Reactive transport modeling of the interaction between water and a cementitious grout in a fractured rock. Application to ONKALO (Finland)

Grouting of water-conducting fractures with low-alkali cement is foreseen for the potential future repository for spent nuclear fuel in Finland (ONKALO). A possible consequence of the interaction between groundwater and grout is the formation of high-pH solutions which will be able to react with the host rock (gneisses) and alter its mineralogy and porosity. A reactive transport modeling study of this possible alteration has been conducted. First, the hydration of the low-alkali cementitious grout has been modeled, using results from the literature as a guide. The hydrated cement is characterized by the absence of portlandite and the presence of a C-S-H gel with a Ca/Si ratio about 0.8 after tens of years (Ca/Si is about 1.7 in Ordinary Portland Cement). Second, calculations have simulated the interaction between flowing water and grout and the formation of an alkalinity plume, which flows beyond the grouted section of the fracture. The calculations include the hydration and simultaneous leaching of the grout through diffusive exchange between the porewater in the grout and the flowing water in the fracture. The formation of an alkaline plume is extremely limited when the low-pH grout is used. Even when using a grout with a lower silica fume content, the extent and magnitude of the alkaline plume is quite minor. These results are in qualitative agreement with monitoring at ONKALO.     

Building global and diffuse solar radiation series and assessing decadal trends in Girona (NE Iberian Peninsula)

Measurement of solar radiation was initiated in Girona, northeast of the Iberian Peninsula, in the late 1980s. Initially, two pyranometers were installed, one of them equipped with a shadowband for measuring the diffuse component. Two other pyranometers currently exist, both ventilated and one of them shadowed, with a sphere, and a pyrheliometer for measuring direct radiation. Additional instruments for other shortwave and longwave components, clouds, and atmospheric aerosols have been installed in recent years. The station is subject to daily inspection, data are saved at high temporal resolution, and instruments are periodically calibrated, all in accordance with the directions of the Baseline Surface Radiation Network. The present paper describes how the entire series of global solar radiation (1987–2014) and diffuse radiation (1994–2014) were built, including the quality control process. Appropriate corrections to the diffuse component were made when a shadowband was employed to make measurements. Analysis of the series reveals that annual mean global irradiance presents a statistically significant increase of 2.5 W m⁻² (1.4 %) decade⁻¹ (1988–2014 period), mainly due to what occurs in summer (5.6 W m⁻² decade⁻¹). These results constitute the first assessment of solar radiation trends for the northeastern region of the Iberian Peninsula and are consistent with trends observed in the regional surroundings and also by satellite platforms, in agreement with the global brightening phenomenon. Diffuse radiation has decreased at −1.3 W m⁻² (−2 %) decade⁻¹ (1994–2014 period), which is a further indication of the reduced cloudiness and/or aerosol load causing the changes.

     

Cenozoic tectosedimentary evolution of Mallorca island

Abstract

The results of recent biostratigraphic, sedimentologic and structural work concerning the island of Mallorca have led us to elaborate a synthesis of the Cenozoic tectosedimentary evolution of this area. The recognition in the field of several unconformities enabled us to distinguish four Depositional Sequences embracing the pre and syntectonic deposits.

From Paleocene to part of Middle Eocene there was no sedimentation in the Mallorca area. This stratigraphie gap follows the onset of Africa-Europe convergence.

The area was stable during the first sequence (Upper Lutetian-Bartonian), which is trangressive towards the NW. Tectonic activity is recorded by the conglomeratic wedges of Depositional Sequence 11 (Priabonian-Lower Chattian). A dramatic paleogeographic change ocurred between Depositional Sequence II and III. Observed thrusts and unstable platform sediments of Depositional Sequence III (Upper Chattian-Lo-wermost Burdigalian) indicate the onset of thrust tectonics in the area. Turbiditic deposits of Depositional Sequence IV (Burdigalian-Langhian) are clearly syntectonic. Post-orogenic deposits range from Serravalian to recent and are not discussed in this paper.

Synthetic regional geological cross-sections have been constructed. They are used to restore the cartographic structural units to their relative pre-tectonic position and a palinspastic map for each Depositional Sequence has been obtained. These maps show both the sedimentary environment distribution and the active tectonic structures; hence they illustrate the tectosedimentary evolution of the Mallorca area through the Cenozoic.

This work has evident limitations arising from the small area studied in relation to the Cenozoic Betic basin and from the lacking subsurface data.     

Temperature effects on asexual reproduction of the scyphozoan Aurelia aurita s.l.: differences between exotic (Baltic and Red seas) and native (Mediterranean Sea) populations

Massive occurrences of jellyfish can cause direct impacts on the economy, especially on tourism and commercial fisheries. Translocation of jellyfish species by humans has caused damaging blooms in new habitats. Aurelia aurita s.l. has been introduced in many locations around the world. To test the potential success of Au. aurita s.l. in various habitats, scyphistomae from different climatic locations (Mediterranean, Red and Baltic Seas) were cultured individually for 201 days at three temperatures (14, 21 and 28 °C) with the same salinity, food and light. We tested the null hypotheses that there were no differences in survival or asexual reproduction (budding and strobilation) amongst populations [native (Mediterranean) and exotic (Red and Baltic)]. Survival of the three scyphistoma populations did not differ significantly across temperatures; however, the Red Sea group had lower survival at all temperatures than did the other populations. Most individuals strobilated at 14 °C. Red Sea scyphistomae strobilated more quickly than Baltic and Mediterranean Sea scyphistomae and produced the fewest ephyrae, whereas Baltic Sea scyphistomae produced the most. Our results indicate that Au. aurita from the Baltic or Red Seas introduced into the Northwest Mediterranean Sea would potentially persist and successfully asexually reproduce there. A new invader could even have greater asexual production than the local Au. aurita s.l. Establishment of the invaders could increase genetic variation of subsequent generations and increase their adaptability to environmental changes. Our results suggest that introduction of exotic Au. aurita s.l. populations could increase jellyfish blooms in the Mediterranean Sea.     

Annama H chondrite—Mineralogy,physical properties,cosmic ray exposure,and parent body history

The fall of the Annama meteorite occurred early morning (local time) on April 19, 2014 on the Kola Peninsula (Russia). Based on mineralogy and physical properties, Annama is a typical H chondrite. It has a high Ar‐Ar age of 4.4 Ga. Its cosmic ray exposure history is atypical as it is not part of the large group of H chondrites with a prominent 7–8 Ma peak in the exposure age histograms. Instead, its exposure age is within uncertainty of a smaller peak at 30 ± 4 Ma. The results from short‐lived radionuclides are compatible with an atmospheric pre‐entry radius of 30–40 cm. However, based on noble gas and cosmogenic radionuclide data, Annama must have been part of a larger body (radius >65 cm) for a large part of its cosmic ray exposure history. The ¹⁰Be concentration indicates a recent (3–5 Ma) breakup which may be responsible for the Annama parent body size reduction to 30–35 cm pre‐entry radius.     

Petrographic and geochemical evidence for multiphase formation of carbonates in the Martian orthopyroxenite Allan Hills 84001

Martian meteorites can provide valuable information about past environmental conditions on Mars. Allan Hills 84001 formed more than 4 Gyr ago, and owing to its age and long exposure to the Martian environment, and this meteorite has features that may record early processes. These features include a highly fractured texture, gases trapped during one or more impact events or during formation of the rock, and spherical Fe‐Mg‐Ca carbonates. In this study, we have concentrated on providing new insights into the context of these carbonates using a range of techniques to explore whether they record multiple precipitation and shock events. The petrographic features and compositional properties of these carbonates indicate that at least two pulses of Mg‐ and Fe‐rich solutions saturated the rock. Those two generations of carbonates can be distinguished by a very sharp change in compositions, from being rich in Mg and poor in Fe and Mn, to being poor in Mg and rich in Fe and Mn. Between these two generations of carbonate is evidence for fracturing and local corrosion.