Sources of Sediment in Lake Pepin on the Upper Mississippi River in Response to Holocene Climatic Changes

Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 ¹⁴C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation, snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America.     

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.     

Late Quaternary Spring-Fed Deposits of the Grand Canyon and Their Implication for Deep Lava-Dammed Lakes

One of the most intriguing episodes in the Quaternary evolution of the Grand Canyon of the Colorado River, Arizona, was the development of vast lakes that are thought to have backed up behind lava erupted into the gorge. Stratigraphic evidence for these deep lava-dammed lakes is expectedly sparse. Possible lacustrine deposits at six areas in the eastern canyon yielded no compelling evidence for sediment deposited in a deep lake. At two of the sites the sediment was associated with late Quaternary spring-fed pools and marshes. Water-lain silt and sand at lower Havasu Creek was deposited 3000 cal yr ago. The deposit contains an ostracode assemblage similar to that living in the modern travertine-dammed pools adjacent to the outcrop. The second deposit, at Lees Ferry, formed in a spring-fed marsh 43,000 cal yr ago, as determined by ¹⁴C and amino acid geochronology. It contains abundant ostracode and mollusk fossils, the richest assemblages reported from the Grand Canyon to date. Our interpretation of these sediments as spring-fed deposits, and their relative youth, provides an alternative to the conventional view that deposits like these were formed in deep lava-dammed lakes that filled the Grand Canyon.     

Wind velocity and sand transport on a barchan dune

We present measurements of wind velocity and sand flux performed on the windward side of a large barchan dune in Jericoacoara, northeastern Brazil. From the measured profile, we calculate the air shear stress using an analytical approximation and treat the problem of flow separation by an heuristic model. We find that the results from this approach agree well with our field data. Moreover, using the calculated shear velocity, we predict the sand flux according to well-known equilibrium relations and with a phenomenological continuum saltation model that includes saturation transients and thus allows for nonequilibrium conditions. Based on the field data and theoretical predicted results, we indicate the principal differences between saturated and nonsaturated sand flux models. Finally, we show that the measured dune moves with invariant shape and predict its velocity from our data and calculations.     

Application of DARLAM to Regional Haze Modeling

— The CSIRO Division of Atmospheric Research limited area model (DARLAM) is applied to atmospheric transport modeling of haze in southeast Asia. The 1998 haze episode is simulated using an emission inventory derived from hotspot information and adopting removal processes based on SO₂.¶Results show that the model is able to simulate the transport of haze in the region. The model images closely resemble the plumes of NASA Total Ozone Mapping Spectrometer and Meteorological Service Singapore haze maps. Despite the limitation of input data, particularly for haze emissions, the three-month average pattern correlation obtained for the whole episode is 0.61. The model has also been able to reproduce the general features of transboundary air pollution over a long period of time. Predicted total particulate matter concentration also agrees reasonably well with observation.¶The difference in the model results from the satellite images may be attributed to the large uncertainties of emission, simplification of haze deposition and transformation mechanisms and the relatively coarse horizontal and vertical resolution adopted for this particular simulation.     

The red bed controversy revisited: shape analysis of Colorado Plateau units suggests long magnetization times

Several Triassic and earliest Jurassic sedimentary units from the Colorado Plateau region have distributions of virtual geomagnetic poles (VGPs) that are highly elongate along the path of apparent polar wander (APW). This suggests that the remanent magnetizations measured in these units were acquired over an extended period of time, possibly approaching 35 m.y., and are not precisely coeval with the stratigraphic age of the rock. Comparison with other paleomagnetic studies shows that the observed elongation is not a general attribute of the age of the rock, nor is it related to paleolatitude. The rocks that yield elongate VGP distributions are dominantly red to brown mudstones, and it is possible that their remanence is dominated by a slowly acquired chemical remanent magnetization, as suggested by Larson et al. [J. Geophys. Res. 87 (1982) 1081] and other authors. However, several superficially similar units from the Colorado Plateau have nearly circular VGP distributions. The process by which remanence is acquired in clastic sedimentary rocks merits further study.     

Absolute velocity of North America during the Mesozoic from paleomagnetic data

We use paleomagnetic data to map Mesozoic absolute motion of North America, using paleomagnetic Euler poles (PEP). First, we address two important questions: (1) How much clockwise rotation has been experienced by crustal blocks within and adjacent to the Colorado Plateau? (2) Why is there disagreement between the apparent polar wander (APW) path constructed using poles from southwestern North America and the alternative path based on poles from eastern North America? Regarding (1), a 10.5° clockwise rotation of the Colorado Plateau about a pole located near 35°N, 102°W seems to fit the evidence best. Regarding (2), it appears that some rock units from the Appalachian region retain a hard overprint acquired during the mid-Cretaceous, when the geomagnetic field had constant normal polarity and APW was negligible.We found three well-defined small-circle APW tracks: 245–200 Ma (PEP at 39.2°N, 245.2°E, R=81.1°, root mean square error (RMS)=1.82°), 200–160 Ma (38.5°N, 270.1°E, R=80.4°, RMS=1.06°), 160 to 125 Ma (45.1°N, 48.5°E, R=60.7°, RMS=1.84°). Intersections of these tracks (the “cusps” of Gordon et al. [Tectonics 3 (1984) 499]) are located at 59.6°N, 69.5°E (the 200 Ma or “J1” cusp) and 48.9°N, 144.0°E (the 160 Ma or “J2” cusp). At these times, the absolute velocity of North America appears to have changed abruptly.North America absolute motion also changed abruptly at the beginning and end of the Cretaceous APW stillstand, currently dated at about 125 and 88 Ma (J. Geophys. Res. 97 (1992b) 19651). During this interval, the APW path degenerates into a single point, implying rotation about an Euler pole coincident with the spin axis.Using our PEP and cusp locations, we calculate the absolute motion of seven points on the North American continent. Our intention is to provide a chronological framework for the analysis of Mesozoic tectonics. Clearly, if APW is caused by plate motion, abrupt changes in absolute motion should correlate with major tectonic events. This follows because large accelerations reflect important changes in the balance of forces acting on the plate, the most important of which are edge effects (subduction, terrane accretion, etc.). Some tectonic interpretations: (1) The J1 cusp may be associated with the inception of rifting of North America away from land masses to the east; the J2 cusp seems to mark the beginning of rapid spreading in the North Atlantic. (2) The J2 cusp signals the beginning of a period of rapid northwestward absolute motion of western North America; motion of tectonostratigraphic terranes in the westernmost Cordillera seems likely to have been directed toward the south during this interval. (3) The interval 88 to 80 Ma saw a rapid decrease in the paleolatitude of North America; unless this represents a period of true polar wander, terrane motion during this time should have been relatively northward.     

Measurement and interpretation of molecular-level forces of interaction between the siderophore azotobactin and mineral surfaces

The forces of interaction were measured between the siderophore azotobactin and the minerals goethite (α-FeOOH) and diaspore (α-AlOOH) in aqueous solution using force microscopy. Azotobactin, a pyoverdin-type siderophore, was covalently linked to a hydrazide terminated atomic force microscope tip using a standard active ester protein coupling technique. Upon contact with each mineral surface, the adhesion force between azotobactin and goethite was two to three times the value observed for the isostructural Al-equivalent diaspore. The affinity for the solid iron oxide surface reflected in the force measurements correlates with the specificity of azotobactin for aqueous ferric iron. Further, the adhesion force between azotobactin and goethite significantly decreases (4 nN to 2 nN) when small amounts of soluble iron (0.1 μM FeCl₃ · 6H₂O) are added to the system at pH 3.5 suggesting a significant specific interaction between the chelating reactive center of azotobactin and the mineral surface. Changes in the force signature with pH and ionic strength were fairly predictable when considering mineral solubility, the charge character of the mineral surfaces, the molecular structure of azotobactin, and the intervening solution. For example, azotobactin-goethite adhesion values were consistently smaller at pH 3.5 relative to the forces at pH 7. At the lower pH, the large number of protons and the increase in the mineral solubility provides additional electron acceptors (e.g., H⁺ and Fe³⁺(aq)) that are free to compete for the basic oxygen chelating sites in the azotobactin structure. It is believed that this competition disrupts siderophore affinity for the surface resulting in decreased adhesion values.     

The postglacial history of three Picea species in New England, USA

Given the difficulty of separating the three Picea species—P. glauca, P. mariana, and P. rubens (white, black, and red spruce)—in the pollen record, little is known about their unique histories in eastern North America following deglaciation. Here we report the first use of a classification tree analysis (CART) to distinguish pollen grains of these species. It was successfully applied to fossil pollen from eight sites in Maine and one in Massachusetts. We focused on the late glacial/early Holocene (14,000 to 8000 cal yr B.P.) and the late Holocene (1400 cal yr B.P. to present)—the two key periods since deglaciation when Picea has been abundant in the region. The result shows a shift from a Picea forest of P. glauca and P. mariana in the late glacial to a forest of P. rubens and P. mariana in the late Holocene. The small number of P. rubens grains identified from the late glacial/early Holocene samples (<5%) suggests that that species was either absent or rare at most of the sites. The occurrence and distribution of the three species do not reveal any geographic or temporal trend during late glacial time, but the data suggest that they were distributed in local patches on the landscape. The results of this study indicate that the recent population expansion of Picea (1000 to 500 cal yr B.P.) was likely the first time since deglaciation that P. rubens was abundant in the region.     

Paleoclimate reconstruction based on the timing of speleothem growth and oxygen and carbon isotope composition in a cave located in the rain shadow in Israel

High-resolution ²³⁰Th/²³⁴U ages and δ¹⁸O and δ¹³C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ¹⁸O and δ¹³C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods.