Spatial Variation of Dissolved Organic Carbon in Soils of Riparian Wetlands and Responses to Hydro-geomorphologic Changes in Sanjiang Plain,China

Spatial variation of dissolved organic carbon(DOC) in soils of riparian wetlands and responses to hydro-geomorphologic changes in the Sanjiang Plain were analyzed through in situ collecting soil samples in the Naoli River and the Bielahong River. The results showed that the average contents of DOC for soil layer of 0–100 cm were 730.6 mg/kg, 250.9 mg/kg, 423.0 mg/kg and 333.1 mg/kg respectively from riverbed to river terrace along the transverse directions of the Naoli watershed. The content of the soil DOC was the highest in the riverbed, lower in the high floodplain and much lower in the river terrace, and it was the lowest in the low floodplain. The difference in the content and vertical distribution of DOC between the riverbed and the three riparian wetlands was significant, while it was not significant among the low floodplain, the high floodplain and the river terrace. The variability of soil DOC was related to the hydrological connectivity between different landscape position of the riparian wetlands and the adjacent stream. Extremely significant correlations were observed between DOC and total organic carbon(TOC), total iron(TFe), ferrous iron(Fe(II)) whose correlation coefficients were 0.819, –0.544 and –0.709 in riparian wetlands of the Naoli River. With the increase of wetland destruction, soil p H increased and soil DOC content changed. The correlation coefficients between soil DOC and TOC, TFe, Fe(II) also changed into 0.759, –0.686 and –0.575 respectively in the Bielahong River. Under the impact of drainage ditches, the correlations between soil DOC and TFe, Fe(II) were not obvious, while the soil p H was weakly alkaline and was negatively correlated with soil DOC in the previous high floodplain. It indicates that riparian hydro-geomorphology is the main factor that could well explain this spatial variability of soil DOC, and the agricultural environmental hydraulic works like ditching also must be considered.     

时空过程网络可视化模拟与分析服务——以溃坝洪水为例

洪水溃坝等复杂灾害现象的时空过程模拟分析,是当前国际地理信息科学热点研究方向之一。随着网络的普及化,公众对GIS时空分析模型的网络实时集成和可视化分析提出了迫切的需求。本文以溃坝洪水为例开展了时空过程网络可视化模拟与分析服务研究,利用Web GL、HTML5、Ajax、Web Service、GPU并行计算等技术手段,通过探讨溃坝洪水时空模型计算优化、网络三维可视化模拟与动态交互分析等关键技术,研发了原型系统并进行应用实验。实验结果表明,本文研究成果有助于实现时空过程信息的网络发布,在线影响分析及动态可视化服务,可为分布式网络环境下溃坝洪水等时空过程信息管理和应急决策提供科学依据和技术支持。     

基于电子鼻的青蛤(Cyclina sinensis)软组织多氯联苯的快速检测方法研究

为建立一种简单快捷的水产品中多氯联苯(PCBs)检测方法,本研究应用电子鼻对青蛤(Cyclina sinensis)软组织中富集的多氯联苯进行检测,并采用HS-SPME-GC-MS(顶空固相微萃取-气质联用)对结果进行了验证。首先利用电子鼻制作PCB15浓度梯度模版,检测PCB15处理72h以及144h的青蛤软组织中残留量,采用LDA和PCA两种方法统计并同模板的浓度进行比较。结论:青蛤软组织中PCB15浓度能明显分开,并随着处理时间的延长,区分效果愈加明显,区分度愈大。PCA的分辨效果明显优于LDA。运用欧氏距离、马氏距离、判别函数法和相关性对含有PCB15的样品浓度分别进行鉴别和验证,四种方法总的鉴别率均达到90%以上,能够较准确地对样品进行验证。电子鼻检测青蛤软组织中的多氯联苯的最低检测限为0.05μg/L,GC-MS为0.5μg/L。     

福建东山岛地质灾害特征与成因初探

海岛是海上陆地国土和人类开发海洋的远涉基地及前进支点。海岛大幅度地快速增长的开发活动与工程建设使脆弱的海岛生态环境正遭受到严重威胁。东山岛是福建第二大岛,近10年随着水产养殖与育苗、风电建设、环岛公路和房地产开发等海岛利用和开发强度的加大,海岛地质灾害及潜在风险陡增。基于现场调查和遥感影像解译,分析东山岛赋存的地质灾害类型及其分布,初步探究了主要地质灾害的诱因,为更有效地保护和可持续性开发东山岛,制定合理长效规划、防灾与减灾对策提供准确依据,并为福建及周边基岩岛的地质灾害调查与防治提供实测数据参考。     

南极半岛东北海域表层沉积有机质来源及其沉积环境

采用气相色谱-质谱技术对南极半岛东北海域海底表层沉积物的总有机碳、有机质碳同位素(δ13 Corg)和生物标志化合物等进行了测试分析。研究区表层沉积物总有机碳TOC平均值高于现代深海沉积物中的平均含量。δ13 Corg的变化说明该海域有机碳来源呈海洋水生生物来源和陆源混合的特征。正构烷烃的峰型分布、主峰碳、饱和烃轻重比C-21/C+22和(C21+C22)/(C28+C29)、甾烷组合和藿烷组合证实研究区西部表层沉积物有机质来源以陆源高等植物为主,其陆源可能来自于附近的南极半岛和南舍得兰群岛;研究区东部表层沉积物有机质来源偏以海源为主,且以低等浮游生物、藻类及细菌生物等海源输入为主。碳优势指数(Carbon preference index,CPI)、奇偶优势指数(Odd-even Predominance,OEP)和甾烷C29ααα20S/(20S+20R)比值显示研究区D1-7站位和D5-9沉积物有机质演化程度较高,D5-2和D2-4站位的有机质演化程度低,其他站位介于中间状态。饱和烃中姥鲛烷、植烷及其比值(Pr/Ph)等组合显示研究区西部以氧化-弱还原的沉积环境为主,其可能是受高温低盐别林斯高晋海水流和附近火山喷发的影响所致;研究区东部以还原—强还原沉积环境为主,可能是受低温高盐的威德尔底层水(WSBW)和威德尔海深层水(WSDW)影响所致。     

南海西北部沉积物捕获器中颗石藻通量和属种组成变化记录

本文利用沉积物捕获器回收的连续时间序列沉降颗粒物样品,研究了南海西北部海南岸外陆坡外缘海域颗石藻的通量和属种组成变化及其环境意义。研究发现,东亚夏季风引起的海南岸外上升流以及冬季风导致的混合层深度增加都会刺激该区域颗石藻的生长,其中夏季上升流的影响尤为显著。从颗石粒属种组成来看,Florisphaera profunda是南海西北部中深层(1 000m)水体中主要的颗石粒优势种,此外Emiliania huxleyi,Gephyrocapsa oceanica和Gephyrocaps ericsonii等属种含量也颇高。然而在将颗石粒折算成颗石球数量后,Emiliania huxleyi则成为主要优势种。沉积物捕获器中F.profunda的相对百分含量与颗石粒总通量呈显著的负相关,表明F.profunda的相对含量与总的颗石藻生产力有着密切联系。本结果对于利用沉积物中的颗石藻记录,尤其是F.profunda相对含量变化,恢复和重建古海洋环境尤其是古海洋生产力的研究提供了直接的理论证据。     

山东半岛北部滨浅海区表层沉积物铝物源鉴别

Surface sediment samples in the near shore area of the north Shandong Peninsula are collected for grain size and element analyses. The results indicate that the surface sediments in the study area are primarily composed of the silt-sized components similar to the Huanghe River. The total concentration of aluminum varies from 5.57% to7.37%(average(6.33 ± 0.40)%), and its spatial distribution is mainly controlled by the grain size. Correlations between the ratio of aluminum to titanium concentration and aluminum concentration, titanium concentration and the mean grain size indicate that aluminum in the near shore surface sediments is affected majorly by the terrigenous source, and partially by the anthropogenic source. The ratios of aluminum to titanium concentrations are larger than the background value of loess matter at some stations due to the existence of excess aluminum associated with human activities. Thus, the sources of aluminum should be identified firstly when aluminum is used as an index of terrigenous matter even in the near shore area dominated by terrigenous deposits.     

基于验潮站组网的深度基准面确定

分析了短期和临时验潮站深度基准确定的不统一性。重点研究了以长期验潮站作为控制,将验潮站组网传递确定深度基准面的方法,具体阐述了最小二乘拟合求取潮差比与平差方法求取深度基准值的计算方法与原理。利用仿真实验与实例计算论证了该方法的合理与可靠性。得出的结论是:在海道测量作业海域,基于验潮站组网确定深度基准可以达到理想的精度,且获得含义统一的深度基准面。     

利用不同盐度诱导长牡蛎三倍体的研究

采用低盐度(4、6、8、10、12、14、16)和高盐度(40、45、50、55、60、65、70)在40%~50%受精卵出现第一极体时处理10和15min,进行长牡蛎三倍体的诱导。在低盐度诱导三倍体实验中,随着盐度降低,D型幼虫孵化率逐渐降低,处理10和15min的卵裂率差异显著(P0.05),孵化率差异不显著(P0.05)。当盐度为8时,处理受精卵10与15min,三倍体诱导率最高分别可达84.4%和91.0%,两处理组三倍体诱导率差异显著(P0.05)。在高盐度诱导三倍体实验中,随着盐度升高,D型幼虫孵化率逐渐降低,处理10和15min的卵裂率和孵化率均差异显著(P0.05)。当盐度为55时,处理受精卵10min,三倍体诱导率最高为80.3%;当盐度为60时,处理受精卵15min,三倍体诱导率最高为97.1%,两处理组三倍体诱导率差异显著(P0.05)。研究发现,在盐度为8和60条件下,40%~50%的受精卵出现第一极体时,处理15min,长牡蛎三倍体诱导率最高。     

A review on the Holocene evolution of an inner-shelf mud deposit in the southeastern Yellow Sea: the Huksan Mud Belt

The Huksan Mud Belt (HMB) has been extensively investigated with respect to its source and evolution since the 1980s. Studies on sediment budget or accumulation rates suggested two different origins, Korean and combined Korean and Chinese. However, neither of the suggested origins appears reliable because they were based on insufficient or inaccurate datasets on the basic sedimentological characteristics of the HMB. Although a major mud transport was inferred to be closely associated with either the Korean Coastal Current or the Yellow Sea Warm Current, their physical characters during the Holocene transgression have been rarely hind-casted thus far. The majority of studies on high-resolution seismic stratigraphy along with core log have suggested that the HMB stratigraphy consists of two units divided by an erosional boundary. The lower unit is further divided into two subunits by a subtle discontinuity that is laterally correlated with the erosional boundary. In line with the stratigraphy, the studies theorized that the erosion of the HMB had produced a re-deposited distal lobe, the younger lower subunit. In addition, this lobe was inferred to have prograded rapidly during the relatively short period of 6,500-5,500 yr B.P. Although the time interval of the erosion coincides with the decelerating rise in sea level, the hydrodynamic cause and effect of the erosion remain inexplicable. Therefore, the source and evolution of the HMB continue to be controversial, due largely to poor understanding of the paleo-physical oceanography of the Yellow Sea during the Holocene.