Estimates of Reynolds stress in a highly energetic shelf sea

In recent years the use of Acoustic Doppler Current Profilers (ADCPs) to estimate Reynolds stresses, using the so-called variance method, has become popular; and although there was great effort in studying the uncertainties on this technique, there were no reports in the main literature of its validity using independent measurements. This work reports on the comparison of ADCP and Acoustic Current Velocimeter (ADV) estimates of Reynolds stresses. The comparison of the ADCP and ADV is encouraging during periods when no strong waves were present with both the explained variance of 0.8 and the slope of the regression being 0.97. Nevertheless, when strong waves are present the method breaks down and the comparison between ADCP and ADV is very poor with R² =0.04.     

Stability, solubility and maximum metal binding capacity in metal–humic complexes involving humic substances extracted from peat and organic compost

The aim of this work is to investigate the influence of pH and the metal:humic substances (HS) ratio on HS complexing capacity and the stability and solubility of metal–HS complexes in solution. We selected four HS with different physicochemical properties and studied their interaction with Cu(II), Zn(II) and Fe(II) at different pH and metal:HS ratios. The selected HS were a humic acid and a whole humic extract (containing the humic and fulvic acids) extracted from black peat, and a fulvic acid and a whole humic extract extracted from a compost of grape solid wastes.Our results showed that HS complexing capacity significantly varied as a function of pH, thus indicating the influence of both functional group ionisation and molecular conformation on this property. As was expected, total acidity affected the complexing capacity of the selected HS.The results related to stability and complexing capacity indicated the possible presence of two binding patterns, one at acid-neutral pH probably involving carboxylates, and another at alkaline pH probably involving carboxylates and phenolic groups. The relationship between these binding patterns and the strength of the binding process varied according to the complexed metal.Complex solubility was greatly affected by the ratio between the concentration of free ionised functional groups and the molecular weight in the HS studied.     

Geochemistry of the volcano-hydrothermal system of El Chichón Volcano, Chiapas, Mexico

 The 1982 eruption of El Chichón volcano ejected more than 1 km³ of anhydrite-bearing trachyandesite pyroclastic material to form a new 1-km-wide and 300-m-deep crater and uncovered the upper 500 m of an active volcano-hydrothermal system. Instead of the weak boiling-point temperature fumaroles of the former lava dome, a vigorously boiling crater spring now discharges  / 20 kg/s of Cl-rich (∼15 000 mg/kg) and sulphur-poor ( / 200 mg/kg of SO₄), almost neutral (pH up to 6.7) water with an isotopic composition close to that of subduction-type magmatic water (δD=–15‰, δ¹⁸O=+6.5‰). This spring, as well as numerous Cl-free boiling springs discharging a mixture of meteoric water with fumarolic condensates, feed the crater lake, which, compared with values in 1983, is now much more diluted (∼3000 mg/kg of Cl vs 24 030 mg/kg), less acidic (pH=2.6 vs 0.56) and contains much lower amounts of S ( / 200 mg/kg of SO₄, vs 3550 mg/kg) with δ³⁴S=0.5–4.2‰ (+17‰ in 1983). Agua Caliente thermal waters, on the southeast slope of the volcano, have an outflow rate of approximately 100 kg/s of 71  °C Na–Ca–Cl water and are five times more concentrated than before the eruption (B. R. Molina, unpublished data). Relative N₂, Ar and He gas concentrations suggest extensional tectonics for the El Chichón volcanic centre. The ³He/⁴He and ⁴He/²⁰Ne ratios in gases from the crater fumaroles (7.3R_a, 2560) and Agua Caliente hot springs (5.3R_a, 44) indicate a strong magmatic contribution. However, relative concentrations of reactive species are typical of equilibrium in a two-phase boiling aquifer. Sulphur and C isotopic data indicate highly reducing conditions within the system, probably associated with the presence of buried vegetation resulting from the 1982 eruption. All Cl-rich waters at El Chichón have a common source. This water has the appearence of a "partially matured" magmatic fluid: condensed magmatic vapour neutralized by interaction with fresh volcaniclastic deposits and depleted in S due to anhydrite precipitation. Shallow ground waters emerging around the volcano from the thick cover of fresh pumice deposits (Red waters) are Ca–SO₄–rich and have a negative oxygen isotopic shift, probably due to ongoing formation of clay at low temperatures. Received: 21 July 1997 / Accepted: 4 December 1997     

Microdeformation of lacustrine laminite sequences from Late Miocene formations of SE Spain: an interpretation of loop bedding

Lacustrine laminated sediments (laminites) present in Late Miocene formations of the Híjar Basin, SE Spain, display well developed loop bedding, a structure consisting of bundles of laminae that are sharply constricted at intervals, giving a morphology of loops or links of a chain. The laminite sequences, which are interbedded with turbidite marlstones, were accumulated on the bottom of a permanently stratified lake developed in a rapidly subsiding basin limited by 010° and 105° normal faults. As deduced from both macro- and microdeformational analyses, the basin evolved under an extensional stress field throughout the Late Miocene. Four main types of loops, simple and complex loops with subcategories, have been recognized within the laminite sequence. Simple loops of type 1 show the best definite pattern, quite similar to ' pinch and swell structures ', a type of boudinage typical of stretching of alternating beds where the competence contrast is not strongly marked. The remaining loop types display contortion and occasional breakage of laminae (microfaulted edges) indicative of microdeformation near the boundary between the ductile-brittle deformational fields. The distribution of the various loop types across the laminite sequence reflects an interplay between progressive lithification of the laminites as sedimentation progressed and tectonic stresses which affected the sediment sequence. Accordingly, a mechanism of deformation under an extensional stress field, ultimately related to the creep movement of the main basin faults which resulted in successive seismic shocks of low magnitude, is proposed to explain the formation of loop bedding in the laminites.     

Development and erosion in the Brazilian Amazon: A geochronological case study

A ²¹⁰Pb chronology of sedimentation in a small floodplain lake in the Jamari river basin (Rondonia, Brazil) provided insight into the relationship between development and erosion in the Brazilian Amazon. Positive correlations between increased sedimentation in the lake and levels of deforestation and mining in the Jamari basin suggested a major increase in erosion associated with these activities. This increase in erosion could diminish agricultural yields in the basin and significantly reduce the useful life of a hydro-electric plant recently built on the river.     

Photoelectrons in the upper atmosphere: A formulation incorporating effects of transport

An efficient scheme is described for computation of photoelectron energy spectra. The method, similar to one used in radiative transfer theory, incorporates effects due to spatial and angular redistribution of electrons. These effects play a dominant role at heights above 400 km.     

Impact of a Saturation-Dependent Dissipation Source Function on Operational Hindcasts of Wind-Waves in the Australian Region

The impact of a modified parametric form of the dissipation source function S ds on the skill of an operational spectral wind-wave model is investigated. Numerical experiments are made with a version of the WAM model presently used operationally by the Australian Bureau of Meteorology to produce sea-state forecasts within the Australian region. Performances of wave hindcasts obtained using several alternative forms of this newly proposed dissipation source function are compared to those produced with forms of S ds commonly used operationally. A new ad hoc technique to compare modelled and observed wave spectra is introduced to assess the quality of calculated one-dimensional frequency spectra.

Our results indicate that wave model performance in terms of integral spectral parameters, such as the significant wave height H s , may benefit from improved parameterisations of the dissipation source term S ds . On the other hand, we also found that model performance was relatively poor in terms of predictions of the one-dimensional frequency spectrum, regardless of the chosen form of S ds . These results suggest that further refinements of the dissipation source term are strongly dependent on improved parametrisations of the nonlinear interactions source term S nl .     

A test of the Tate equation to predict bubble size at an orifice in the presence of frother

Air bubbles of uniform size (ca. 1 mm diameter) were generated at a submerged orifice (glass capillary) under controlled frequency (down to ca. 0.06 s^− 1) in aqueous solutions of frother (Dowfroth 250). The bubbles were sized with an imaging technique. One objective was to establish whether the Tate equation (static balance between buoyancy and capillary forces) could be used as a standard sizing calibration method. Another aim was to verify whether with decreasing surface tension (due to increasing frother concentration) the anticipated decrease in bubble size agreed with the equation prediction. An effect of frother was detected compatible with the role of surface tension but divided into two concentration regions, seemingly the result of a gradual change in bubble shape and wetting: > 6 ppm the bubble holds a spherical shape and the capillary appeared to be completely wetted while at ≤ 6 ppm a degree of non-wetting and bubble distortion (neck formation just prior to detachment) were apparent, supported by qualitative observations. In addition, at > 6 ppm the Tate value was only approached by decreasing the bubble frequency but not attained. Plausible causes for the failure to reach the predicted size are discussed.     

ESTIMATION OF ERRORS IN ABSORBANCE RATIO MEASUREMENTS

Ratio measurements are commonly used to address a variety of analytical problems in environmental,forensic and pharmaceutical laboratories.In absorbance ratioing techniques,analytical chemists rely onthe spectral features of the analyte(s)of interest.The absorbances at two wavelengths are monitored andthe ratio of these two absorbances is computed.This ratio is then used to confirm the identity of theanalyte(s)of interest,the purity of a product or the overlap of chromatographic peaks.These decisionsoften have far-reaching consequences(e.g.the identification of the source,biogenic or petrogenic,ofhydrocarbons in biological tissues or water).Given the cost and the liabilities associated with suchdecisions,it is unfortunate that these ratios are seldom reported with any statistical confidence.Thepurpose of this study is to delineate the parameters that affect absorbance ratio measurements.Themodels that can be used to estimate the statistical confidence in these measurements are derived andevaluated experimentally.The results show that these models can estimate the relative standard deviationsin absorbance ratios accurately.They can also estimate the effect of signal-to-noise ratio and the choiceof wavelengths on the precision of absorbance ratios.