Ion Implants as Matrix‐Appropriate Calibrators for Geochemical Ion Probe Analyses

Ion microprobe elemental and isotopic determinations can be precise but difficult to quantify. Error is introduced when the reference material and the sample to be analysed have different compositions. Mitigation of such ‘matrix effects’ is possible using ion implants. If a compositionally homogeneous reference material is available which is ‘matrix‐appropriate’ (i.e., close in major element composition to the sample to be analysed, but having an unknown concentration of the element, E, to be determined) then ion implantation can be used to introduce a known amount of an E isotope, calibrating the E concentration and producing a matrix‐appropriate calibrator. Nominal implant fluences (ions cm^?2) are inaccurate by amounts up to approximately 30%. However, ion implantation gives uniform fluences over large areas; thus, it is possible to ‘co‐implant’ an additional reference material of any bulk composition having known amounts of E, independently calibrating the implant fluence. Isotope ratio measurement standards can be produced by implanting two different isotopes, but permil level precision requires postimplant calibration of the implant isotopic ratio. Examples discussed include (a) standardising Li in melilite; (b) calibrating a ²⁵Mg implant fluence using NIST SRM 617 glass and (c) using Si co‐implanted with ²⁵Mg alongside NIST SRM 617 to produce a calibrated measurement of Mg in Si.     

Use of drones to analyse sedimentary successions exposed in the foreshore

Drones have revolutionised the gathering of geoenvironmental data over the last decade. To date, the majority of drone studies of sedimentary rock successions have focussed on well-exposed vertical to subvertical cliff sections. Here, we describe a fundamental method to obtain new data and perspectives on sedimentary successions exposed in partially-obscured foreshore or other horizontal to subhorizontal outcrop surfaces using drones. We illustrate the technique using an example from foreshore exposures of Jurassic strata near Helmsdale, Scotland, UK. Our method aims to make the process of safely collecting drone footage accessible and covers practical considerations from pre-field preparation to data processing. Capturing drone imagery in a foreshore setting involves trade-offs between the time of day which constrains the lighting, the time of year which determines algal cover and tidal range, and the flight time available which indirectly governs image resolution. We show how: (1) orthomosaic images can be used to view sedimentary deposits at different scales and angles enabling identification of large-scale sedimentary features marked by small-scale changes in orientation and lateral variability; (2) production of digital elevation models permits differentially weathered features covered by water or algae to be distinguished, and (3) drones can be used for close up photography of inaccessible features.     

Three Spaces of Spatial Cognition

As we move about and interact in the world, we keep track of different spaces, among them the space of navigation, the space immediately around the body, and the space of the body. We review research showing that these spaces are conceptualized differently. Knowledge of the space of navigation is systematically distorted. For example, people mentally rotate roads and land masses to greater correspondence with global reference frames, they mentally align roads and land masses, they overestimate distances near the viewpoint relative to those far from it. These and other distortions indicate that the space of navigation is schematized to elements and spatial relations relative to reference frames and perspective. The space around the body is organized into a mental framework consisting of extensions of the major axes of the body. Times to report objects around the body suggest that the relative accessibility of the axes depends on their perceptual and functional properties and the relation of the body to the world. Finally, times to verify named or depicted body parts indicate that body schemas depend on perceptual and functional significance. Thus, these spaces (and they are not the only ones important to human interaction) differ from one another and are not conceptualized as Euclidean. Rather they are schematized into elements and spatial relations that reflect perceptual and conceptual significance.     

Surge in sulphur and halogen degassing from Ambrym volcano,Vanuatu

Volcanoes provide important contributions to atmospheric budgets of SO₂ and reactive halogens, which play significant roles in atmospheric oxidative capacity and radiation. However, the global source strengths of volcanic emissions remain poorly constrained. These uncertainties are highlighted here by the first measurements of gas emission rates from Ambrym volcano, Vanuatu. Our initial airborne ultraviolet spectroscopic measurements made in January 2005 indicate fluxes of 18–270 kg s^-1 of SO₂, and 62–110 g s^-1 of BrO, into the atmosphere, placing Ambrym amongst the largest known contemporary point sources of both these species on Earth. We also estimate high Cl and F fluxes of ~8–14 and ~27–50 kg s^-1, respectively, for this period. Further observations using both airborne and spaceborne remote sensing reveal a fluctuating SO₂ output between 2004 and 2008, with a surge in the first half of 2005, and underline the substantial contribution that a single passively degassing volcano can make to the atmospheric budget of sulfur and halogens.     

Periglacial geoarchaeology at the Dog Creek site,Northern Yukon

The Dog Creek archaeological site (NcVi‐3), located in the northern Yukon, provides evidence of complex site transformational processes related to microclimatic conditions occurring since the mid‐Holocene. Geoarchaeological research at Dog Creek sought to interpret site formation processes in order to understand the relationship between surficial artifacts, buried artifacts, and stratified sediments. It also attempted to reconstruct the periglacial processes that were active in transforming the site and their relationships to microclimatic conditions. Sedimentology and fabric analysis show that artifacts were buried by solifluction and disturbed by frost heave and cryoturbation. Radiocarbon dating and pollen analysis demonstrated that solifluction took place approximately 5200–2000 years ago when a spruce forest existed at the site. This evidence suggests an onset of cooling conditions that continues to the present. After the mid‐Holocene, the spruce treeline began to move south toward its present position. © 2001 John Wiley & Sons, Inc.     

A laboratory study of Equotip surface hardness measurements on a range of sandstones: What influences the values and what do they mean?

The Equotip rebound tester is a simple, non-destructive technique to measure the surface hardness of materials. Having a low impact energy gives the Equotip advantages over the commonly used Schmidt Hammer on weathered rock and stone. In this study we have investigated the influence of different parameters (sample size, moisture content and surface roughness) on the surface hardness values obtained from freshly cut blocks of four types of sandstone. In a series of laboratory experiments both Single Impacts (SIM) and Repeat Impacts (RIM) methods have been used with C and D probes (which have different impact energies). Our results show that whilst sample size is of great importance we find that smaller samples can be reliably evaluated than previously reported. Moisture contents are also found to exert a more important influence on both SIM and RIM results than previously thought, with up to 26% lower hardness values recorded on saturated vs dry sandstone. Conversely, we find that surface roughness (over Sz values of 100 to 800 microns) does not have a significant impact on SIM measurements collected using the D probe. Both SIM and RIM data are found to be good proxies for compressive strength and open porosity, with SIM data collected with the C probe showing the best fits. Data collected using 3D microscopy helps visualize and quantify the small impact marks created by the Equotip and confirms that these are much reduced when using the C vs D probe. The results highlight the benefits of the Equotip to studies of the nature and deterioration of sandstone, the need for careful evaluation of any confounding factors which might influence the values obtained, and illustrate the different advantages of C and D probes. © 2019 John Wiley & Sons, Ltd.     

Imprints of wave climate and mean sea level variations in the dynamics of a coastal spit over the last 250 years: Cap Ferret,SW France

In coastal areas, sea level rise (SLR) and changing wave climates are expected to be the main oceanic drivers of shoreline adjustments. These drivers have been shown to vary on a wide spectrum of spatial and temporal scales. Nonetheless, a general rule about how this variability impacts global shorelines remains to be articulated. Here, we discuss the impacts of wave climate changes and SLR on the evolution of a barrier spit–inlet system over the last 250 years. The distal end of the Cap Ferret barrier spit, SW France, has undergone large-scale oscillations that were well correlated with variations of the decadal average of the winter North Atlantic Oscillation (NAO) index. The local wave climate hindcast supports that increased alongshore wave energy fluxes associated with the positive phase of the NAO were responsible for the updrift retreat of the spit. By opposition, the spit has elongated downdrift when waves were less energetic and more shore normal, as during the negative phase of the NAO. In addition, lower rates of SLR appeared to be necessary for the spit to develop, as higher rates of SLR very likely forced the adjacent inlet to enlarge, at the expense of the spit. These results should help to predict and detect coastal adjustments driven by climate change and by climate variability. © 2019 John Wiley & Sons, Ltd.     

Variation in Saturated Hydraulic Conductivity at the Outcrop Scale,the Whanganui Basin,New Zealand

Groundwater flow and contaminant transport are strongly influenced by hydrogeological spatial variation. Understanding the textural heterogeneity of aquifer and aquitard units is critical for predicting preferential flow pathways, but is often hindered by sparse hydrogeological data, widely spaced data points, and complex stratigraphy. Here, we demonstrate the application of a relatively new air permeameter technology, providing a cost-effective, rapid alternative for characterizing hydrostratigraphic units in the field. The aim of this research is to (1) characterize the variation of saturated hydraulic conductivity across shallow-marine hydrostratigraphic units of the Whanganui Basin, New Zealand, and (2) assess the variation of saturated hydraulic conductivity within individual hydrostratigraphic units and relate these changes to facies and depositional environments. Results suggest heterogeneity within fine-grained aquitard units is controlled by bioturbation, whereby burrowing, ingestion and defecation results in grain size segregation and differential micrite cementation. Coarse-grained heterolithic aquifer facies display sharp changes in permeability across planar to cross-bedded sets, related to current and wave energy fluctuations within shallow-marine depositional settings. Bedding plane orientation creates high permeability zones that promotes down dip subsurface flow. Down dip gradation of coarse-grained nearshore facies into fine-grained shelf facies along the paleo shoreline-shelf transect is suggested to promote lateral and vertical groundwater flow within the basin fill. Air permeameter techniques have potential for application within groundwater basins around the world, providing datasets that facilitate greater understanding of groundwater systems, informing practices and policies for targeted water quality management.