Geochemistry, mineralogy and genesis of pyrophyllite deposits in the Pötürge Region (Malatya, Eastern Turkey)

In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.     

Evaluating the anthropogenic and geologic impacts on water quality of the Eğirdir Lake, Turkey

E?irdir Lake is the second largest fresh water lake with 482 km² surface area of Turkey. The lake is an indispensable water source for our country and region because of available water capacity and usage aims such as drinking-irrigation water, tourism, and fishing. However, especially contaminants located in the E?irdir Lake catchment affect the lake water quality negatively in times. Therefore, determination of the water quality of the lake has quite importance for region human health and sustainable usage of the lake. The major factors that control the quality of the E?irdir Lake water are agricultural activities in the basin, water–rock interaction, and domestic and industrial wastes. This study investigates the anthropogenic and geologic impact originated from pollution sources and water–rock interaction in the lake watershed basin to the E?irdir Lake water quality. For this purpose, geological, hydrogeological, and hydrological properties of the lake basin with point and nonpoint pollution sources were investigated. To determine the water quality of the lake, 48 water samples were collected especially from locations representing effects of pollutants in May and October 2009. The analysis results were compared with maximum permissible limit values recommended by World Health Organization and Turkish drinking water standards. The contents of all chemical and physical parameters are higher in dry periods than wet period, and water pollution was observed at discharge points of the streams into the lake. Also, pH, turbidity, potassium, chemical oxygen demand, ammonium, aluminum, iron, and lead concentrations were found to be above drinking water standards.     

Fluid inclusion and sulfur isotope thermometry of the Inkaya (Simav-Kütahya) Cu-Pb-Zn-(Ag) mineralization, NW TURKEY

The Inkaya Cu-Pb-Zn-(Ag) mineralization, located about 20 km west of the Simav (Kütahya-Turkey), is situated in the northern part of the Menderes Massif Metamorphics. The mineralization is located along an E-W trending fault in the Cambrian Simav metamorphics consisting of quartz-muscovite schist, quartz-biotite schist, muscovite schist, biotite schist and the Ar?kayas? formation composed of marbles. Mineralized veins are 30–35 cm in width. The primary mineralization is represented by abundant galena, sphalerite, chalcopyrite, pyrite, fahlore and minor amounts of cerussite, anglesite, digenite, enargite, chalcocite, covellite, bornite, limonite, hematite and goethite with gangue quartz. Fluid inclusion studies on the quartz samples collected from the mineralized veins indicate that the temperature range of the fluids is 235°C to 340°C and the salinities are 0.7 to 4.49 wt. % NaCl equivalent. The wide range of homogenization temperatures indicates that two different fluid generations were trapped in quartz. Sulfur isotope studies of the sulfide minerals showed that all of the δ ³⁴S values are between ?2.1 and 2.6 per mil. These values are a typical range for hydrothermal sulfide minerals that have sulfur derived from a magmatic source. Pyrite-galena and pyrite-chalcopyrite sulfur isotope fractionation is consistent with an approach to isotopic equilibrium, and calculated temperatures are 254.6 and 277.4°C for pyrite-galena and 274.7°C for pyrite-chalcopyrite. The microthermometric data and sulfur isotope thermometry indicate the existence of a hydrothermal fluid that circulated along the fault crossing the Simav metamorphics and Ar?kayas? formation. Fluid inclusion and sulfur isotope thermometry can be used in combination with ore petrographical and geological information to provide site-specific targets for meso-hypothermal metal concentrations.     

Biperiodic orbital period modulation of the W UMa binary system CK Bootis

A study of the orbital period variation of the W UMa system CK Bootis is made using an extended observational time base. The biperiodicity of the orbital period modulation is emphasized. Both detected periodicities (24.14 yr and 10.62 yr) cannot be explained through the light-time effect unless the companion would be a white dwarf as suggested by other authors, too. Moreover, we also argue that, nowadays at least, it seems that there is no causal relation between the orbital period variation and the recently discovered visual companion. Consequently, we infer that at least one of the two periodicities may be related to the magnetic activity cycles in the component stars of CK Boo, while the other periodicity could be related to the presence of a fourth companion in the system.     

Computerised development control and approval system for City Hall of Kuala Lumpur

This paper will discuss the computerised development control and approval system being developed for the Planning and Development Control Department. City Hall of Kuala Lumpur, with stress on the GIS architecture developed within the system. The prospects and challenges towards implementation of the system are also discussed.     

Multiple linear regression,multi-layer perceptron network and adaptive neuro-fuzzy inference system for forecasting precipitation based on large-scale climate signals

ABSTRACT

Nowadays, mathematical models are widely used to predict climate processes, but little has been done to compare the models. In this study, multiple linear regression (MLR), multi-layer perceptron (MLP) network and adaptive neuro-fuzzy inference system (ANFIS) models were compared for precipitation forecasting. The large-scale climate signals were considered as inputs to the applied models. After selecting the most effective climate indices, the effects of large-scale climate signals on the seasonal standardized precipitation index (SPI) of the Maharlu-Bakhtaran catchment, Iran, simultaneously and with a delay, was analysed using a cross-correlation function. Hence, the SPI time series was forecasted up to four time intervals using MLR, MLP and ANFIS. The results showed that most of the indices were significant with SPI of different lag times. Comparison of the SPI forecast results by MLR, MLP and ANFIS models showed better performance for the MLP network than the other two models (RMSE = 0.86, MAE = 0.74 for the first step ahead of SPI forecasting).

Editor D. Koutsoyiannis; Associate editor F. Pappenberger     

A simplified approximation for seismic analysis of silo–bulk material system

In order to estimate the distribution, as well as the magnitude, of dynamic material pressures on ground-supported silos a simplified seismic analysis procedure was utilized. The seismic analysis of silos can be complex, as the evaluation of several parameters must be taken into consideration, including the properties of bulk materials used and how the bulk materials and silo wall are joined together. It is therefore useful to develop an analytical approximation in order to better assess results. In addition to a simplified model for the seismic analysis of a silo–bulk material system being utilized, a three-dimensional finite element model was also incorporated. Using the finite element method, a more realistic representation of the structure is possible. Moreover, the finite element method also takes into consideration contact problems between the bulk material and the silo wall, which results in easier analyses. Both a squat and a slender silo were selected for this study. The results obtained in the study of selected examples were compared with those findings obtained via EN1998-4. Modified Veletsos and Younan approximations, which are commonly used for the analysis of grain silos, were also used. Results and analysis concluded that the proposed analytical model provided, overall, a good outcome, especially in regards to the analysis of dynamic material pressure. It should be noted that using the analytical method as proposed in Eurocode, the dynamic material pressure for squat silos can be underestimated, but the results for slender silos are stronger.     

Organochlorine residue and toxic metal (Pb, Cd and Cr) levels in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey

In this study, organochlorine and toxic metal (Pb, Cd and Cr) analyses have been done in the surface sediments. Sediment samples have been collected from 7 parts of the Marmara Sea and the coast of Istanbul during 2009. Total Pb, Cd and Cr contents vary between 32 μg g(-1) and 122 μg g(-1); 0.19 μg g(-1) and 1.16 μg g(-1); 62 μg g(-1) and 372 μg g(-1), respectively. EF values of Pb and Cr are higher than 1.5 in all the stations. EF value of Cd is considerably high at Station MY1 (Tuzla Port). Total organochlorine residue contents range between 4.33 ng g(-1) and 22.2 ng g(-1) in the surface sediments.