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31.
Abstract— Quantifying the peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent bodies. Various geothermometers have been used to estimate equilibration temperatures for chondrites of the highest metamorphic grade (type 6), but results are inconsistent and span hundreds of degrees. Because different geothermometers and calibration models were used with different meteorites, it is unclear whether variations in peak temperatures represent actual ranges of metamorphic conditions within type 6 chondrites or differences in model calibrations. We addressed this problem by performing twopyroxene geothermometry, using QUILF95, on the same type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer (Nakamuta and Motomura 1999). We also calculated temperatures for published pyroxene analyses from other type 6 H, L, and LL chondrites to determine the most representative peak metamorphic temperatures for ordinary chondrites. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865–926 °C), L6 (812–934 °C), and LL6 (874–945 °C) chondrites. Plagioclase temperature estimates are 96–179 °C lower than pyroxenes in the same type 6 meteorites. Plagioclase estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (~900 °C), which agrees with previously published oxygen isotope geothermometry, is at least 50 °C lower than the peak temperatures used in current asteroid thermal evolution models. This difference may require minor adjustments to thermal model calculations. 相似文献
32.
Summary A model of radial drifting and oscillating dipoles to represent geomagnetic palaeosecular variations, which showed to be appropriate for the Southern Hemisphere, is evaluated for the Northern Hemisphere. After a new fitting of some involved parameters, its theoretical results are compared with the palaeomagnetic data of Lake de Bouchet (France) and the Black Sea. A time lag between the declination and inclination profiles is observed in both cases. A good cross-correlation coefficient is obtained for the declination and inclination data.Presented at 2nd conference on New Trends in Geomagnetism, Castle of Bechyn, Czechoslovakia, September 24–29, 1990. 相似文献
33.
We have calculated prominence thread models for different values of the center temperature and pressure. We have simultaneously solved the radiative transfer, statistical equilibrium and ionization equilibrium equations assuming a three-level atom plus continuum. We have also computed the energy balance equation including the hydrogen radiative losses from our calculations, plus other radiative losses and heat conduction. Some models have been calculated assuming possible variations in thermal conductivity and heating terms. We computed the lines and continua emitted by a number of threads, in order to compare with the observations and evaluate how the different values of the parameters affect the profiles and absolute intensities of L, L, H, and Ly continuum.Member of the Carrera del Investigador, CONICET, Argentina.c.c.67 Suc. 28 Buenos Aires 1428, Argentina. 相似文献
34.
Verónica Oliveros Gilbert Féraud Luis Aguirre Luis Ramírez Michel Fornari Carlos Palacios Miguel Parada 《Mineralium Deposita》2008,43(3):281-293
The 40Ar/39Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district
in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic
Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed
mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting
a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit.
Because of the superposition of several magmatic and hydrothermal events, the obtained 40Ar/39Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories
of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate
volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting
the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal
stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma.
Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is
the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in
the metallogenic belt of the Coastal Cordillera of northern Chile.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
35.
RAÚL DE LA HORRA Ma ISABEL BENITO JOSE LÓPEZ‐GÓMEZ ALFREDO ARCHE JOSÉ F. BARRENECHEA JAVIER LUQUE 《Sedimentology》2008,55(6):1849-1873
The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis. 相似文献
36.
GERNOT ARP CHRISTIAN OSTERTAG‐HENNING SELÇÜK YÜCEKENT JOACHIM REITNER VOLKER THIEL 《Sedimentology》2008,55(5):1227-1251
Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe2+ and Mn2+ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO3 precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO3 precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ13C in conjunction with evaporite pseudomorphs showing extremely low δ13CCarb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition. 相似文献
37.
Ferromanganese crusts were found in carbonates of tectonostratigraphic units located in the northern and southern areas of the eastern External Subbetic of the Betic Cordilleras (SE Spain). The crusts are associated with four stratigraphic discontinuities of the Jurassic pelagic swells sequences: D1 (Late Carixian-Early Domerian), D2 (Middle Toarcian-Early Bajocian), D3 (Middle Bathonian-Middle Oxfordian), D4 (Early Tithonian-Late Albian). Two main textural types of crusts are distinguished. Type I crusts are thin and characterized by the presence of goethite, quartz, albite and phyllosilicates. Moreover, they show Si, Al, Mg, Na, Ti and K contents close to the European Shale Composite contents and Fe/Mn ratios (>350) higher than type II crusts. Type II crusts occur as thicker banded laminae and/or macrooncoids. They consist mainly of goethite and Mn-oxyhydroxides, which are enriched in REE, Co, Ni and Cu and show a strong Ce positive anomaly. After stratigraphical, mineralogical and geochemical data, the crust formation would be produced by the exposition of bottom sediments during long periods to a thin layer of oxidizing sea and porewater enriched in metallic elements. The textural and compositional variations between crusts can be explained by taking into account the bathymetric conditions. In shallower swells, the precipitation of a thick layer of banded type II crusts and in deeper areas, thin type I crusts were formed. Organic influence was only important in crusts from D3 of the northern area where textural evidence indicates the existence of seasonal periodically alternation between organism accretion and fine sedimentation. These were preceded and followed by phases in which the inorganic precipitation of oxides prevailed together with the fine sedimentation. 相似文献
38.
Reactive dissolved Hg (HgR), non-reactive dissolved Hg (HgNR), particulate Hg (HgP), dissolved organic C (DOC), particulate organic C (POC), salinity and other interpretative parameters were determined in water samples collected in the North Channel and in adjacent areas of the Tagus estuary (Portugal). Higher concentrations of both dissolved and particulate Hg in the North Channel indicate a pollution source and raise the possibility of Hg escaping to adjacent areas by tidal action. This transport was confirmed by the increase of HgR with salinity and HgNR with DOC, along a longitudinal axis paralleling the North Channel. Apparently, Hg leaving this channel is progressively complexed by inorganic and organic ligands. Near the mouth of the estuary, values decreased reflecting dilution with seawater. Moreover the HgP:POC ratio also increased seaward, suggesting mixing with Hg enriched particles that escaped the North Channel, or incorporation of dissolved Hg species in river-derived particles. These results suggest that the pathway of anthropogenic Hg in contaminated waters may be identified by their enrichment in organic matter, both in the dissolved and particulate fraction. 相似文献
39.
The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2 总被引:2,自引:1,他引:1
Josep M. Soler Marco Boi Jos Luis Mogolln Jordi Cama Carlos Ayora Peter S. Nico Nobumichi Tamura Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions. 相似文献
40.
The Simpevarp area is one of the alternative sites being considered for the deep geological disposal of high level radioactive waste in Sweden. In this paper, a coupled regional groundwater flow and reactive solute transport model of the Simpevarp area is presented that integrates current hydrogeological and hydrochemical data of the area. The model simulates the current hydrochemical pattern of the groundwater system in the area. To that aim, a conceptual hydrochemical model was developed in order to represent the dominant chemical processes. Groundwater flow conditions were reproduced by taking into account fluid-density-dependent groundwater flow and regional hydrogeologic boundary conditions. Reactive solute transport calculations were performed on the basis of the velocity field so obtained. The model was calibrated and sensitivity analyses were carried out in order to investigate the effects of heterogeneities of hydraulic conductivity in the subsurface medium. Results provided by the reactive transport model are in good agreement with much of the measured hydrochemical data. This paper emphasizes the appropriateness of the use of reactive solute transport models when water-rock interaction reactions are involved, and demonstrates what powerful tools they are for the interpretation of hydrogeological and hydrochemical data from site geological repository characterization programs, by providing a qualitative framework for data analysis and testing of conceptual assumptions in a process-oriented approach. 相似文献