Sea cliffs resulting from late Miocene extensional tectonics: the Serra Gelada case study (Betic Cordillera, Spain)

The Serra Gelada sea cliffs are carved in Mesozoic carbonate rocks belonging to the External Zones of the eastern Betic Cordillera (Alicante, SE Spain). Several normal faults with vertical slips of more than a hundred metres have played an important role in the origin of this coastline. Some previous studies propose that the present cliff morphology was mainly originated by Quaternary fault activity. However, the integration of geomorphological features, stratigraphical and sedimentological data, together with the results of the tectonic analysis of fractures occurring in Serra Gelada, and a detailed study of seismic reflection profiles carried out in the adjacent continental shelf, indicate that these normal faults were active mainly during the late Miocene. Therefore, the Serra Gelada sea cliffs represent a tectonically controlled long-term landscape. Thus, normal faults have not significantly modified the Serra Gelada relief since then. Furthermore, the northern part of the Serra Gelada cliff may be considered as an inherited pre-Quaternary relict palaeocliff since it has only undergone very little erosive recession.     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

Is Prediction of Future Landslides Possible with a GIS?

This contribution explores a strategy for landslide hazard zonation inwhich layers of spatial data are used to represent typical settings inwhich given dynamic types of landslides are likely to occur. Theconcepts of assessment and prediction are defined to focus on therepresentation of future hazardous events and in particular on themyths that often provide obstacles in the application of quantitativemethods. The prediction rate curves for different applications describethe support provided by the different data layers in experiments inwhich the typical setting of hazardous events is approximated bystatistically integrating the spatial information.     

Oxygen isotope composition and geothermometry of granulite to greenschist facies metamorphic rocks: a study from the Neoproterozoic collision-related nappe system, south of São Francisco Craton, SE Brazil

Oxygen isotope studies were carried out across units of a Neoproterozoic nappe system, south of São Francisco Craton. A temperature decrease toward the base of the system is found, consistent with a previously recognized inverted metamorphic pattern. The tectonic contact of the basal unit and the reworked southern São Francisco craton show a steep temperature gradient, suggesting that low temperature thrusting acted as the dominant tectonic process. The contrasts between the δ¹⁸O values of the Três Pontas-Varginha and Carmo da Cachoeira nappes and the differences among the samples and minerals are consistent with the preservation of sedimentary isotopic composition during metamorphism. The small differences in the δ¹⁸O values between the undeformed and the deformed calc-silicate samples (1.6‰) suggest that the δ¹⁸O value of mylonitization fluids was close to that which equilibrated with the metamorphic assemblage. The distinct δ¹⁸O values of metapelitic and calc-silicate samples and the great temperature difference from one type to the other indicate that no large-scale fluid interaction processes occurred during metamorphism. Oxygen isotopic estimations of both Três Pontas-Varginha undeformed rocks and Carmo da Cachoeira unaltered equivalents indicate δ¹⁸O values of up to 18‰. Comparison between these values and those from the ‘basement’ orthogneisses (8.3–8.5‰) indicates the latter are not sources for the metapelites.     

Microstructural evolution of the Seridó Belt, NE-Brazil: the effect of two tectonic events on development of c-axis preferred orientation in quartz

The polyphase evolution of the Seridó Belt (NE-Brazil) includes D₁ crust formation at 2.3–2.1 Ga, D₂ thrust tectonics at 1.9 Ga and crustal reworking by D₃ strike-slip shear zones at 600 Ma. Microstructural investigations within mylonites associated with D₂ and D₃ events were used to constrain the tectono-thermal evolution of the belt. D₂ shear zones commenced at deeper crustal levels and high amphibolite facies conditions (600–650 °C) through grain boundary migration, subgrain rotation and operation of quartz c-prism slip. Continued shearing and exhumation of the terrain forced the re-equilibration of high-T fabrics and the switching of slip systems from c-prism to positive and negative a-rhombs. During D₃, enhancement of ductility by dissipation of heat that came from syn-D₃ granites developed wide belts of amphibolite facies mylonites. Continued shearing, uplift and cooling of the region induced D₃ shear zones to act in ductile-brittle regimes, marked by fracturing and development of thinner belts of greenschist facies mylonites. During this event, switching from a-prism to a-basal slip indicates a thermal path from 600 to 350 °C. Therefore, microstructures and quartz c-axis fabrics in polydeformed rocks from the Seridó Belt preserve the record of two major events, which includes contrasting deformation mechanisms and thermal paths.     

Validation of Landslide Susceptibility Maps; Examples and Applications from a Case Study in Northern Spain

A procedure for validating landslide susceptibility maps wasapplied in a study area in northern Spain and the results obtained compared. Validationwas used to carry out sensitivity analysis for individual variables and combinationsof variables. The validity of different map-making methods was tested, as well as theutility of different types of Favourability Functions. The results obtained show thatvalidation is essential to determine the predictive value of susceptibility maps. Italso helps to better select the most suitable function and significant variables, thus improving the efficiency of the mapping process. Validation based on a temporal strategy makes it possible to derive hazard maps from susceptibility maps.     

Effects of early season defoliation ofAnthyllis cytisoides(a Mediterranean browse species) on further herbivore attack

To determine if defoliation of a woody plant affects foraging by folivorous insects, we examined the infection rate (number of leaves damaged per total number of leaves sampled on marked stems) ofAnthyllis cytisoidesunder three experimental treatments: 10, 50 and 90% plant defoliation. Observations were made for three age classes, established by trunk base perimeter (equal to or lower than 11 cm, between 11 and 20 cm, larger than 20 cm). Plants respond positively to artificial defoliation by increasing total vegetative length of the stem and total inflorescence length. This response is most evident in young individuals.Response to herbivory was measured as overall infection rate and also as infection rate by different feeding guilds—chewing, mining, or sucking insects. We found that increased defoliation elicited increased resistance of leaves to insect attack. This was particularly evident in young plants. Different insect guilds respond in different ways. Attack by chewing insects declines with defoliation for all plant age classes; only sucking insects which feed on the oldest plants reduce feeding rate with plant defoliation. Finally, mining insects present the opposite trend in young and senescent plants.     

A mass transfer model of bauxite formation

The formation of bauxite due to weathering of a granitic protolith has been simulated by means of a one-dimensional flow and reaction model based on the mass transfer principle. The model couples mineral dissolution and precipitation reactions, speciation in solution, and advective solute transport in a porous medium. A very important aspect of the modeling study is the use of mineral reaction rates determined experimentally in the laboratory. The important effects of solution saturation state and pH have been incorporated into the kinetic rate laws governing the heterogeneous reactions. The values of these parameters have been obtained from the scientific literature to guarantee that realistic reaction rates are used in the simulations. Albite and quartz are the minerals that make up the parent rock in the model. Gibbsite, kaolinite, and a Na-mica (as a surrogate for smectite) are the secondary minerals that have been taken into account. Long-term simulations (>1 Ma) have been run, and the formation of a bauxitic profile, with an upper gibbsite-rich and a lower kaolinite-rich zone, is predicted. In early stages of the process (up to a few hundreds of thousands of years), both gibbsite and kaolinite precipitate directly from solution as a consequence of albite dissolution. In later stages, the bulk of gibbsite precipitation derives from the incongruent dissolution of kaolinite, while kaolinite precipitation is still caused by the dissolution of albite. This is also reflected by the formation of two reaction fronts in the profile. These results are compared with weathering sequences from the Los Pijiguaos bauxite deposit, Venezuela. The overlap between the gibbsite and kaolinite zones and the replacement of kaolinite by gibbsite are consistent with model calculations. Mechanical denudation has to be called upon to explain the limited thicknesses of the weathering profiles in the field. The role of mechanical erosion is supported by the presence of microsedimentary structures in the bauxite and the balance between dissolved and suspended loads in the streams draining the area.