Organochlorine residue and toxic metal (Pb, Cd and Cr) levels in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey

In this study, organochlorine and toxic metal (Pb, Cd and Cr) analyses have been done in the surface sediments. Sediment samples have been collected from 7 parts of the Marmara Sea and the coast of Istanbul during 2009. Total Pb, Cd and Cr contents vary between 32 μg g(-1) and 122 μg g(-1); 0.19 μg g(-1) and 1.16 μg g(-1); 62 μg g(-1) and 372 μg g(-1), respectively. EF values of Pb and Cr are higher than 1.5 in all the stations. EF value of Cd is considerably high at Station MY1 (Tuzla Port). Total organochlorine residue contents range between 4.33 ng g(-1) and 22.2 ng g(-1) in the surface sediments.     

Investigation of the effects of expectation values for radii on the determination of transition probabilities using WBEPM theory

Transition probabilities for some excited s-p and p-s transition arrays of neutral nitrogen have been calculated using the weakest bound electron potential model theory (WBEPMT) for the investigation of effects of expectation values of radii.We have used both numerical non-relativistic Hartree-Fock (NRHF) wave functions and numerical Coulomb approximation (NCA) wave functions to calculate expectation values of radii. The transition probability results obtained using the parameters determined with two different wave functions agree well with each other and accepted values taken from NIST for low values of transition probability. However, the NRHF wave functions present better results for p-s transitions, while NCA wave functions are better in s-p transitions for large values of transition probability.     

Airborne Gravimetry Survey for the Marine Area of the United Arab Emirates

The Military Survey Department (MSD) of the United Arab Emirates (UAE) undertook an airborne gravity survey project for the marine area of the country in 2009, especially to strengthen the marine and coastal geoid in the near-shore regions. For the airborne gravity survey, 5 km spacing coast-parallel flight lines were planned and surveyed. These lines were supplemented by cross-lines in order to assess the quality of the airborne gravity surveys. The flight lines were extended 10 km, spacing lines further offshore. A Beech King Air 350 aircraft was used for the surveys, collecting data at a typical flight speed of 170 knots and a typical flight elevation of 900–1500 m, depending on weather conditions and topography. Gravity was measured with a ZLS-modified LaCoste and Romberg gravimeter (S-99), augmented with a Honeywell strap-down inertial navigation system unit. The estimated accuracy for the airborne gravity data is better than 2.0 mGal r.m.s., as judged from the airborne track crossovers. The new airborne gravimetry data changed the UAE coastal geoid by up to 30 cm in some regions, highlighting the importance of airborne gravity coastal surveys.     

Interpretation of Magnetic Anomalies and Estimation of Depth of Magnetic Crust in Slovakia

The magnetic map of Slovakia used in the paper was compiled as part of a project titled Atlas of Geophysical maps and profiles in 2001. The residual magnetic data were analyzed to produce Curie point estimates. To remove distortion of magnetic anomalies caused by the Earth’s magnetic field, reduction to pole transformation was applied to the magnetic anomalies using the magnetization angle of the induced magnetization. Anomalies reduced to the pole tend to be better correlated with tectonic structures. We applied a 3-km upward continuation to the residually compiled magnetic anomalies in order to remove effects of topography. The depth of magnetic dipoles was calculated by an azimuthally averaged power spectrum method for the entire area. Such estimates can be indicative of temperatures in the crust, since magnetic minerals lose their spontaneous magnetization according to Curie temperature of the dominant magnetic minerals in the rocks. The computed Curie point depths in the Slovakia region vary between 15.2 km and 20.9 km. Heat flow higher than 100 mWm⁻² occurs at the central volcanics and eastern part of Slovakia, where the Curie point depths values are shallow. The correlation between Curie point depths, heat flow and crust depth was investigated for two E-W cross sections. Heat flow and Curie point depth values are correlated with each other however, these values could not be correlated with crust depth. The Curie point isotherm, which separates magnetic and non-magnetic parts of the crust, is represented in two cross sections.     

The optimization of the antibiotics extraction from wastewaters and manure using Box–Behnken experimental design

The aim of this study was to optimize the solid-phase extraction method of several antibiotics in order to determine their concentration in wastewater (influent and effluent) and manure samples. The selected antibiotics for the present study were ampicillin, ceftazidime, cefepime, imipenem, piperacillin/tazobactam, tetracycline, erythromycin, ciprofloxacin, norfloxacin, vancomycin, gentamicin, sulfamethoxazole/trimethoprim. The optimum extraction conditions were established using a three- and four-factor Box–Behnken design under response surface methodology. The extraction of the antibiotics from liquid matrices was performed on several types of cartridges (Oasis HLB, Strata-X and HyperSep Retain PEP). With Oasis HLB cartridges were obtained the best recovery degrees (74.81 and 105.39% with the exception of tazobactam 58.70% and gentamicin 51.57%). This type of cartridges was further used for all of the samples collected for this study. In the case of the manure samples were tested two different extraction techniques: ultrasounds- and microwave-assisted solvent extraction, the first one being the most efficient. All the extractions obtained during the present study were evaluated by high-performance liquid chromatography with two detectors, diode array and mass spectrometer in positive ionization mode.     

Trace element contents and C-O isotope geochemistry of the different originated magnesite deposits in Lake District (Southwestern Anatolia), Turkey

Vein-stockwork magnesite in the Madenli area, sedimentary huntite-magnesite in the A?a??t?rtar area, and lacustrine hydromagnesite in the Salda Lake area are located in the Bey?ehir-Hoyran and Lycian nappe rocks around Isparta and Burdur, Southwest Anatolia. The aim of this study is to understand trace element contents and carbon-oxygen isotope ratios in different originated magnesite, magnesite bearing huntite, and hydromagnesite deposits. Also, the element contents and isotope ratios of the magnesite occurrences are to compare with each other and similar magnesite occurrences in Turkey and world. It is found that the Madenli magnesite occurrences in the ?arkikaraa?aç ophiolites, A?a??t?rtar magnesite bearing huntite deposits in the lacustrine rocks of the Miocene-Pliocene, and the Salda hydromagnesite deposits in lacustrine basin on the Ye?ilova ophiolites. The paragenesis contains a common carbonate mineral magnesite, less calcite, serpentine, smectite, dolomite, and talc in the Madenli magnesite occurrences, mostly huntite and locally magnesite, dolomite, calcite, illite, quartz, and smectite in the A?a??t?rtar huntite-magnesite occurrences, and only hydromagnesite mineral in the Salda Lake hydromagnesite occurrences. Vein and stockwork Madenli magnesite deposits were recognized by higher total iron oxide concentrations (mean 1.10 wt%) than sedimentary A?a??t?rtar magnesite bearing huntite (mean 0.13 wt%) and lacustrine Salda hydromagnesite (mean 0.22 wt%) deposits. It is suggested that high Fe content (up to 5%) in the magnesite associated with ultramafic rocks than those from sedimentary environments (≤1% Fe). Based on average Ni, Co, Ba, Sr, As and Zr contents in the magnesite deposits, average Ni (134.63 ppm) and Co (15.19 ppm) contents in the Madenli magnesite and Salda hydromagnesite (36.85 ppm for Ni, 3.15 ppm for Co) have higher values than A?a??t?rtar huntite + magnesite (7.67 ppm for Ni and 0.89 ppm for Co). Average Ni-Co contents of these deposits can have close values depending on ophiolite host rock. Average Ba values of the Madenli (108.09 ppm) and A?a??t?rtar (115.88 ppm) areas are higher than those of Salda hydromagnesite (13.15 ppm). Sediment-hosted A?a??t?rtar magnesite-huntite deposits have the highest Sr contents (mean 505.81 ppm) as reasonably different from ultrabasic rock-related Madenli magnesite (mean 38.76 ppm) and Salda hydromagnesite (mean 36.70 ppm). The highest Sr content of sedimentary A?a??t?rtar deposits reveals that Sr is related to carbonate rocks. As and Zr contents have the highest average values (As 52.76 ppm and Zr 9.67 ppm) in the A?a??t?rtar deposits different from Madenli magnesite (As 0.54 ppm and Zr 1.67 ppm) and Salda hydromagnesite (As 0.5 ppm and Zr 2.58 ppm) deposits. High As and Zr concentrations in the A?a??t?rtar magnesite-huntite deposits may come from volcanic rocks in near country rocks. The δ ¹³C (PDB) isotope values vary between ?10.1 and ?11.4‰ in the Madenli magnesite, 7.8 to 8.8‰ for huntite, 1.7 to 8.3‰ for huntite + magnesite and 4.0‰ for limestone + magnesite in the A?a??t?rtar huntite-magnesite deposits, and 4.4 to 4.9‰ for Salda Lake hydromagnesite. The sources of the CO₂ are hydrothermal solutions, meteoric waters, groundwater dissolved carbon released from fresh water carbonates and marine limestone, soil CO₂, and plant C3 in the Madenli magnesite, and may be deep seated metamorphic reactions in limestone and shales of rich in terms of organic matter. The sources of CO₂ in A?a??t?rtar huntite and Salda hydromagnesite were meteoric water, groundwater dissolved inorganic carbon, fresh water carbonates, and marine limestone. The δ ¹⁸O (SMOW) isotope composition ranges from 26.8 to 28.1‰ in the Madenli magnesite, 30.4 to 32.4‰ for huntite and 29.8 to 35.5‰ for huntite + magnesite and 26.9‰ for limestone + magnesite in the A?a??t?rtar area, and 36.4 to 38.2‰ in the Salda Lake hydromagnesite. The Salda Lake hydromagnesite has heavier oxygen isotopic values than others. The sources of oxygen in the Madenli magnesite deposits are hydrothermal solutions, meteoric water, freshwater carbonates, and marine limestone, but the sources of oxygen of the A?a??t?rtar magnesite-huntite are meteoric water, fresh water carbonates, and marine limestone. The Salda Lake hydromagnesite has very high δ¹⁸O isotope values indicating a strong evaporitic environment. Magnesium (Mg⁺²) and silica are released by disintegration of very weathered-serpentinized ultrabasic rocks of all magnesite deposits and from partly dolomite and dolomitic limestone in the A?a??t?rtar magnesite bearing huntite deposits. In the A?a??t?rtar area, calcium (Ca⁺²) for huntite mineralization is provided by surrounding carbonate rocks. Based on isotopic data, host rocks, petrographic properties of the Madenli magnesite can be described as an ultramafic-associated hydrothermal vein mineralization corresponding to “Kraubath type” deposits, but A?a??t?rtar ve Salda Lake deposits are sedimentary mineralization (lacustrine/evaporitic) corresponding to “Bela Stena type” deposits. The estimated temperature using average δ¹⁸O isotope values is about 33.51 °C for Madenli magnesite, 48.33 °C for A?a??t?rtar huntite-magnesite, and 25 °C for Salda hydromagnesite. Based on isotope data, we can be say that the Madenli magnesite, A?a??t?rtar magnesite-huntite, and Salda hydromagnesite occur at low to moderate-low temperature water and alkaline (pH 8.5–10.5) under surface or near-surface conditions.     

Seismic microzonation and earthquake damage scenarios for urban areas

A methodology for seismic microzonation and earthquake damage scenarios may be considered as composed of two stages. In the first stage, microzonation maps with respect to estimated earthquake characteristics on the ground surface are generated for an investigated urban area. The effects of local geological and geotechnical site conditions are taken into account based on site characterization with respect to representative soil profiles extending down to the engineering bedrock. 1D site response analyses are performed to calculate earthquake characteristics on the ground surface using as many as possible, hazard compatible real acceleration time histories. In the second stage, vulnerability of buildings and pipeline systems are estimated based on site-specific ground motion parameters. A pilot study is carried out to evaluate seismic damage in a district in Istanbul, Turkey. The results demonstrate the significance of site characterization and site response analysis in calculating the earthquake characteristics on the ground surface in comparison to simplified empirical procedures.     

Silicification of pelitic schist in the Ryoke low-pressure/temperature metamorphic belt, Southwest Japan: Origin of competent layers in the middle crust

We propose that competent layers composed of silicified rocks in the Cretaceous Ryoke low-pressure/temperature (low- P/T ) metamorphic belt in the Iwakuni–Yanai area, Southwest Japan, may be an exhumed equivalent of a seismically-reflective bright-layer in the middle crust. Silicified rocks crop out as layers or long lenticular bodies several to fifteen meters in thickness, and they are restricted to the area of greenschist facies conditions within a structural thickness of about one kilometer. The silicified rock layers exhibit a sharp contact with subjacent biotite schist but a gradational contact with overlying pelitic schist. Silicified rock is mainly composed of fine-grained quartz and minor muscovite and biotite, and some colored minerals have been variably decolorized by alteration. This implies that silicification turned the color of pelitic schists to pale gray or milky white. Quartz veins cutting schistosity at high angles were preferentially developed in the silicified rocks, while schistosity-parallel quartz veins, which underwent viscous flow, were observed in the underlying biotite schists. En echelon quartz veins and fishnet-like quartz veins are characteristic of silicified rocks. The modes of occurrence of quartz veins indicate that silicified rocks were competent relative to underlying biotite schist. The combination of contact with high-competence contrast adjacent to low-permeability silicified rocks may be a good reflector of seismic waves. If the silicified rocks were distributed in the middle crust to a considerable extent, they may result in seismic bright-layer reflections.     

Liquefaction of silts: the Adapazari criteria

Ground failures in the form of liquefaction, loss of bearing capacity and soil softening have been observed during the 1999 Marmara (Turkey) earthquake. Research to understand the failure phenomena has been carried out since the earthquakes. This paper attempts to provide explanations to the liquefaction failure of silts in seismic conditions. Findings from a large amount of data collected in the city of Adapazari on the physical and mechanical properties of soils is presented. A geomorphological map of the city has shown that there are surprising horizontal and vertical variations of the facies due to the activity of rivers in the past. Cases of liquefaction appear to have concentrated in former backswamp areas where silts and sandy silts were deposited by crevasse splays. Properties of the soils in zones of liquefaction and non-liquefaction have been determined down to a reasonable depth by measuring the average size, clay content and liquidity index as well as cone penetration resistances with porewater pressures to discover that there is significant discrepancy among those profiles susceptible to liquefaction and non-liquefying deposits. A set of “Adapazari Criteria” is proposed which is intended to improve over the “Chinese Criteria” and is simple enough to be universally applicable. This classification is similar to the existing criteria but emphasizes more on the clay content in addition to measuring the liquid limit and the liquidity index as well as the average size.