12,000-Year, preliminary results of the stable nitrogen and carbon isotope record from the Empakai Crater lake sediments, Northern Tanzania

The stable isotope compositions of organic carbon and nitrogen, the contents of organic carbon and nitrogen and C/N ratios for two cores recovered from the Empakai Crater at water depths of 11 and 20 m are used to document climatic changes in northern Tanzania. Eight ¹⁴C AMS dates determined on total organic matter (OM) indicate that the sedimentation rate in this lake is about 30 cm/ka for the late Pleistocene to early Holocene period. There are differences in the δ¹³C values of organic carbon between the two cores, which may be a result of differences in location from the present shoreline and of different water depths. In the deeper-water core the δ¹³C values show a general downcore decrease to the base of the core with a sharp change to lower values of about 4‰ at a depth of 100 cm (8.7 ka). The general trend of downcore decrease in ¹³C values can be attributed either to a systematic decrease in the relative proportion of C₄ type of OM, owing to an increase in precipitation and change in vegetation cover from grassland to forest, or to utilization of isotopically enriched carbon during photosynthesis. The δ¹⁵N values show a general downcore increase with again a sharp change of about 5‰ to lower values at about 8.7 ka. A sharp change of about 5‰ and 4‰ to more depleted values at a depth of 100 cm of both ¹⁵N and ¹³C, respectively, suggests either hiatus or abrupt change in climatic condition from wetter conditions to drier conditions. There is enhanced preservation of OM in the lake as depicted by high mean values of organic carbon and nitrogen at both sites.     

Did the “Autochthonous” European foreland of Corsica Island (France) experience Alpine subduction?

Despite the important role played by the Sardinia‐Corsica block in the reconstruction of the Western Mediterranean geodynamics, the extent of involvement of the “Autochthonous” European margin exposed in Corsica (France) (i.e., Hercynian Corsica) in the Alpine orogeny remains uncertain. Stratigraphic and sedimentological studies in the post‐Variscan deposits on the Hercynian Corsica are scarce and even scarcer are the structural and metamorphic constraints. To face these uncertainties, we present new stratigraphic, structural and metamorphic data from the area of Razzo Bianco, Central Corsica, where a complete sequence belonging to the European continental margin is exposed. Field and structural investigations demonstrate that the sequence represents the easternmost edge of the downgoing European plate. Metamorphic studies on the Eocene deposits indicate that the margin was buried at depth up to blueschist facies conditions and, subsequently, it was progressively exhumed mainly through the activation of oblique top‐to‐the NW shear zones.     

Cotton canopy reflectance under variable solar zenith angles: Implications of use in evapotranspiration models

Evapotranspiration (ET) is an important parameter in hydrologic processes and modelling. In agricultural watersheds with competing uses of fresh water including irrigated agriculture, estimating crop evapotranspiration (ET_c) accurately is critical for improving irrigation system and basin water management. The use of remote sensing-based basal crop coefficients is becoming a common method for estimating crop evapotranspiration for multiple crops over large areas. The Normalized Difference Vegetation Index (NDVI) and the Soil Adjusted Vegetation Index (SAVI), based on reflectance in the red and near-infrared bands, are commonly used for this purpose. In this paper, we examine the effects of row crop orientation and soil background darkening due to shading and soil surface wetness on these two vegetation indices through modelling, coupled with a field experiment where canopy reflectance of a cotton crop at different solar zenith angles, was measured with a portable radiometer. The results show that the NDVI is significantly more affected than the SAVI by background shading and soil surface wetness, especially in north–south oriented rows at higher latitudes and could lead to a potential overestimation of crop evapotranspiration and irrigation water demand if used for basal crop coefficient estimation. Relationships between the analysed vegetation indices and canopy biophysical parameters such as crop height, fraction of cover and leaf area index also were developed for both indices.     

Shear-wave polarizations in the Peter the First Range indicating crack-induced anisotropy in a thrust-fault regime

Summary. Three-component seismograms of small local earthquakes recorded in the Peter the First Range of mountains near Garm, Tadzhikistan SSR, display shear-wave splitting similar to that previously observed near the North Anatolian Fault in Turkey. The Peter the First Range is in a region of compressional tectonics, whereas the North Anatolian Fault is a comparatively simple strike-slip fault. Detailed analysis of the Turkish records suggests that the splitting is diagnostic of crack-induced anisotropy caused by vertical microcracks aligned parallel to the direction of maximum compression. Preliminary examination of paper records from Garm shows that most shear waves arriving within the shear-wave window display shear-wave splitting, and that the polarizations of leading shear-waves are consistently aligned in a NE/SW direction. The area is complicated and the tectonics are not well-understood, but the NE/SW direction is approximately perpendicular to the compressional axis in many of the fault-plane mechanisms of the earthquakes. These earthquakes are usually at depths between 5 and 12 km, although there are some deeper events nearby.
Parallel shear-wave polarizations, such as those observed, are expected to indicate the strike of nearly vertical parallel microcracks, which would be aligned parallel to the direction of maximum compression. Thus the shear-wave polarizations in the Peter the First Range indicate that the directions of principal stress are reversed in the rock above the earthquake foci where thrust faulting is taking place.     

High-Frequency Response of the Atmospheric Electric Potential Gradient Under Strong and Dry Boundary-Layer Convection

The spectral response of atmospheric electric potential gradient gives important information about phenomena affecting this gradient at characteristic time scales ranging from years (e.g., solar modulation) to fractions of a second (e.g., turbulence). While long-term time scales have been exhaustively explored, short-term scales have received less attention. At such frequencies, space-charge transport inside the planetary boundary layer becomes a sizeable contribution to the potential gradient variability. For the first time, co-located (Évora, Portugal) measurements of boundary-layer backscatter profiles and the 100-Hz potential gradient are reported. Five campaign days are analyzed, providing evidence for a relation between high-frequency response of the potential gradient and strong dry convection.     

The Balance Between Capturing Phosphorus from Manure and Wastewater and the Demand for Crop Fertilizer in Italy

Phosphorus (P) is an essential nutrient required for plant growth and at the same time a costly pollutant, which can cause eutrophication of water bodies. Modern agriculture relies heavily on mineral fertilisers, which contain phosphorus derived from phosphate rock, because, without regular applications, crop yields would be limited. Since phosphate rock is a non-renewable resource, there are growing concerns regarding future phosphorus scarcity and the sustainability of modern agriculture. For many farmers, animal manure was once a means of maintaining soil fertility, but now it presents a major operational problem. This study evaluated the possibility of recycling phosphorus on a national and regional scale in Italy, using major sources of manure and wastewater. These results were successively compared with an estimate of the agricultural demand for phosphorus. Considering the quantity of phosphorus fertilizer that was applied to the soil–plant system, for the years 2001–2010, the annual phosphorus requirement of Italian crops was about 101,000 t of P. Therefore, the phosphorus source comprising animal manure and civil/industrial waste (117,500 t of P and 40,000 t of P, respectively) could potentially satisfy the average annual agronomic phosphorus demand. Regarding the geographical distribution of phosphorus supply and demand on a regional scale, areas with a large deficit of phosphorus included Calabria, Puglia and Marche. However, when only livestock waste was considered, Sicily, Umbria and Friuli could also be considered to be regions experiencing a phosphorus deficit.

     

Coal combustion by-product quality at two stoker boilers: Coal source vs. fly ash collection system design

Fly ashes from two stoker boilers burning Pennsylvanian Eastern Kentucky high volatile A bituminous coal blends were examined for their petrology and chemistry. The source coals have similar trace element contents. One of the ash collection systems was retrofitted with a baghouse (fabric filter) system, collecting a finer fly ash at a cooler flue gas temperature than the plant that has not been reconfigured. The baghouse ash has a markedly higher trace element content than the coarser fly ash from the other plant. The enhanced trace element content is most notable in the As concentration, reaching nearly 9000 ppm (ash basis) for one of the collection units. Differences in the ash chemistry are not due to any substantial differences in the coal source, even though the coal sources were from different counties and from different coal beds, but rather to the improved pollution control system in the steam plant with the higher trace element contents.     

Progression in sulfur isotopic compositions from coal to fly ash: Examples from single-source combustion in Indiana

Sulfur occurs in multiple mineral forms in coals, and its fate in coal combustion is still not well understood. The sulfur isotopic composition of coal from two coal mines in Indiana and fly ash from two power plants that use these coals were studied using geological and geochemical methods. The two coal beds are Middle Pennsylvanian in age; one seam is the low-sulfur (< 1%) Danville Coal Member of the Dugger Formation and the other is the high-sulfur (> 5%) Springfield Coal Member of the Petersburg Formation. Both seams have ash contents of approximately 11%. Fly-ash samples were collected at various points in the ash-collection system in the two plants. The results show notable difference in δ³⁴S for sulfur species within and between the low-sulfur and high-sulfur coal. The δ³⁴S values for all sulfur species are exclusively positive in the low-sulfur Danville coal, whereas the δ³⁴S values for sulfate, pyritic, and organic sulfur are both positive and negative in the high-sulfur Springfield coal. Each coal exhibits a distinct pattern of stratigraphic variation in sulfur isotopic composition. Overall, the δ³⁴S for sulfur species values increase up the section in the low-sulfur Danville coal, whereas they show a decrease up the vertical section in the high-sulfur Springfield coal. Based on the evolution of δ³⁴S for sulfur species, it is suggested that there was influence of seawater on peat swamp, with two marine incursions occurring during peat accumulation of the high-sulfur Springfield coal. Therefore, bacterial sulfate reduction played a key role in converting sulfate into hydrogen sulfide, sulfide minerals, and elemental sulfur. The differences in δ³⁴S between sulfate sulfur and pyritic sulfur is very small between individual benches of both coals, implying that some oxidation occurred during deposition or postdeposition.The δ³⁴S values for fly ash from the high-sulfur Springfield coal (averaging 9.7‰) are greatly enriched in ³⁴S relative to those in the parent coal (averaging 2.2‰). This indicates a fractionation of sulfur isotopes during high-sulfur coal combustion. By contrast, the δ³⁴S values for fly-ash samples from the low-sulfur Danville coal average 10.2‰, only slightly enriched in ³⁴S relative to those from the parent coal (average 7.5‰). The δ³⁴S values for bulk S determined directly from the fly-ash samples show close correspondence with the δ³⁴S values for SO₄^− 2 leached from the fly ash in the low-sulfur coal, suggesting that the transition from pyrite to sulfate occurred via high-temperature oxidation during coal combustion.