Acidic atmospheric deposition has adversely affected aquatic ecosystems globally. As emissions and deposition of sulfur (S) and nitrogen (N) have declined in recent decades across North America and Europe, ecosystem recovery is evident in many surface waters. However, persistent chronic and episodic acidification remain important concerns in vulnerable regions. We evaluated acidification in 269 headwater streams during 2010–2012 along the Appalachian Trail (AT) that transits several ecoregions and is located downwind of high levels of S and N emission sources. Discharge was estimated by matching sampled streams to those of a nearby gaged stream and assuming equivalent daily mean flow percentiles. Charge balance acid-neutralizing capacity (ANC) values were adjusted to the 15th (Q15) and 85th flow percentiles (Q85) by applying the ANC/discharge slope among sample pairs collected at each stream. A site-based approach was applied to streams sampled twice or more and a second regression-based approach to streams sampled once to estimate episodic acidification magnitudes as the ANC difference from Q15 to Q85. Streams with ANC <0 μeq/L doubled from 16% to 32% as discharge increased from Q15 to Q85 according to the site-based approach. The proportion of streams with ANC <0 μeq/L at low flow and high flow decreased from north to south. Base cation dilution explained the greatest amount of episodic acidification among streams and variation in sulfate (SO42−) concentrations was a secondary explanatory variable. Episodic SO42− patterns varied geographically with dilution dominant in northern streams underlain by soils developed in glacial sediment and increased concentrations dominant in southern streams with older, highly weathered soils. Episodic acidification increased as low-flow ANC increased, exceeding 90 μeq/L in 25% of streams. Episodic increases in ANC were the dominant pattern in streams with low-flow ANC values <30 μeq/L. Chronic and episodic acidification remain an ecological concern among AT streams. The approach developed here could be applied to estimate the magnitude and extent of chronic and episodic acidification in other regions recovering from decreasing levels of atmospheric S and N deposition. 相似文献
Modern, ambient tritium concentrations in precipitation are lower and more temporally consistent now that they have recovered from the historic thermonuclear bomb peak of the mid-1960s. With the bomb peak no longer the overriding influence on atmospheric tritium concentrations, anthropogenic point sources, such as nuclear-generating stations (NGS), have the largest influence, though the extent and temporal variability of this influence remains uncharacterized. The lack of precipitation monitoring locations means that spatial trends in tritium concentrations in precipitation are unknown. To address this data gap, tritium concentrations in shallow modern groundwater are interpolated throughout southern Ontario (Canada), at the center of the Great Lakes Basin, and the interpolation is tested as a precipitation proxy with a statistical comparison that shows good agreement between the shallow groundwater and precipitation datasets. The shallow groundwater tritium interpolation is used to delineate the extent of NGS influence as representing 66% of the study area. Recharge timings in the subcropping bedrock aquifers of the study area are interpreted qualitatively in areas outside of NGS influence to be primarily a mix of pre-bomb and modern recharge, with no indication of peak recharge levels remaining. The influence of drift thickness on the proportion of tritium-dead versus tritium-live samples is observed spatially and confirmed by comparing data distributions. The oldest waters (pre-1953) tend to occur in subcropping bedrock aquifers underlying the thickest sediment packages.
Natural Hazards - We performed a seismic vulnerability assessment that involves geotechnical and building structure analysis for Puerto Vallarta, Mexico, a city located along the pacific coast.... 相似文献
The restoration of tidal wetland and seagrass systems has the potential for significant greenhouse gas benefits, but project-level accounting procedures have not been available at an international scale. In this paper, we describe the Verified Carbon Standard Methodology for Tidal Wetland and Seagrass Restoration, which provides greenhouse gas accounting procedures for marsh, mangrove, tidal forested wetland, and seagrasses systems across a diversity of geomorphic conditions and restoration techniques. We discuss and critique the essential science and policy elements of the methodology and underlying knowledge gaps. We developed a method for estimating mineral-protected (recalcitrant) allochthonous carbon in tidal wetland systems using field-collected soils data and literature-derived default values of the recalcitrant carbon that accompanies mineral deposition. We provided default values for methane emissions from polyhaline soils but did not provide default values for freshwater, oligohaline, and mesohaline soils due to high variability of emissions in these systems. Additional topics covered are soil carbon sequestration default values, soil carbon fate following erosion, avoided losses in organic and mineral soils, nitrous oxide emissions, soil profile sampling methods, sample size, prescribed fire, additionality, and leakage. Knowledge gaps that limit the application of the methodology include the estimation of CH4 emissions from fresh and brackish tidal wetlands, lack of validation of our approach for the estimation of recalcitrant allochthonous carbon, understanding of carbon oxidation rates following drainage of mineral tidal wetland soils, estimation of the effects of prescribed fire on soil carbon stocks, and the analysis of additionality for projects outside of the USA. 相似文献
Media accounts routinely refer to California's Assembly Bill 32 (AB 32), the Global Warming Solutions Act of 2006, as “landmark” climate change legislation. On its surface, this label is an accurate reflection of the state's forward-thinking stance across many environmental issues including pesticides, toxic substances, solid waste, and air quality. For all its promise, however, AB 32 can also be considered a low point in the landscape of conflict between state environmental regulators and California's environmental justice movement. While the legislation included several provisions to address the procedural and distributive dimensions of environmental justice, the implementation of AB 32 has been marked by heated conflict. The most intense conflicts over AB 32 revolve around the primacy of market mechanisms such as “cap and trade.” This article examines the drivers and the manifestations of these dynamics of collaboration and conflict between environmental justice advocates and state regulators, and pays particular attention to the scalar and racialized quality of the neoliberal discourse. The contentiousness of climate change politics in California offers scholars and practitioners around the world a cautionary tale of how the best intentions for integrating environmental justice principles into climate change policy do not necessarily translate into implementation and how underlying racialized fractures can upend collaboration between state and social movement actors. 相似文献
The MERLIN team together with Melvin Hoare and Karen Wills , review MERLIN's revealing role in studying star formation throughout the universe – from nearby stars to the most distant galaxies. 相似文献