New major element analyses of proximal tephras from the Azores and suggested correlations with cryptotephras in North-West Europe

The Azores Archipelago is one of the most active volcanic areas in the North Atlantic region. Approximately 30 eruptions have been reported over the last 600 years with some major VEI 5 (Volcanic Explosivity Index) eruptions further back in time. The geochemical composition of associated tephra-derived glass, however, is not well characterized. An Azorean origin of cryptotephras found in distal areas such as North Africa, the British Isles and Greenland has been suggested, but proximal data from the Azores are scarce and the correlations have only been tentative. These tephras have a traychtic composition, which excludes an Icelandic origin. In a previous study, we presented major element analyses of proximal tephra-derived glass from five Holocene eruptions on the Azores Islands. There is a striking geochemical similarity between tephras from volcanoes on São Miguel and Irish cryptotephras, and especially with eruptives from the Furnas volcano. Here we present new analyses of proximal tephras that confirm and strengthen a link between Furnas and cryptotephras found in south-west Ireland. We also suggest a correlation between a previously unsourced tephra found in a Swedish bog with an eruption of the Sete Cidades volcano c. 3880 a cal BP.     

Granular element method for three‐dimensional discrete element calculations

This paper endows the recently‐proposed granular element method (GEM) with the ability to perform 3D discrete element calculations. By using non‐uniform rational B‐Splines to accurately represent complex grain geometries, we proposed an alternative approach to clustering‐based and polyhedra‐based discrete element methods whereby the need for complicated and ad hoc approaches to construct 3D grain geometries is entirely bypassed. We demonstrate the ability of GEM in capturing arbitrary‐shaped 3D grains with great ease, flexibility, and without excessive geometric information. Furthermore, the applicability of GEM is enhanced by its tight integration with existing non‐uniform rational B‐Splines modeling tools and ability to provide a seamless transition from binary images of real grain shapes (e.g., from 3D X‐ray CT) to modeling and discrete mechanics computations.Copyright © 2013 John Wiley & Sons, Ltd.     

8000 years of vegetation history in the northern Iberian Peninsula inferred from the palaeoenvironmental study of the Zalama ombrotrophic bog (Basque‐Cantabrian Mountains,Spain)

This paper focuses on pollen, spores, non‐pollen palynomorphs (NPPs) and certain geochemical elements from the ombrotrophic blanket bog of Zalama (Basque‐Cantabrian Mountains, northern Iberian Peninsula), with the support of a robust chronology based on 17 AMS ¹⁴C dates. The main results related to the last 8000 years show that, during the early middle Holocene, pines and deciduous forests were the most extensive tree formations. At the beginning of the succession, pines reach 44%, showing regional presence, whereas after 7600 cal. a BP, deciduous forests were particularly abundant. From c. 6500 cal. a BP the pollen diagram constructed from our samples shows the first anthropogenic evidence, linked with the new economic practices related to the Neolithic of the Basque‐Cantabrian Mountains. From 3300 cal. a BP the expansion of Fagus sylvatica is particularly clear, and has since then become one of the dominant forest species in this region. We also discuss the Holocene evolution of other noteworthy plant communities in southwestern Europe, such as Taxus baccata, Juglans and shrublands.     

Metals discharged during different flow conditions from a mixed agricultural‐forest catchment (NW Spain)

Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.     

Short‐ and long‐term evapotranspiration rates at ecological restoration sites along a large river receiving rare flow events

Many large rivers around the world no longer flow to their deltas, due to ever greater water withdrawals and diversions for human needs. However, the importance of riparian ecosystems is drawing increasing recognition, leading to the allocation of environmental flows to restore river processes. Accurate estimates of riparian plant evapotranspiration (ET) are needed to understand how the riverine system responds to these rare events and achieve the goals of environmental flows. In 2014, historic environmental flows were released into the Lower Colorado River at Morelos Dam (Mexico); this once perennial but now dry reach is the final stretch to the mighty Colorado River Delta. One of the primary goals was to supply native vegetation restoration sites along the reach with water to help seedlings establish and boost groundwater levels to foster the planted saplings. Patterns in ET before, during, and after the flows are useful for evaluating whether this goal was met and understanding the role that ET plays in this now ephemeral river system. Here, diurnal fluctuations in groundwater levels and Moderate Resolution Imaging Spectroradiometer (MODIS) data were used to compare estimates of ET specifically at 3 native vegetation restoration sites during 2014 planned flow events, and MODIS data were used to evaluate long‐term (2002–2016) ET responses to restoration efforts at these sites. Overall, ET was generally 0–10 mm d^?1 across sites, and although daily ET values from groundwater data were highly variable, weekly averaged estimates were highly correlated with MODIS‐derived estimates at most sites. The influence of the 2014 flow events was not immediately apparent in the results, although the process of clearing vegetation and planting native vegetation at the restoration sites was clearly visible in the results.     

OSL signal resetting in young deposits determined with a pulsed photon‐stimulated luminescence (PPSL) unit

Optical Stimulated Luminescence (OSL) is a technique that can be used for dating geological materials deposited within the last half‐million years, including sediments transported by air, water or gravity, as well as rocks heated at high temperatures. Recently, several studies have shown that OSL can also provide information on sediment transport. The pulsed photon‐stimulated luminescence (PPSL) unit (also known as a portable OSL reader) developed by the Scottish Universities Environmental Research Centre is an instrument designed to read luminescence signals from bulk (untreated) sediment samples comprising poly‐mineral and poly‐grain fractions. In this contribution, we evaluate the potential of the PPSL unit to assess the degree of OSL signal resetting in 27 young deposits (<2 ka) transported by different geomorphic agents in volcanic, coastal and fluvial depositional settings located in Mexico. Our results are in agreement with previous findings that used the Risø TL/OSL reader, confirming that sediments transported by debrisflows contain the highest inherited luminesce signals. Infrared stimulation (IRSL) values in volcanic ash, lavas, and sand beach and dune deposits exhibit low scatter. However, with blue stimulation (BLSL) these samples reveal a large degree of scattering, attributed to charge transfer in the case of the coastal deposits and to the low sensitivity of quartz in the case of volcanic material. The luminescence signals of fluvial sediments exhibit a highly scattered distribution in both IRSL and BLSL. We conclude that the use of a PPSL unit is a simple approach to assess the degree of OSL signal resetting in deposits sourced from different geological environments. This research contributes to previous studies that have investigated new applications of the PPSL unit to assist in OSL dating of geological materials.     

Importance of mixotrophic nanoplankton in Aysén Fjord (Southern Chile) during austral winter

Mixotrophy, the combination of autotrophic and heterotrophic nutrition in the same organism, is widespread in planktonic algae. Several reports from temperate and high-latitude fjords in Scandinavia suggest the occurrence of a niche in late summer and autumn during post-bloom conditions in which mixotrophic algae can become important grazers in pelagic ecosystems, accessing the nutrients bound in their prey to overcome nutrient limitation. Here, we experimentally determined the trophic modes and bacterivory rates for the nanoplankton community (2–20 μm) in Aysén Fjord located in the Chilean Northern Patagonia during two contrasting seasons: winter and spring. While mixotrophic nanoplankton was virtually absent from the system in spring, in winter at occasions it even constituted the dominant trophic group of the nanoplankton with abundances of >900 cells mL^?1. This indicates a second niche for mixotrophs in winter, when mixotrophy allows overcoming light limitation.     

Latitudinal patterns of export production recorded in surface sediments of the Chilean Patagonian fjords (41–55°S) as a response to water column productivity

The Chilean Patagonian fjords region (41–56°S) is characterized by highly complex geomorphology and hydrographic conditions, and strong seasonal and latitudinal patterns in precipitation, freshwater discharge, glacier coverage, and light regime; all of these directly affect biological production in the water column. In this study, we compiled published and new information on water column properties (primary production, nutrients) and surface sediment characteristics (biogenic opal, organic carbon, molar C/N, bulk sedimentary δ¹³C_org) from the Chilean Patagonian fjords between 41°S and 55°S, describing herein the latitudinal pattern of water column productivity and its imprint in the underlying sediments. Based on information collected at 188 water column and 118 sediment sampling sites, we grouped the Chilean fjords into four main zones: Inner Sea of Chiloé (41° to ～44°S), Northern Patagonia (44° to ～47°S), Central Patagonia (48–51°S), and Southern Patagonia (Magellan Strait region between 52° and 55°S). Primary production in the Chilean Patagonian fjords was the highest in spring–summer, reflecting the seasonal pattern of water column productivity. A clear north–south latitudinal pattern in primary production was observed, with the highest average spring and summer estimates in the Inner Sea of Chiloé (2427 and 5860 mg C m^?2 d^?1) and Northern Patagonia (1667 and 2616 mg C m^?2 d^?1). This pattern was closely related to the higher availability of nutrients, greater solar radiation, and extended photoperiod during the productive season in these two zones. The lowest spring value was found in Caleta Tortel, Central Patagonia (91 mg C m^?2 d^?1), a site heavily influenced by glacier meltwater and river discharge loaded with glacial sediments. Biogenic opal, an important constituent of the Chilean fjord surface sediments (Si_OPAL ～1–13%), reproduced the general north–south pattern of primary production and was directly related to water column silicic acid concentrations. Surface sediments were also rich in organic carbon content and the highest values corresponded to locations far away from glacier influence, sites within fjords, and/or semi-enclosed and protected basins, reflecting both autochthonous (water column productivity) and allochthonous sources (contribution of terrestrial organic matter from fluvial input to the fjords). A gradient was observed from the more oceanic sites to the fjord heads (west–east) in terms of bulk sedimentary δ¹³C_org and C/N ratios; the more depleted (δ¹³C_org ?26‰) and higher C/N (23) values corresponded to areas close to rivers and glaciers. A comparison of the Chilean Patagonian fjords with other fjord systems in the world revealed high variability in primary production for all fjord systems as well as similar surface sediment geochemistry due to the mixing of marine and terrestrial organic carbon.     

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.     

Tropical precipitation anomalies and d‐excess evolution during El Niño 2014‐16

The last 2014‐16 El Niño event was among the three strongest episodes on record. El Niño considerably changes annual and seasonal precipitation across the tropics. Here, we present a unique stable isotope data set of daily precipitation collected in Costa Rica prior to, during, and after El Niño 2014‐16, in combination with Lagrangian moisture source and precipitation anomaly diagnostics. δ²H composition ranged from ‐129.4 to +18.1 (‰) while δ¹⁸O ranged from ‐17.3 to +1.0 (‰). No significant difference was observed among δ¹⁸O (P=0.186) and δ²H (P=0.664) mean annual compositions. However, mean annual d‐excess showed a significant decreasing trend (from +13.3 to +8.7 ‰) (P<0.001) with values ranging from +26.6 to ‐13.9 ‰ prior to and during the El Niño evolution. The latter decrease in d‐excess can be partly explained by an enhanced moisture flux convergence across the southeastern Caribbean Sea coupled with moisture transport from northern South America by means of an increased Caribbean Low Level Jet regime. During 2014‐15, precipitation deficit across the Pacific domain averaged 46% resulting in a very severe drought; while a 94% precipitation surplus was observed in the Caribbean domain. Understanding these regional moisture transport mechanisms during a strong El Niño event may contribute to a) better understanding of precipitation anomalies in the tropics and b) re‐evaluate past stable isotope interpretations of ENSO events in paleoclimatic archives within the Central America region.