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271.
Andrés Blanco María J. Salazar Carolina Vergara Cid María L. Pignata Judith H. Rodriguez 《Environmental Earth Sciences》2017,76(4):182
The Pb, Cu and Zn content, the physicochemical parameters in soils (EC, OM%, soil texture and pH) and the metal accumulation of Glycine max plants at different growth stages were evaluated. Topsoil and soybean samples were collected in the vicinity of a former battery-recycling plant, with the results showing that only the concentrations of Pb in soils corresponding to sites located near to the lead emission source were above the maximum permissible levels. However, soybean crops accumulated Pb above the permitted levels at all studied sites, revealing a potential toxicological risk for direct consumption. Thus, the accumulation of Pb in soybean was directly related to the translocation factor of the metal from roots to aerial parts of the plant. This was evidenced as a lower accumulation at early growth stages and a higher accumulation at maturity, with the distribution between organs coinciding with nutrient incorporation and remobilization in the plant. Moreover, the bioconcentration factor revealed that the bioaccumulation of lead in soybean was a consequence of the lead-recycling plant activity in the past. Taken together, results of the present study demonstrated that soybean crops can incorporate and accumulate potentially toxic metals, such as lead. 相似文献
272.
The freight and logistics sector is of significant importance as an enabler and driver of the global economy, but it is also inherently vulnerable to hazardous weather. Despite this, there is currently no quantitative assessment of how climate change may affect the sector. This paper applies multidisciplinary climate change impact assessment tools and conceptual frameworks to the road freight sector of Great Britain in order to identify potential future weather-related safety issues. Relationships between weather and freight accidents are determined using road accident data and meteorological observations, which are then used with climate change scenarios to arrive at projections of possible impacts across the regions of Great Britain. Included in the study are industry perceptions of future trends within the sector and wider economy which many affect freight’s exposure and sensitivity to weather. These are elicited through interviews and an iterative expert Delphi study. Hence, unlike many other climate change impact assessments, this innovative study takes into account the potentially significant impact of socio-economic change (including institutional and operational). The results show that summer precipitation and winter ice-related accidents are likely to decrease across most of the country, whereas winter rain-related accidents are projected to increase. However, it is postulated that some of the impacts of climate change will be modified by reflexive behavioural change on the part of the driver and either institutional adaptation or complacency on the part of the road authorities. The paper concludes by framing the study in a range of future scenarios outlining how the socio-economic environment could influence the road transport network and how it is used, modifying the impact of climate change. 相似文献
273.
铂族元素在地壳中的富集:以布什维尔德杂岩为例 总被引:1,自引:0,他引:1
地幔是地壳铂族元素富集的主要源库。铂族元素迁移主要有两个途径:(1)地幔部分熔融物质侵入地壳;(2)地幔板片就位于俯冲/碰撞带。前一途径比后一途径重要得多。地幔物质进入地壳造成铂族元素富集并成为可供开采的主矿产而非副产品,这一过程可包含许多成矿作用机制:(i)基性侵入体中Ni-Cu硫化物矿浆的发育,岩浆冷却与分离结晶作用导致富含Cu,Pt,Pd的硫化物矿浆的形成;(ii)层状侵入体一定层位形成高品位的铂族元素硫化物层,伴生或不伴生铬铁岩;(iii)富铂族元素及硫化物的岩浆沿着层状侵入体的边缘就位;(iv)直至层状侵入体结晶分异作用晚期的硫化物不混溶滞后分离;(v)不发育硫化物不混溶作用的铬铁矿结晶作用;(vi)低程度硫化物浸染带中的热液作用与铂族元素富集;(vii)乌拉尔-阿拉斯加型侵入体重结晶过程中的铂族元素与铬铁矿的次生富集作用,岩体在风化过程中形成砂矿床;(viii)黑色页岩形成过程中Pt的富集。南非布什维尔德火成杂岩蕴藏世界Pt资源的75%,Pd资源的54%,Rh资源的82%,并具有(ii)、(iii)、(iv)、(v)、(vi)成矿作用的实例。在这些作用中,作用(ii)形成的现有经济储量和资源量占90%,作用(iii)占9%。Merensky矿层(占总资源量30%)是一个铂族元素富集层位,它含1~3铬铁矿薄层,在可采宽度内硫化物平均含量为1%~3%(质量分数)。硫化物一般被认为是铂族元素的主要聚集体。该矿层由两个或两个以上含硫化物的基性热岩浆上升汇聚而成。这些岩浆的汇聚造成超镁铁质堆晶岩的厚度(主要是斜方辉石岩,某些地区包括橄榄岩)变化于50cm至数米之间。开采通常集中在厚度不到1m的地带。矿层的成因至今仍存在争议,一些观点认为铂族元素来自下部上升的热液流体,另一些观点认为铂族元素来自上部岩浆的硫化物沉降作用,并形成了Merensky辉石岩。已经知道矿层上覆的辉石岩、苏长岩和斜长岩中矿物来自两种岩浆类型:一种富含MgO(12%,质量分数)和Cr,而贫Al2O3(12%);另一种含典型的粒玄岩成分。UG-2铬铁岩含有全部经济资源量的58%,由一0.6~1m厚的铬铁岩层(有时见辉石岩夹层)和上覆的1~3层由铬铁矿所构成的薄层。虽然硫化物被认为至少是某些情况下对铂族元素的富集起作用,但UG-2的硫化物含量(0.5%~1.5%)显著低于Merensky矿层。UG-2层之下共有13个铬铁岩层位,所有的都含铂族元素,虽然铂族元素总含量和(Pt+Pd)/(Ru+Ir+Os)比值远低于UG-2。UG-2内所含的辉石岩"夹层"具高的87Sr/86Sr比值,说明与顶部熔融岩石的混合促进了铬铁岩和硫化物的形成。作用(iii)的主要实例是Platreef。目前它占总资源量的9%。不过,沿该带正积极开展找矿勘探工作,这一比例将来还会提高。这一矿层的厚度比Merensky和UG-2都要大,目前开采厚度达50多米。Platreef呈带状,上部为斜方辉石岩的堆晶岩;下部为辉石岩、长石辉石岩和苏长岩,它们与页岩、铁矿层和白云岩强烈相互作用,直接形成了底盘岩石。笔者认为Platreef是不同期次岩浆作用的结果,这些作用形成了不同的单元产物,包括布什维尔德主岩浆房的UG-2和Merensky矿层。新的岩浆进入主岩浆房会造成先存岩浆移位、岩浆错动并会冲破岩浆房的壁。圆筒状、带状岩管中的超镁铁岩含极高的Pt品位,在布什维尔德杂岩的下部切穿堆晶层,被认为是热液再活化的产物。它们现在未被开采,只是构成存封的铂族元素资源,对整个杂岩体资源没有重要的贡献。 相似文献
274.
Jeffrey?D.?MirochaEmail author Branko?Kosovi? Judith?A.?Curry 《Boundary-Layer Meteorology》2005,117(1):37-71
A diagnostic study of heat transfer within the lower atmosphere and between the atmosphere and the surface of the Arctic Ocean
snow/ice pack during clear-sky conditions is conducted using data from the Surface Heat Budget of the Arctic Ocean (SHEBA)
field experiment. Surface heat budgets computed for four cloudy and four clear periods show that, while the net turbulent
heat fluxes at the surface are small during the cloudy periods, during the clear-sky periods they are a considerable source
of surface heating, balancing significant portions of the conductive heat fluxes from within the snow/ice pack. Analysis of
the dynamics and thermodynamics of the lower atmosphere during the clear-sky periods reveals that a considerable portion of
the heat lost to the surface by turbulent heat fluxes is balanced by locally strong heating near the atmospheric boundary-layer
(ABL) top due to the interaction of subsiding motions with the strong overlying temperature inversions surmounting the ABL.
This heat is then entrained into the ABL and transported to the surface by turbulent mixing, maintained by a combination of
vertical wind shear and wave-turbulence interactions. The frequency of stable, clear-sky periods, particularly during the
winter, combined with these results, suggests that the downward transfer of heat through the lower atmosphere and into the
surface represents an important component of the heat budgets of the lower atmosphere and snow/ice pack over the annual cycle 相似文献