Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

The rayleigh-taylor instability of a stratified rotating fluid through a porous medium in a two-dimensional magnetic field

The effect of finite conductivity on the Rayleigh-Taylor instability of an incompressible, viscous rotating fluid through a porous medium has been studied in the presence of a two-dimensional horizontal magnetic field. It has been shown that the solution is characterized by a variational principle. By making use of the existence of the variational principle, proper solutions have been obtained for a semi-infinite fluid in which density has a one-dimensional (exponential) vertical stratification. The dispersion relation has been derived and solved numerically. It is found that finite resistivity and porosity have a destabilizing effect on the Rayleigh-Taylor instability while rotation has a stabilizing effect.     

A 20 cm2 CCD mosaic camera for a dark matter search part I : Mechanics,optics and cryogeny

A 20cm ² CCD mosaic camera has been especially built to search for dark galactic halo objects by the gravitational microlensing effect. The sensitive area is made of 16 edge-buttable CCDs developped by Thomson-CTS, with 23×23 µm ² pixels. The 35 kg camera housing and mechanical equipment is presented. The associated electronics and data acquisition system are described in a separate paper. The camera resides at the focal plane of a 40 cm, f/10, Ferson reflector. The instrument has been in operation since December 1991 at the La Silla Observatory (ESO).     

Transient response of a circular cavity in a poroelastic medium

This paper considers the transient response of a pressurized long cylindrical cavity in an infinite poroelastic medium. To obtain transient solutions, Biot's equations for poroelastodynamics are specialized for this problem. A set of exact general solutions for radial displacement, stresses, pore pressure and discharge are derived in the Laplace transform space by using analytical techniques. Solutions are presented for three different types of prescribed transient radial pressures acting on the surface of a permeable as well as an impermeable cavity surface. Time domain solutions are obtained by inverting Laplace domain solutions using a reliable numerical scheme. A detailed parametric study is presented to illustrate the influence of poroelastic material parameters and hydraulic boundary conditions on the response of the medium. Comparisons are also presented with the corresponding ideal elastic solutions to portray the poroelastic effects. It is noted that the maximum radial displacement and hoop stress at the cavity surface are substantially higher than the classical static solutions and differ considerably from the transient elastic solutions. Time histories and radial variations of displacement, hoop stress, pore pressure and fluid discharge corresponding to a cavity in two representative poroelastic materials are also presented.     

Shakedown in layered pavements under moving surface loads

Elastic–plastic deformations in pavements consisting of layers of different frictional materials are investigated. The upper bound, kinematic shakedown theorem is used to obtain estimates of the critical shakedown loads. Fully general three-dimensional deformations are considered. The influence of the loading distribution, interactions between loads, and the effect of varying the thickness, stiffness and strength of the layers are explored. Consequences of this investigation for particular existing designs of flexible pavements are investigated. In particular, it is found that the strength of the subgrade has no effect on the magnitude of the critical shakedown load.     

Radiocarbon on Titan

Abstract— We explore the likely production and fate of ¹⁴C in the thick nitrogen atmosphere of Saturn's moon Titan and investigate the constraints that measurements of ¹⁴C might place on Titan's photochemical, atmospheric transport and surface‐atmosphere interaction processes. Titan's atmosphere is thick enough that cosmic‐ray flux limits the production of ¹⁴C: absence of a strong magnetic field and the increased distance from the Sun suggest production rates of ?9 atom/cm²/s, ?4x higher than Earth. The fate and detectability of ¹⁴C depends on the chemical species into which it is incorporated: as methane it would be hopelessly diluted even in only the atmosphere. However, in the more likely case that the ¹⁴C attaches to the haze that rains out onto the surface (as tholin, HCN or acetylene and their polymers), haze in the atmosphere or recently deposited on the surface would be quite radioactive. Such radioactivity may lead to a significant enhancement in the electrical conductivity of the atmosphere which will be measured by the Huygens probe. Measurements with simple detectors on future missions could place useful constraints on the mass deposition rates of photochemical material on the surface and identify locations where surface deposits of such material are “freshest”.     

The Expansion of the Hamiltonian of the Planetary Problem into the Poisson Series in All Keplerian Elements (Theory)

The study of the evolution of planetary systems, primarily of the Solar System, is one of the basic problems of celestial mechanics. The stability of motion of giant planets on cosmogonic time scales was established by numerical and analytical methods, but the question about the evolution of orbits of terrestrial planets and arbitrary solar-type planetary systems remained open. This work initiates a series of papers allowing one to advance in solving the problem of the evolution of the solar-type planetary systems on cosmogonic time scales by using powerful analytical tools. In the first paper of this series, we choose the optimum reference system and obtain the Poisson series expansion of the Hamiltonian of the problem in all Keplerian elements. We propose to use the integral representation of the corresponding coefficients or the Poisson processor means instead of conventionally addressing any possible special functions. This approach extremely simplifies the algorithm. The next paper of this series deals with the calculation of the expansion coefficients.     

A 59-second period in the very high energy gamma-ray emission from the Geminga pulsar

An analysis of our observations of the Geminga object with the GT-48 ground-based gamma-ray telescope has shown that its very-high-energy gamma-ray flux is modulated with a 59-s period. The 59-s period and its time derivative previously inferred from satellite data have been confirmed. According to our data, the period was 61.94 s in 1997 at MSD=50573. The statistical significance of this result is (1?4.5)×10^?4.     

A viable mechanism for the production of energy in active galactic nuclei

It is suggested that a collapsing supermassive object, which acts as an ultra-high energy particle accelerator, is the precursor of an active galactic nucleus and that the gravitational energy released during the collapse of the object is locked in the quark-gluon plasma permeated by leptons into which the entire matter in the core of the object is converted as a result of the collapse. It is also pointed out that the collapse of the object to a space-time singularity is inhibited by Pauli's exclusion principle as well as by Heisenberg's uncertainty principle and that the object explodes, before it could collapse to a singularity, thereby releasing the enormous amount of energy locked in the quark-gluon plasma.