Effects of Bioirrigation and Salinity on Arsenic Distributions in Ferruginous Concretions from Salt Marsh Sediment Cores (Southern Brazil)

Arsenic (As), iron (Fe), and manganese (Mn) contents were measured in sediment nodules and associated pore waters obtained from sediment cores collected from a salt marsh on Pólvora Island (southern Brazil). Sediment cores were obtained when brackish water dominated the estuary, at two different environments: an unvegetated mudflat colonized by crabs (Neohelice granulata), and a low intertidal stand vegetated by Spartina alterniflora. We determined the percentage of nodules in each depth interval of the cores, along with redox potential, and As, Fe, and Mn contents of the nodules. The mineralogy of the nodules was investigated, and results showed they are mainly composed by quartz, phyllosilicates, and amorphous Fe–Mn oxides/oxyhydroxides. Pore water results showed that bioturbation by local crabs supports oxygen penetration to depths of ca. 25 cm below the salt marsh surface, with lower Fe contents in pore water associated with the brackish period. However, S. alterniflora growth appears to have a greater impact on sediment geochemistry of Fe, Mn, and possibly As due to sulfate reduction and the associated decrease in pore water pH. Higher Fe concentrations were observed in the pore waters during the period of brackish water dominance, which also corresponded to the S. alterniflora growth season. The study demonstrates that differences in geochemical conditions (e.g., Fe content) that can develop in salt marsh sediments owing to different types of bioirrigation processes (i.e., bioirrigation driven by crabs versus that related to the growth of S. alterniflora) play important roles in the biogeochemical cycling of As.

     

The Santa Filomena meteorite shower: Trajectory,classification, and opaque phases as indicators of metamorphic conditions

On August 19, 2020, at 13:18—UTC, a meteor event ended as a meteorite shower in Santa Filomena, a city in the Pernambuco State, northeast Brazil. The heliocentric orbital parameters resulting from images by cameras of the weather broadcasting system were semimajor axis a = 2.1 ± 0.1 au, eccentricity e = 0.55 ± 0.03, and inclination i = 0.15^o ± 0.05. The data identified the body as an Apollo object, an Earth-crossing object with a pericenter interior to the Earth's orbit. The chemical, mineralogical, and petrological evaluations, as well as the physical analysis, followed several traditional techniques. The meteorite was identified as a H5-6 S4 W0 ordinary chondrite genomict breccia. The large amount of metal in the meteorite made a metallographic evaluation based on the opaque phases possible. The monocrystalline kamacite crystals suggest a higher petrological type and the distorted Neumann lines imply at least two different shock events. The absence of the plessite phase shows that the meteorite did not reach the highest shock levels S5 and S6. The well-defined polycrystalline taenite is indicative of petrologic types 4 and 5 due to the conserved internal tetrataenite rim at the boundaries. The presence of polycrystalline taenites and the characteristics of the Agrell Effect suggest that the Santa Filomena meteorite did not reheat above 700°C. The absence of martensite confirms reheating temperatures <800°C and a slow cooling rate. The Ni contents and sizes of the zoned taenite particles indicate a slow cooling rate ranging from 1 to 10 K Myr⁻¹.     

Measuring bluff erosion part 2: pairing aerial photographs and terrestrial laser scanning to create a watershed scale sediment budget

Effectively managing and reducing high suspended sediment loads in rivers requires an understanding of the magnitude of major sediment sources as well as erosion and transport processes that deliver excess fine sediments to the channel network. The focus of this research is to determine the magnitude of erosion from tall bluffs, a primary sediment source in the 2880 km² Le Sueur watershed, Minnesota, USA. We coupled analyses of seven decades of aerial photographs with four years of repeat terrestrial laser scanning (TLS) to determine erosion rates on bluffs. Together, these datasets provide decadal‐scale retreat rates throughout the entire watershed and high‐resolution geomorphic change detection on a subset of bluffs to both constrain erosion rates and document how environmental conditions affect bluff retreat. Erosion rates from aerial photographs and TLS were extrapolated from 243 and 15 measured bluffs, respectively, to all 480 bluffs in the Le Sueur watershed using multiple techniques to obtain estimates of sediment loading from these features at the watershed‐scale. Despite different spatial and temporal measurement scales, the aerial photograph and TLS estimates yielded similar results for bluff retreat rate and total mass of sediment derived from bluffs, with bluffs in the Le Sueur watershed yielding 135 000 ± 39 000 Mg/yr of fine sediment. Comparing this value to the average annual total suspended solids (TSS) load determined from gauging from 2000 to 2010, we determined that bluffs comprise 57 ± 16% of the total TSS load, making bluffs the single most abundant fine sediment source in the basin. Copyright © 2012 John Wiley & Sons, Ltd.     

Kos Plateau Tuff (KPT) on Kalymnos island, Aegean volcanic arc: A geochemical approach

Thirteen pumice samples from the D and E ignimbrite units of Kalymnos Tuff have been analyzed for their biotite and feldspar phenocryst mineral chemistry and for bulk major and 20 trace, including 14 Rare Earth elements, to define and compare their petrochemistry with the Kos Plateau Tuff (KPT). For the same purpose major element analyses were obtained from Kalymnos Tuff and KPT glasses. Both KPT and Kalymnos pumice lapilli are rhyolites characterized by a well-developed ‘silky’ texture and roundish quartz. Phenocrysts of biotite and feldspars (sanidine, oligoclase) from both tuffs display compositional overlap. Crystals are charac-terized by undulatory extinction (quartz), fractures (sanidine, oligoclase) and bent cleavages (biotite) due to the explosive origin of their host. Both tuffs show well-defined petrogenetic trends and extensive compositional overlaps on major and trace element variation diagrams suggesting that they are consanguineous. However, D ignimbrite samples are more evolved than those obtained from E ignimbrite as indicated from major elements, alkali earths (Ba, Rb, Sr), immobile (Zr, Y), compatible (V) and hygromagmatophile trace element (Th) distributions. This evidence indicates a stratified magma chamber under a ～16 Km caldera superstructure which is mostly submarine.     

NEW METHOD FOR IDENTIFICATION OF ANCIENT STARCH WITH THERMOSTABLE ALPHA-AMYLASE

目前古代淀粉粒鉴别的两种方法,即显微镜观察法和碘着色测试法,均不能确保鉴别的准确性.针对耐热性α-淀粉酶只对淀粉产生降解的特点,设计出古代淀粉粒鉴别的“耐热性α-淀粉酶降解法”,并运用到考古样品中淀粉粒的分析和鉴定之中.本文详细介绍了耐热性α-淀粉酶降解法的原理和流程,并通过古代淀粉粒的鉴别实验,确定了该方法在确切鉴别考古样品中淀粉粒的实用性和有效性;同时现代大麦和莲藕淀粉粒的降解实验结果表明不同植物来源以及同种植物内部不同粒径的淀粉粒其降解速率存在明显差异,而古代淀粉粒在耐热性α-淀粉酶作用下出现的降解速率差异的现象,或可揭示古代淀粉粒的植物来源,甚至长期埋藏对其产生的影响.     

Solute geochemical mass-balances and mineral weathering rates in small watersheds II: Biomass nutrient uptake,more equations in more unknowns,and land use/land cover effects

Paired watersheds are used to develop a deciduous nutrient uptake stoichiometry. The watersheds are those of the House Rock Run and the Brubaker Run located in the Pennsylvania Appalachian Piedmont, USA. These two watersheds are nearly identical with respect to bedrock, regolith, climate, geomorphology, morphometry, baseflow hydrology, and type and successional stage of forest vegetation. They only differ by the percentage of deciduous forest cover, with House Rock Run having 59% and Brubaker Run having 76%. From differences in their stream chemistries the biomass nutrient uptake stoichiometry of K_1.0Mg_1.0Ca_1.4 was determined. This stoichiometry applies to an aggrading deciduous biomass and differs from those previously used which were derived from net primary production (NPP) data. The difference may reflect that macronutrients in plant tissue may also originate from atmospheric inputs and/or decomposing biomass. Although this stoichiometry may not be applied to all deciduous forest-covered watersheds, it is likely an improvement over a stoichiometry determined from NPP data.     

Employability and flexible retirement: Variations in academia in an age of austerity

With both declining and ageing populations, countries are addressing the threats to their competitiveness by attracting more highly educated workers and by investing in human capital, especially through policies to increase the rates of participation by young people in tertiary education. As the population is still ageing, there are concerns over the affordability of state support for the elderly, their roles in society and the economy. Active and flexible lifestyles extend healthy life expectancy, so extending the length of the working life is increasingly seen as a way to ease the transition to an economy where an ageing population is affordable.Senior academic staff, exemplars of such post-industrial flexibility, have long been accommodated beyond the statutory retirement age. Their benign conditions of work; high private and social returns to experience and knowledge; and their high levels of those skills, labour power and other capacities which do not degenerate with age, combine to prolong the length of their effective working lives. Against this, as in other sectors, redundancies, voluntary severance and other schemes to reduce staffing have encouraged early retirement. Increased demand for higher education has driven changes in the lecturing labour mix, with increasing use of a peripheral workforce of both early career and retiring staff. This has seen semi-retirement within higher education evolving to stretch the period over which withdrawal takes place.In this context, the exploratory work reported here considers the initial responses by employers and trades unions in Scottish Higher Education to the abolition of the default retirement age and the introduction of ‘The Employment Equality (Repeal of Retirement Age Provisions) Regulations 2011’.     

Flood disaster subcultures in The Netherlands: the parishes of Borgharen and Itteren

The Netherlands knows a persistent threat of flooding. To adapt to this dangerous reality, the Dutch have cultivated what disaster research literature has labeled ‘disaster subcultures’ or a set of cultural (tangible and intangible) tools to deal with the recurrent hazard. While there is abundant attention for the way the Dutch ‘coastal’ and ‘low-lying’ communities deal with the recurrent threat of (coastal) flooding, less is known about the way the Dutch ‘high-lands’ deal with the yearly threat of (fluvial) flooding. This article presents the findings of an explorative research endeavor (2011–2013) aimed at discerning if the disaster subculture concept has contemporary relevance in the Netherlands, particularly with respect to flooding, and if so, whether applying this lens would reveal more about the nature of existing disaster subcultures. Because less is known about the Dutch ‘high-lands,’ we chose to look into the existence and attributes of disaster subcultures in the parishes Borgharen and Itteren, which experience a systematic threat of flooding. Our findings suggest that the disaster subculture lens is valuable as it enables the empirical appreciation of disaster subcultures, even in a small country like the Netherlands, and it unveiled elements of these neighboring parishes’ flood reality that otherwise might have gone unnoticed and that seem central to understanding these two parishes’ levels of vulnerability and resilience. It is our contention that the concept ‘disaster subculture’ makes a greater understanding possible of the cultural context from which vulnerability and resilience to specific and recurrent threats emerge.     

Wetland Accretion Rate Model of Ecosystem Resilience (WARMER) and Its Application to Habitat Sustainability for Endangered Species in the San Francisco Estuary

Salt marsh faunas are constrained by specific habitat requirements for marsh elevation relative to sea level and tidal range. As sea level rises, changes in relative elevation of the marsh plain will have differing impacts on the availability of habitat for marsh obligate species. The Wetland Accretion Rate Model for Ecosystem Resilience (WARMER) is a 1-D model of elevation that incorporates both biological and physical processes of vertical marsh accretion. Here, we use WARMER to evaluate changes in marsh surface elevation and the impact of these elevation changes on marsh habitat for specific species of concern. Model results were compared to elevation-based habitat criteria developed for marsh vegetation, the endangered California clapper rail (Rallus longirostris obsoletus), and the endangered salt marsh harvest mouse (Reithrodontomys raviventris) to determine the response of marsh habitat for each species to predicted >1-m sea-level rise by 2100. Feedback between vertical accretion mechanisms and elevation reduced the effect of initial elevation in the modeled scenarios. Elevation decreased nonlinearly with larger changes in elevation during the latter half of the century when the rate of sea-level rise increased. Model scenarios indicated that changes in elevation will degrade habitat quality within salt marshes in the San Francisco Estuary, and degradation will accelerate in the latter half of the century as the rate of sea-level rise accelerates. A sensitivity analysis of the model results showed that inorganic sediment accumulation and the rate of sea-level rise had the greatest influence over salt marsh sustainability.