Effects of hydrothermal alteration on the compositions of chromian spinels

Chromite spinels in hydrothermally altered rocks from fracture-zone ultramafic rocks and from both ultramafic cumulate pods and sheeted dikes in the Josephine ophiolite, California, display a wide variety of compositions. Alteration of the spinel may not be visible in thin section. The primary composition changes accompanying hydrothermal alteration are increase in Cr/(Cr+Al) and/or Fe²⁺/(Fe²⁺+Mg). In general, altered spinel grains associated with hornblende and chlorite show an increase in Cr/(Cr+Al) from core to rim. Altered spinel grains associated with serpentine show an increase in Fe²⁺/(Fe²⁺+Mg) from core to rim but may not show an increase in Cr/(Cr+Al). The compositional zoning in some altered spinel grains appears to result both from reaction of clinopyroxene plus spinel to form hornblende, and from reaction of hornblende to form chlorite. These observations suggest that subsolidus hydrothermal metamorphic effects need to be considered when interpreting spinel compositions and the compositions should not be interpreted solely in terms of igneous processes. Further, the presence of highly altered spinels may be indicative of hydrothermal alteration in rocks where other evidence of such alteration is absent.     

Portfolio screening to support the mainstreaming of adaptation to climate change into development assistance

The need to mainstream adaptation to climate change into development planning and ongoing sectoral decision-making is increasingly recognised, and several bilateral and multilateral development agencies are starting to take an interest. Over the past years at least six development agencies have screened their project portfolios, generally with two goals in mind: (1) to ascertain the extent to which existing development projects already consider climate risks or address vulnerability to climate variability and change, and (2) to identify opportunities for incorporating climate change explicitly into future projects. As each portfolio screening was conducted independently, the broader lessons emerging from the screenings have not been systematically analysed. In this paper we assess the screening activities to date, focusing on both the results and the methods applied. Based on this assessment we identify opportunities for development agencies to expand their current focus on the links between climate and development. Most agencies already consider climate change as a real but uncertain threat to future development, but they have given less thought to how different development patterns might affect vulnerability to climate change. The screenings undertaken have shown the need to take a comprehensive approach to adaptation and its integration into development planning and sectoral decision-making, and a number of policy initiatives have been taken to promote such integration. We provide some initial guidance as to how portfolio screening can be carried out in a way that would allow agencies to assess systematically the relevance of climate change to their ongoing and planned development projects.     

Effects of UV radiation on the RNA/DNA ratio of Copepods from Antarctica and Chile

The effect of ultraviolet (UV) radiation on marine organisms has been an important focus of recent research, with depletion of the ozone layer resulting in increased UV radiation at high latitudes. Sev...     

Ocean acidification and photic‐zone anoxia at the Toarcian Oceanic Anoxic Event: Insights from the Adriatic Carbonate Platform

Severe global climate change led to the deterioration of environmental conditions in the oceans during the Toarcian Stage of the Jurassic. Carbonate platforms of the Western Tethys Ocean exposed in Alpine Tethyan mountain ranges today offer insight into this period of environmental upheaval. In addition to informing understanding of climate change in deep time, the effect of ancient carbon cycle perturbations on carbonate platforms has important implications for anthropogenic climate change; the patterns of early Toarcian environmental deterioration are similar to those occurring in modern oceans. This study focuses on the record of the early Toarcian Oceanic Anoxic Event (ca 183.1 Ma) in outcrops of the north‐west Adriatic Carbonate Platform in Slovenia. Amidst environmental deterioration, the north‐west Adriatic Platform abruptly transitioned from a healthy, shallow‐water environment with diverse metazoan ecosystems to a partially drowned setting with low diversity biota and diminished sedimentation. An organic carbon‐isotope excursion of ?2.2‰ reflects the massive injection of CO₂ into the ocean‐atmosphere system and marks the stratigraphic position of the Toarcian Oceanic Anoxic Event. A prominent dissolution horizon and suppressed carbonate deposition on the platform are interpreted to reflect transient shoaling of the carbonate compensation depth to unprecedentedly shallow levels as the dramatic influx of CO₂ overwhelmed the ocean’s buffering capacity, causing ocean acidification. Trace metal geochemistry and palaeoecology highlight water column deoxygenation, including the development of photic‐zone anoxia, preceding and during the Toarcian Oceanic Anoxic Event. Ocean acidification and reduced oxygen levels likely had a profoundly negative effect on carbonate‐producing biota and growth of the Adriatic Platform. These effects are consistent with the approximate doubling of the concentration of CO₂ in the ocean‐atmosphere system from pre‐event levels, which has previously been linked to a volcanic triggering mechanism. Mercury enrichments discovered in this study support a temporal and genetic link between volcanism, the Toarcian Oceanic Anoxic Event and the carbonate crisis.     

Multicriteria seismic hazard assessment in Puerto Vallarta metropolitan area,Mexico

Natural Hazards - Puerto Vallarta, a medium-size tourist city, located in the Pacific Coast of Mexico, in a similar way as many other coastal cities, combines human activity with the potential...     

Mercury dynamics in sulfide-rich sediments: Geochemical influence on contaminant mobilization within the Penobscot River estuary, Maine, USA

Research concerning the fate and biogeochemical cycling of mercury (Hg) within coastal ecosystems has suggested that microbially mediated diagenetic processes control Hg mobilization and that ligands with strong affinity for Hg, such as dissolved inorganic sulfide (S(-II)) and dissolved organic matter (DOM), control Hg partitioning between the dissolved and particulate phases. We have studied total Hg cycling in the sediments of the Penobscot River estuary using a combination of equilibrium porewater samplers and kinetic modeling. The Penobscot estuary has been subject to Hg contamination from multiple industries including a recently closed chlor-alkali production facility. The Hg concentration within the estuary surface sediments ranges from 1.25 to 27.5 nmol Hg g⁻¹ sediment and displays an association with sediment organic matter and a concentration maximum within 3 cm of the sediment-water interface (SWI). Porewater profiles for the Penobscot estuary are divisible into three kinetically discrete intervals with respect to Hg dynamics. Beginning at depth in the sediment and moving upward toward the SWI we have defined: (1) a zone of net Hg solubilization at depth, with a zero-order net Hg production rate , (2) a zone of net Hg consumption within the zone dominated by FeS_(s) precipitation with , and (3) a zone of net diffusive transfer within the vicinity of the SWI. Zone 1 is characterized by dissolved S(-II) concentrations ranging from 400 to 500 μM. Equilibrium modeling in this zone suggests that inorganic S(-II) plays the dominant role in both mobilization of sediment-bound Hg and complexation of dissolved Hg. In zone 2, FeS_(s) precipitation occurs concomitant with Hg consumption. Net transfer within zone 3 is consistent with the potential for ligand-mediated Hg efflux across the SWI. S(-II)-mediated Hg mobilization at depth in Penobscot estuary sediments suggests a broadening of the depth interval over which biogeochemical Hg cycling must be examined. Our results also show that, while estuary sediments act as a net sink for particulate Hg inputs, they may also function for a considerable time interval as a source of dissolved Hg.     

Equifinality and uncertainty in physically based soil erosion models: application of the GLUE methodology to WEPP–the Water Erosion Prediction Project–for sites in the UK and USA

Despite the wealth of soil erosion models available for the prediction of both runoff and soil loss at a variety of scales, little quantification is made of uncertainty and error associated with model output. This in part reflects the need to produce unequivocal or optimal results for the end user, which will often be an unrealistic goal. This paper presents a conceptually simple methodology, Generalized Likelihood Uncertainty Estimation (GLUE), for assessing the degree of uncertainty surrounding output from a physically based soil erosion model, the Water Erosion Prediction Project (WEPP). The ability not only to be explicit about model error but also to evaluate future improvements in parameter estimation, observed data or scientific understanding is demonstrated. This approach is applied to two sets of soil loss/runoff plot replicates, one in the UK and one in the USA. Although it is demonstrated that observations can be largely captured within uncertainty bounds, results indicate that these uncertainty bounds are often wide, reflecting the need to qualify results that derive from ‘optimum’ parameter sets, and to accept the concept of equifinality within soil erosion models. Attention is brought to the problem of under‐prediction of large events/over‐prediction of small events, as an area where model improvements could be made, specifically in the case of relatively dry years. Finally it is proposed that such a technique of model evaluation be employed more widely within the discipline so as to aid the interpretation and understanding of complex model output. Copyright © 2000 John Wiley & Sons, Ltd.     

Neighbourhoods and health: A review of the New Zealand literature

Over the past two decades, there has been a resurgence of interest into place‐based influences on health. Researchers have identified that various characteristics of neighbourhoods exert an influence on the health outcomes and behaviours of local residents. Understanding the processes linking places to health provides considerable potential for a range of policy interventions. We review the New Zealand‐based neighbourhoods and health research. Consideration is given to the types of neighbourhood characteristics, as well the range of health outcomes that have been studied. Finally, we suggest some priorities for further research into the mechanisms underpinning neighbourhood influences on health in New Zealand.     

Late‐glacial and Holocene palaeoceanography of the North Icelandic shelf

High‐resolution gravity cores and box cores from the North Icelandic shelf have been studied for palaeoceanographic history based on lithological and biostratigraphical foraminiferal data. Results from two outer shelf cores covering the last 13.6 k ¹⁴C yr BP are presented in this paper. The sediments accumulated in north–south trending basins on each side of the Kolbeinsey Ridge at water depths of ca. 400 m. Sedimentation rates up to 1.5 m kyr⁻¹ are observed during the Late‐glacial and Holocene. The Vedde and Saksunarvatn tephras are present in the cores as well as the Hekla 1104. A new tephra, KOL‐GS‐2, has been identified and dated to 13.4 k ¹⁴C yr BP, and another tephra, geochemically identical to the Borrobol Tephra, has been found at the same level. At present, the oceanographic Polar Front is located on the North Icelandic shelf, which experiences sharp oceanographic surface boundaries between the cold East Icelandic Current and the warmer Irminger Current. Past changes in sedimentological and biological processes in the study area are assumed to be related to fluctuations of the Polar Front. The area was deglaciated before ca. 14 kyr BP, but there is evidence of ice rafting up to the end of the GS‐1 (Greenland Stadial 1, Younger Dryas) period, increasing again towards the end of the Holocene. Foraminiferal studies show a relatively strong GS‐2 (pre‐13 kyr BP) palaeo‐Irminger Current, followed by severe cooling and then by unstable conditions during the remainder of the GI‐1 (Greenland Interstadial 1, Bølling–Allerød) and GS‐1 (Younger Dryas). Another cooling event occurred during the Preboreal before the Holocene current system was established at about 9 kyr BP. After a climatic optimum between 9 and 6 kyr BP the climate began to deteriorate and fluctuate. Copyright © 2000 John Wiley & Sons, Ltd.