The deep geothermal potential of the Berlin area

In this study, we model the geothermal potential of deep geological formations located in the Berlin region in Germany. Berlin is situated in a sedimentary geological setting (northeastern German basin), comprising low-enthalpic aquifers at horizons down to 4–5 km depth. In the Berlin region, the temperature increases almost linearly with depth by about 30 K per kilometer, thus allowing for direct heating from deep aquifer reservoirs in principle. Our model incorporates eight major sedimentary units (Jurassic, Keuper, Muschelkalk, Upper/Middle/Lower Buntsandstein, Zechstein Salt and Sedimentary Rotliegend). Owing to lack of available petro-physical rock data for the Berlin region, we have evaluated literature data for the larger northeastern German basin to develop a thermodynamic field model which regards depth-corrected equations of state within statistical intervals of confidence. Integration over the thicknesses of the respective structural units yields their “heat in place”—energy densities associated with the pore fluid and the rock matrix under local conditions in Joule per unit area at the surface. The model predicts that aquifers in the Middle Buntsandstein and in the Sedimentary Rotliegend may well exhibit energy densities about 10 GJ m^?2 for the pore fluids and 20 GJ m^?2 to 40 GJ m^?2 for the rock matrices on average. Referring these figures to the city area of Berlin (about 892 km²), a significant hydrothermal potential results, which however remained undeveloped until today for the reason of present development risks. The model accounts for these risks through statistical intervals of confidence which are in the order of ±60 to ±80 % of the trend figures. To minimize these uncertainties, scientific field explorations were required in order to assess the petro-physical aquifer properties locally.     

Vertical mixing of gravel over a long flood series

Vertical sediment exchange is a fundamental component of bedload transport in gravel‐bed channels. This paper describes the characteristic depth of exchange achieved over a long flood series. Analysis is based on 11 recoveries of magnetically tagged gravels deployed in Carnation Creek, Canada, completed between 1990 and 2008. Vertical grain exchange mixes gravels throughout the streambed relatively rapidly. Within one to eight floods the mean burial depth approaches two times the surface layer thickness, quantified by the 90th percentile of the size distribution. Finer gravels are mixed more rapidly into the bed than coarser gravels. Both active and passive grain exchanges throughout most of the bed produce the overall vertical distribution of marked grains. Gravel exchanges exhibit fairly consistent patterns once tracers are well mixed by large floods. Results highlight the role of flood sequence in determining exchange depths, support the notion of an upper limit to exchange, and underscore the importance of passive grain exchange. Copyright © 2011 John Wiley & Sons, Ltd.     

Selecting parameters for the environmental interpretation of peat molecular chemistry – A pyrolysis-GC/MS study

A number of samples from a deep peat bog in Tierra del Fuego were analyzed using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) in order to extract parameters that might be used to interpret the peat chemistry in terms of vegetation change, anaerobic and aerobic decomposition, and fire incidence. The choice of parameters was based on factor analysis of 177 pyrolysis products, quantified for 13 samples, separated into extract and residue, as well as the total samples. Factor analysis of extracts, residues and total samples yielded similar classifications in terms of vegetation and decomposition. Pyrolysis products and ratios that most clearly differentiated samples were used to interpret the depth profile. Although interpretation was not always straightforward, indications of parameters to describe vegetation shifts, aerobic and anaerobic decomposition, and fire largely coincided. These parameters will be used in a forthcoming study for a more complete interpretation of the peat profile.     

Evaluating prey capture by larval mummichogs (Fundulus heteroclitus) as a potential biomarker for contaminants

We evaluated larval prey capture as a "behavioral biomarker" of contamination by examining feeding behavior of larval mummichogs (Fundulus heteroclitus) from many different sites, including a severely contaminated "Superfund" site, moderately contaminated sites, and reference areas. Prey capture ability was related to sediment contaminant levels. The levels of contaminants at a site were highly correlated with each other, so that the impact of individual contaminants was confounded. The number of captures of brine shrimp by mummichog larvae from all sites was highly variable, but significant negative correlations of prey capture were seen with mercury, lead, zinc, cadmium, and PCBs. As observed previously with adults, polyaromatic hydrocarbons (PAHs) did not appear to impair prey capture ability. The only site in which prey capture rates of 8-day old larvae were severely affected was the most highly contaminated Superfund site, Berry's Creek, NJ. This implies that larval prey capture is not as sensitive a behavioral biomarker for contamination as adult behavior studied previously.     

A chemical investigation of the transport and fate of petroleum hydrocarbons in littoral and benthic environments: The TSESIS oil spill

The fate of saturated and aromatic hydrocarbons discharged into the coastal Baltic Sea environment from the TSESIS oil spill has been studied in the acute and postacute (one year) phases of the spill. Periodic samples of Mytilus edulis (mussels) from eight littoral zone stations and Macoma balthica from nine soft bottom stations were obtained as well as sediment trap samples and surface sediment samples. Glass capillary gas chromatography and gas chromatographic mass spectrometry were used as the analytical tools to determine saturated and aromatic hydrocarbon composition and concentrations in these samples.Sediment trap samples indicated that sizable quantities of chemically and microbially weathered oil were sedimented, and available for benthic uptake shortly after the spill. After initial uptake of sedimented oil (500 to 1000 μ/g dry weight), Macoma populations appear to have begun slow depuration through the first winter after the spill, but TSESIS oil was again introduced to the benthic stations studied during the following summer. Mytilus populations in the region were severely impacted by the oil. Initial depuration of spilled oil during the first month was rapid and nearly complete at all but the most heavily impacted stations one year after the spill. The post-spill depuration of assimilated hydrocarbons was characterised by a relative retention of alkylated dibenzothiophenes and alkylated phenanthrenes compared to their unsubstituted parent compounds and compared with the entire homologous naphthalene series.These data suggest that petroleum hydrocarbons from the TSESIS spill have become a chronic source of degraded saturated and aromatic hydrocarbons to the soft bottom benthic communities. Petroleum hydrocarbons in the benthic environment from this spill appear to reside in the difficulty sampled and mobile flucculent layer at the sediment/water interface and may affect epifaunal communities for an extended period of time.     

Why Web GIS May Not Be Enough: A Case Study with the Virtual Research Vessel

During several decades of investigation, the East Pacific Rise seafloor-spreading center at 9°-10°N has been explored by marine geologists, geophysicists, chemists, and biologists, and has emerged as one of the best studied sections of the global midocean ridge. It is an example of a region for which there is now a great wealth of observational data, results, and data-driven theoretical studies. However, these have yet to be fully utilized, either by research scientists or educators. While the situation is improving, a large amount of data, results, and related theoretical models still exist either in an inert, noninteractive form (e.g., journal publications) or as unlinked and currently incompatible computer data or algorithms. Presented here is the prototype of a computational environment and toolset, called the Virtual Research Vessel, to improve the situation by providing marine scientists and educators with simultaneous access to data, maps, and numerical models. While infrastructure is desired and needed for ready access to data and the resulting maps via web GIS in order to link disparate data sets (data to data), it is argued that data must also be linked to models for better exploration of new relations between observables, refinement of numerical simulations, and the quantitative evaluation of scientific hypotheses. For widespread data access, web GIS is therefore only a preliminary step rather than a final solution, and the ongoing implementation of the Virtual Research Vessel (scheduled for final completion in 2004-2005) is a case study for the midocean ridge community to test the effectiveness of moving beyond the data-to-data mode towards data-to-models and data-to-interpretation.     

Institutional ambiguity in implementing the European Union Marine Strategy Framework Directive

This article addresses the institutional ambiguity that exists between the European, Regional and Member State levels in the implementation of the Marine Strategy Framework Directive (MSFD). The two main reasons for the emergence of institutional ambiguity are (1) the MSFD being a framework directive and (2) Member States are required to coordinate the implementation of the MFSD through the Regional Sea Conventions. Institutional ambiguity refers to the interference zone between different institutional settings that come together in new policy practices. New rules of the game are needed to bring these institutional settings together and the room to manoeuvre for the actors who negotiate these rules is a defining feature of institutional ambiguity. This article analyses the institutional ambiguity associated with MSFD implementation on the European and regional level for four European Seas: the North Sea, the Baltic Sea, the Mediterranean Sea and the Black Sea. The results indicate different levels of institutional ambiguity in each of the four regions, with the lowest level of ambiguity in the Baltic Sea and the highest in the Mediterranean Sea. Institutional ambiguity also exists on the European level, as coordination efforts have not resulted in clear directions for the implementation of the MSFD as yet. The level of institutional ambiguity is influenced by the relative number of EU member states bordering the particular sea and whether they consider implementation of the MFSD to be urgent. Member States bordering the Mediterranean and the Black Seas lack the support of Regional Sea Conventions in addition to receiving limited direction from the European level.     

Mapping Curvilinear Structures with Local Anisotropy Kriging

Interpolating geo-data with curvilinear structures using geostatistics is often disappointing. Channels, for example, become disconnected sets of lakes when interpolated from point data. In order to improve the interpolation of geological structures (e.g., curvilinear structures), we present a new form of kriging, local anisotropy kriging (LAK). Local anisotropy kriging combines a gradient algorithm from image analysis with kriging in an iterative way. After an initial standard kriging interpolation, the gradient algorithm determines the local anisotropy for each cell in the grid using a search area around the cell. Subsequently, kriging is carried out with the spatially varying anisotropy. The anisotropy calculation and subsequent kriging steps will then succeed until the result is satisfactory in the way of reproducing the curvilinear structures. Depending on the size of the search area more or less detail in the geological structures can be reproduced with LAK. Using test examples we show that LAK interpolates data with curvilinear structures more realistically than standard kriging. In a real world case, using bathymetric data of the Oosterschelde estuary, LAK also proves to be quantitatively superior to standard kriging. Absolute interpolation errors are decreased by 23%. Local anisotropy kriging only uses information from point data, which makes the method very objective, it only presents “what the data can tell.”