Dual sensor streamer technology used in Sleipner CO2 injection monitoring

CO₂ has been injected into the saline aquifer Utsira Fm at the Sleipner field since 1996. In order to monitor the movement of the CO₂ in the sub‐surface, the seventh seismic monitor survey was acquired in 2010, with dual sensor streamers which enabled optimal towing depths compared to previous surveys. We here report both on the time‐lapse observations and on the improved resolution compared to the conventional streamer surveys. This study shows that the CO₂ is still contained in the subsurface, with no indications of leakage. The time‐lapse repeatability of the dual sensor streamer data versus conventional data is sufficient for interpreting the time‐lapse effects of the CO₂ at Sleipner, and the higher resolution of the 2010 survey has enabled a refinement of the interpretation of nine CO₂ saturated layers with improved thickness estimates of the layers. In particular we have estimated the thickness of the uppermost CO₂ layer based on an analysis of amplitude strength together with time‐separation of top and base of this layer and found the maximum thickness to be 11 m. This refined interpretation gives a good base line for future time‐lapse surveys at the Sleipner CO₂ injection site.     

Biomarker responses as indication of contaminant effects in blue mussel (Mytilus edulis) and female eelpout (Zoarces viviparus) from the southwestern Baltic Sea

During a field study performed in spring and autumn 2001 and 2002, blue mussels (Mytilus edulis) and female eelpout (Zoarces viviparus) were collected at three locations in the Wismar Bay (Baltic Sea), and several biomarkers of contaminant effects were analysed. Besides seasonal and inter-annual variations, biomarker signals were most pronounced at the location closest to Wismar Harbour (Wendorf) in both species. Lysosomal membrane stability (LMS) was lowest and acetylcholinesterase activity (AChE) was significantly reduced. Frequency of micronuclei (MN) was significantly higher (in blue mussels), indicating mutagenic effects. In eelpout elevated levels of DNA adducts, EROD induction and PAH-metabolites were measured. Metallothionein (MT), biomarker for trace metal exposure, showed a gradient only in spring. Organochlorine contaminant analyses (PCBs, DDTs) corresponded to the observed biomarker levels. The results obtained clearly demonstrate pollution effects in the southwestern Baltic Sea. Moreover, they show that a multibiomarker approach is also applicable in a brackish water environment.     

Geochemistry and mineralogy of platinum-group elements at Hartley Platinum Mine,Zimbabwe

The behaviour of platinum-group elements (PGE) in the exogenic cycle was examined in profiles of oxidized Main Sulfide Zone (MSZ) ores, in which the general metal distribution patterns of the pristine MSZ are grossly preserved. However, at similar Pt grades, significant proportions of Pd have been lost from the system. This indicates that Pd is more mobile than Pt and is dispersed in the supergene environment. Sperrylite and cooperite/braggite are stable in the oxidized MSZ. In contrast, the (Pt,Pd)-bismuthotellurides, common in pristine MSZ ores, have disintegrated, and ill-defined (Pt,Pd)-oxides or (Pt,Pd)-hydroxides have formed. The assemblage of detrital PGM present in the Makwiro River close to the Hartley Platinum Mine indicates further mineralogical changes. Sperrylite largely remains stable whereas most cooperite/braggite grains have been partly altered or completely destroyed. Grains of Pt-Fe alloy are ubiquitous in the alluvial sediments. Most likely, these grains are neo-formations that formed either from pre-existing, unstable PGM or via a solution stage under low-temperature conditions.     

Spatial inference with an interchangeable rule format

Rule interchange between information systems is expanding as new interoperable rule formats are emerging from research. However, existing spatial inference systems generally operate on locally stored data with an internal rule format. Consequently, their design offers little support or facilities for rule interchange. This article presents the requirements, components and design for a spatial inference system with rule interchange. Computational efficiency and overall functionality of the design are considered separately, with the latter demonstrated using encoded agricultural legislation and data. A spatial inference system with rule interchange is based on three primary components: rule representation, spatial functionality and data integration. Of these, the interoperable rule representation and data integration distinctly differ from existing spatial inference systems. The presented inference system combines a spatial superset of the W3C Rule Interchange Format (RIF) with full Open Geospatial Consortium simple feature access (OGC SFA) functionality and on-demand data integration utilising Resource Deception Framework (RDF). The design was found to be effective with a computational efficiency depending predominantly on the spatial operations. This design could be further adapted to implement spatial extensions for existing inference systems. Considerable benefits were also discovered when RIF was used as the native language for the inference engine, thereby removing the need for rule transformations and facilitating on-demand data integration with the GML.     

Pulp and paper mill pollution and subsequent ecosystem recovery of a large boreal lake in Finland: a paleolimnological analysis

Sedimentary diatom frustules and chironomid remains, in addition to the chemical stratigraphy of 32 elements and resin acids, were studied from short-core samples taken from two basins and a sheltered bay of Lake Päijänne in southern Finland (about 61 °10–62 °15 N, 25 °30 E). The lake was formerly oligotrophic but has been subject to effluent loading from pulp and paper mills during the past century since the opening of the first pulp mill in the 1880s. Four developmental phases were distinguished and named mainly according to the effects found in the basin close to the pollution source: (1) the pre-industrial phase (from the 1800s to ca. 1920), including the early years of industrialization, with low impacts; (2) the phase of increasing pollution (ca. 1920–1969); (3) the phase of severe pollution (1970–1981); and (4) the water protection phase (1982 onwards).Distinct differences were observed between pelagic (diatoms) and benthic (chironomid) ecosystems in their response to pollution. Effluent loading from the pulp and paper mills had a pronounced impact on chironomid assemblages, but only a slight influence on diatoms in the basin close to the pollution source. In the southern basin, approximately 60 km downstream, an increase in acidophilous species was observed in the diatom assemblages during the early years of pollution, but changes in chironomids in this basin were negligible. The water protection work of the past 30 years, which has led to an improvement in water quality and a marked recovery of the profundal biota, has also resulted in a slight increase in primary production of the lake. The decrease in brown-coloured effluent water has led to an increase in thickness of the lake's photic productive layer, while the toxicity of the water has simultaneously diminished. Rapid changes in chironomid assemblages and sedimentation observed in the sheltered bay highlight the importance of local land-use activities as causes of environmental change in this area, and especially their effects on sedimentation and benthic life.     

Structure of the crust and uppermost mantle beneath southern Finland revealed by analysis of local events registered by the SVEKALAPKO seismic array

In 1998–1999, a large-scale seismic array was deployed in Finland as a part of the EUROPROBE/SVEKALAPKO subproject, involving 14 European universities and research institutes. The objective of the project was to map the deep lithosphere structure and thickness beneath the Fennoscandian Shield by means of teleseismic events. In addition, about 580 local seismic events were registered during the data acquisition period. Among them, only eight local earthquakes were recorded, the rest being quarry blasts from mining sites in Russia, Finland, Estonia and Sweden. In this study, we present the analysis of the seismic wave field from the strongest local events registered by the majority of the stations of the SVEcofennian–KArelian–LAPland–KOla Transect (SVEKALAPKO) array with the aim of mapping the structure of the upper mantle beneath the array. For this purpose, we selected the events corresponding to a single source type and compared these recordings with those from wide-angle reflection and refraction experiments in the area to identify the regional phases. The record sections of selected events demonstrate strong reflections (PmP) from the Moho boundary. The refracted Pn phases can be seen as first arrivals at distances of about 200–400 km from the source. At offsets of about 400–800 km, phases reflected from inhomogeneities in the uppermost mantle (P1) and double reflections from the Moho boundary (PmPPmP) were recorded.Results from 2D forward ray trace modeling of reflected and refracted P-waves along four profile swathes from SVEKALAPKO stations demonstrate that the mantle reflections originate from two different groups of boundaries beneath the array: one group of phases arrive from subhorizontal and gently dipping reflectors below the Moho boundary at a depth of 70–90 km, while the other group are phases originating from a depth of 100 to 130 km. Based on the irregular character of the first group of reflections, their different spatial orientation and correlation with the Moho offsets, we interpret the boundaries of this group as relicts of ancient subduction and collision processes. The second group of reflections can be explained by a transition from mechanically strong to mechanically weak lithosphere.     

Early and Middle Valdaian glaciations, ice-dammed lakes and periglacial interstadials in northwest Russia: new evidence from the Pyoza River area

The Pyoza River area in the Arkhangelsk district exposes sedimentary sequences suitable for study of the interaction between consecutive Valdaian ice sheets in Northern Russia. Lithostratigraphic investigations combined with luminescence dating have revealed new evidence on the Late Pleistocene history of the area. Overlying glacigenic deposits of the Moscowian (Saalian) glaciation marine deposits previously confined to three separate transgression phases have all been connected to the Mikulinian (Eemian) interglacial. Early Valdaian (E. Weichselian) proglacial, lacustrine and fluvial deposits indicate glaciation to the east or north and consequently glacier damming and meltwater run-off in the Pyoza area around 90–110 ka BP. Interstadial conditions with forest-steppe tundra vegetation and lacustrine and fluvial deposition prevailed at the end of the Early Valdaian around 75–95 ka BP. A terrestrial-based glaciation from easterly uplands reached the Pyoza area at the Early to Middle Valdaian transition around 65–75 ka BP and deposited glaciofluvial strata and subglacial till (Yolkino Till). During deglaciation, laterally extensive glaciolacustrine sediments were deposited in ice-dammed lakes in the early Middle Valdaian around 55–75 ka BP. The Barents–Kara Sea ice sheet deposited the Viryuga Till on the lower Pyoza from northerly directions. The ice sheet formed the Pyoza marginal moraines, which can be correlated with the Markhida moraines further east, and proglacial lacustrine deposition persisted in the area during the first part of the Middle Valdaian. Glacio-isostatic uplift caused erosion followed by pedogenesis and the formation of a deflation horizon in the Middle Valdaian. Widely dispersed periglacial river plains were formed during the Late Valdaian around 10–20 ka BP. Thus, the evidence of a terrestrial-based ice sheet from easterly uplands in the Pyoza area suggests that local piedmont glaciers situated in highlands such as the Timan Ridge or the Urals could have developed into larger, regionally confined ice sheets. Two phases of ice damming and development of proglacial lakes occurred during the Early and Middle Valdaian. The region did not experience glaciation during the Late Valdaian.     

The tilt effect for Saturn's rings

Multiple-scattering computations are carried out to explain the variation of the observed brightness of the A and B rings of Saturn with declination of the Earth and Sun. These computations are performed by a doubling scheme for a homogeneous plane-parallel scattering medium. We test a range of choices for the phase function, albedo for single scattering, and optical depth of both the rings. Isotropic scattering and several other simple phase functions are ruled out, and we find that the phase function must be moderately peaked in both the forward and backward directions. The tilt effect can be explained by multiple scattering in a homogeneous layer, but, for ring B, this requires a single-scattering albedo in excess of 0.8. The brightest part of ring B must have an optical depth greater than 0.9. We find that the tilt effect for ring A can be reproduced by particles having the same properties as those in ring B with the optical depth for the A ring in the range 0.4 to 0.6.