

A nonlinear shallow water model in cylindrical polar coordinate system is developed, using an explicit finite difference scheme with a very fine resolution, to compute different aspects of tsunami at North Sumatra and the adjacent island Simeulue in Indonesia, and the Penang Island in Peninsular Malaysia. The pole of the frame is placed on the mainland of Penang (100.5°E) and the model area extends up to the west of Sumatra (87.5°E). The model is applied to simulate the propagation of tsunami wave towards North Sumatra, Simeulue and Penang Islands associated with Indonesian tsunami of 26 December 2004. The model is also applied to compute water levels along the coastal belts of those islands. Computed and observed water level data are found to be in good agreement and North Sumatra is found to be vulnerable for very high surges. The computed and observed arrival times of high surges are also in reasonable agreement everywhere. Further studies are carried out to investigate the effect of convective terms and it is found that their effects are insignificant in tsunami propagation and weakly significant for wave amplitude very near to the coast.     

Water fluxes and their control on the terrestrial carbon balance: Results from a stable isotope study on the Clyde Watershed (Scotland)

The gradients between precipitation and runoff quantities as well as their water isotopes were used to establish a water balance in the Clyde River Basin (Scotland). This study serves as an example for a European extreme with poorly vegetated land cover and high annual rainfall and presents novel water stable isotope techniques to separate evaporation, interception and transpiration with annual averages of 0.029 km³ a⁻¹, 0.220 km³ a⁻¹ and 0.489 km³ a⁻¹, respectively. Transpiration was further used to determine CO₂ uptake of the entire basin and yielded an annual net primary production (NPP) of 352 × 10⁹ g C (Giga gram) or 185.2 g C m⁻². Compared to other temperate areas in the world, the Clyde Basin has only half the expected NPP. This lower value likely results from the type of vegetation cover, which consists mostly of grasslands. Subtracting the annual heterotrophic soil respiration flux (R_h) of 392 Gg (206.1 g C m⁻² a⁻¹) from the NPP yielded an annual Net Ecosystem Productivity (NEP) of −40 Gg C, thus showing the Clyde Watershed as a source of CO₂ to the atmosphere. Despite the unusual character of the Clyde Watershed, the study shows that areas with predominant grass and scrub vegetation still have transpirational water losses that by far exceed those of pure evaporation and interception. This infers that vegetation can influence the continental water balances on time scales of years to decades.     

Correlation of JMA instrumental seismic intensity with strong motion parameters

The Japan Meteorological Agency (JMA) seismic intensity (I_JMA) has been used as a measure of strong shaking for many years in Japan, and it necessitates to know the correlation between the JMA seismic intensity and other strong motion indices, e.g. Peak Ground Acceleration (PGA), Peak Ground Velocity (PGV), and Spectrum Intensity (SI). In this study, two strong motion data sets were selected; in which, the first set consists of 879 three‐components non‐liquefied records selected from 13 major earthquake events that occurred in Japan, the United States, and Taiwan, and the second set consists of 17 liquefied records selected from 7 major earthquake events that occurred in Japan and the United States. The JMA seismic intensity and other ground motion indices were calculated using the selected data sets. The relationships between the JMA seismic intensity and PGA, PGV, and SI were then derived performing a two‐stage linear regression analysis. Results from the analysis show that the JMA instrumental seismic intensity shows higher correlation with SI than PGA or PGV, and it shows the highest correlation with the parameters such as the combination of PGA and SI or the product of PGA and SI. The obtained relationships are also compared with the ones obtained by other studies, which may be useful for the disaster management agencies in Japan and deployment of new SI‐sensors that monitor both PGA and SI. Copyright © 2002 John Wiley & Sons, Ltd.