Response Surface Modeling of Cu(II) Removal from Electroplating Waste by Adsorption: Application of Box–Behnken Experimental Design

The use of kaolinite‐based clay minerals as a low‐cost natural adsorbent for the removal of Cu(II) from electroplating waste leachate was studied. Batch experiments were conducted to determine the effects of varying adsorbent loading, initial pH, adsorbent dosage, and contact time. Box–Behnken design with three variables like initial pH, adsorbent dosage, and contact time at three different levels was studied to identify a significant correlation between the effects of these variables to the amount of Cu(II) adsorbed. The methodology identifies the principal experimental variables, which have the greatest effect on the adsorption process. After optimizing the input variables by using Simplex algorithm, the adsorption of Cu(II) was maximal (99.9% with a maximum (positive) standard deviation of 9.4) at pH 6.24, adsorbent dosage of 0.83 g L^?1, and contact time of 97 min, respectively. Furthermore, the experimental values are in good agreement with predicted values, the correlation coefficient and adjusted correlation coefficients were found to be 0.96 and 0.87, respectively.     

Treatability of Dye Solutions Containing Disperse Dyes by Fenton and Fenton‐Solar Light Oxidation Processes

This study attempts to explore the possibility of treating dye solutions containing Disperse Yellow 119 and Disperse Red 167 by Fenton and Fenton under solar‐light oxidation processes. Experiments were conducted to examine the effects of various operating conditions on the performance of the treatment systems. The Fenton results showed that 98.6% spectral absorption coefficient (SAC) and 90.8% chemical oxygen demand (COD) removals were proved at pH 3, 50 mg/L Fe²⁺, and 75 mg/L H₂O₂, 15 min oxidation time for Disperse Yellow 119. After 40 min solar irradiation time during Fenton process the SAC removal was 99.1%. COD reduction of about 98.3% was observed at the same time. It was also obtained as 97.8% SAC and 97.7% COD removal with pH 3, 75 mg/L Fe²⁺, 100 mg/L H₂O₂, and 25 min oxidation time for Disperse Red 167 at this optimum conditions. For Disperse Red 167 during Fenton under solar light process, after 40 min of solar irradiation time the SAC and COD reduction were obtained 99.3 and 98.4%, respectively.     

A STATISTICAL TEST OF FLORISTIC ZONES AS INFERRED FROM THE POLLEN RECORD: SOUTHERN NEW ENGLAND

This study presents the stratigraphic and floristic interpretations of data collected from a 6.49 m core taken within the Rowley River Marsh, Massachusetts. Twenty-five samples were collected at 28 centimeter intervals from the core in this Holocene coastal marsh. Based on stratigraphic control, the age of the core samples includes a time sequence extending back 4,600 years from the present. Analysis of the core stratigraphic units suggests the environment has essentially been a low energy estuarine system for the past 4,600 years. The 25 samples were also processed for pollen taxa present since 4,600 years B.P. A discriminant function analysis was used to test the floristic zonal similarity of the diagnostic taxa (Picea, Pinus, Carya, Tsuga, Quercus) from the core with those same taxa used to establish the floristic zones for the southern New England region. The results of the analysis demonstrated that 84% of the samples were correctly classified by floristic zone. Although the distribution of diagnostic taxa from this study is generally in agreement with the previously established floristic zones, the Tsuga taxa are present throughout the temporal sequence, suggesting the occurrence of a cooler climate regime for the sampling site since 4,600 years B.P.     

Physical parameters of some close binaries: ET Boo,V1123 Tau,V1191 Cyg,V1073 Cyg and V357 Peg

With the aim of providing new and up-to-date absolute parameters of some close binary systems, new BVR CCD photometry was carried out at the Ankara University Observatory (AUG) for five eclipsing binaries, ET Boo, V1123 Tau, V1191 Cyg, V1073 Cyg and V357 Peg between April, 2007 and October, 2008. In this paper, we present the orbital solutions for these systems obtained by simultaneous light and radial velocity curve analyses. Extensive orbital solution and absolute parameters for ET Boo system were given for the first time through this study. According to the analyses, ET Boo is a detached binary while the parameters of four remaining systems are consistent with the nature of contact binaries. The evolutionary status of the components of these systems are also discussed by referring to their absolute parameters found in this study.     

Ground water radon anomalies in Bodrum Peninsula

Bodrum Peninsula is located between Hellenic Trench in the west and Gökova Fault Zone in the east which is affected by hundreds of earthquakes every year. Because of its active environment is allowed to monitor tracers/precursors continuously to analyse natural processes. This study focused on the determination of ground water radon (²²²Rn) concentrations in the Bodrum Peninsula in terms of seismic activities. Radon levels of ten ground water wells were measured periodically throughout the peninsula and these wells were divided into two groups according to the number of earthquakes they are exposed. Radon variations in second group stations are fairly significant as a result of high number of earthquakes. In these stations, radon continuously increased before the seismic storm and then decreased step by step. The results indicated that radon variations in ground waters of Bodrum Peninsula can be a good indicator for seismic storms instead of one specific event.     

Seismic failure probability of concrete slab on CFR dams with welded and friction contacts by response surface method

In this study, failure probability of the concrete slab on concrete-faced rockfill (CFR) dams with welded and friction contact is investigated under earthquake effects by reliability analysis. For this purpose, Torul CFR dam is selected as an example and numerical solutions are performed by considering combination of reliability analysis–finite element method. 1992 Erzincan earthquake acceleration record is used in the finite element analysis considering deconvolved-base rock input model. In this model, the ground motion to be applied to the foundation base rock is obtained by deconvolution of the free-field surface record. In the materially nonlinear analysis, Drucker–Prager model is used for concrete slab and multi-linear kinematic hardening model is utilized for rockfill. Geometrically nonlinearity is also taken into account. Viscous boundary conditions are defined in the finite element model for both foundation soil and reservoir water. The hydrodynamic pressure of the reservoir water is considered using 2D fluid finite elements based on the Lagrangian approach. Both welded contact and friction contact based on the Coulomb’s friction law are defined in the structural connections. Improved Rackwitz–Fiessler method is used with response surface method in the reliability analysis. The tensile and compression strengths of the concrete slab are utilized in the implicit limit state functions considering various thicknesses. The probability of failure of the most critical points in the concrete slab is obtained. According to this study, the probabilities of failure obtained from the CFR dam including friction contact are lower. When the welded contact is considered in joints, the probability of failure of the concrete slab is 1 due to tensile stress limit state and compression stress limit state only if concrete slab is linear. The most critical probability of failure of the concrete slab appears in the case that the concrete slab is linear and rockfill is materially nonlinear. The probability of failure of the concrete slab decreases if the nonlinearity of the concrete is considered. Also, hydrodynamic pressure decreases the reliability of the concrete slab.     

Heavy metals contamination levels at the Coast of Aliağa (Turkey) ship recycling zone

Alia?a Bay is one of the most important maritime zones of Turkey where shipping activity, shipbreaking industry, steel works and petrochemical complexes exist together. Concentrations of heavy metals and organic carbon in sediment of the Alia?a Bay were investigated to evaluate an environmental risk assessment from metals contamination in 2009-2010. Comparison of the metal concentrations with average shale and Mediterranean background levels revealed that most of the samples from the Alia?a were polluted with Hg, Cd, Pb, Cr, Cu, Zn, Mn and Ni. It was found that Hg, Pb, Cu, Zn and Ni levels in Alia?a Bay exceeded the PEL values. Sediments, contaminated with Pb, Cr, Cu, Zn and Ni were considered as heavily polluted per the SQG.     

210Po and 210Pb variations in fish species from the Aegean Sea and the contribution of 210Po to the radiation dose

In recent years, there has been increasing interest in the significance of natural radionuclides, particularly (210)Po, in the marine environment. (210)Po, a naturally occurring alpha emitter, accumulates in marine organisms and reflects differences in their diets. In the literature, there is no data for (210)Po and (210)Pb activity concentrations for fish species on the Turkish coast of Aegean Sea. Therefore, in this study, multiple fish species were collected from six stations seasonally on the Turkish coast of Aegean Sea and were analyzed for their (210)Po and (210)Pb content. The (210)Po and (210)Pb concentrations in the fish samples were found to vary from undetectable levels to 499 ± 44 Bq kg(-1) dry weight (dw) and from 1.0 ± 0.3 Bq kg(-1) to 35 ± 4.0 Bq kg(-1) (dw), respectively. There were no significant differences in the activity concentrations of (210)Po and (210)Pb in fish samples between seasons (ANOVA, P>0.05). The highest dose contribution of (210)Po to humans was calculated to be 10,530 μSv year(-1).