Patterns of spatial variation of nutrient content,epiphyte load and shoot size of Posidonia oceanica seagrass meadows (Mediterranean Sea)

Knowledge of patterns of spatial variability of vegetative development, epiphyte load and nutrient availability in seagrass meadows is essential for the adequate design of research and environmental monitoring programmes. Differences in shoot size, epiphyte load and nutrient content of leaves and epiphytes of the Mediterranean endemic seagrass Posidonia oceanica at spatial scales ranging from metres to hundreds of metres are evaluated using a hierarchical nested sampling design. The size and epiphyte load of P. oceanica shoots and the nitrogen and phosphorus content of leaves and epiphytes were different in most of the spatial scales considered. Sampling efforts concentrated at the metre scale incorporated most of the variability in size, epiphyte load and nutrient content of the leaves and epiphytes of P. oceanica shoots. Epiphyte load showed no correlation with nutrient content in the epiphytes or in the leaves. However, epiphyte load and shoot size were negatively correlated, which suggests that light penetration in the canopy may be a main determinant of epiphyte load.     

Geochemical Assessment of a Subtropical Reservoir: A Case Study in Curitiba,Southern Brazil

Suspended particles and dissolved substances in water provide reactive surfaces, influence metabolic activity and contribute to the net sediment deposition. It therefore plays an important part in the ecology and quality of the water mass. The water quality in reservoirs is crucial and it is naturally maintained by flushing and sedimentation, which continuously remove phosphorus from the water. In some reservoirs, however, these removal processes are countered by recycling of ions which could play a key role to start and/or maintain the eutrophic state. The combination of macro‐, trace‐ and microanalysis techniques can be useful to trace pollution sources through a chemical fingerprint, whether be during an acute environmental disaster or a long‐term release of pollutants. The water quality and total metal content of reservoir sediments were assessed in a reservoir, situated in the capital of the Paraná State, in the South‐Eastern part of Brazil. The goal of this paper was to determine the metal presence in the sediment and metal and ionic speciation in the Green River reservoir water. Water and bed sediment samples, collected from various sites during 2008 and 2009, were investigated using XRF, ICP‐OES, ICP‐MS, XRD and zeta potential measurements. Based on the results, the heavy metal concentration and chemical composition of the suspended matter in the water samples, as well as the sediment's chemical composition will be discussed.     

Dispersive Liquid–Liquid Microextraction for Preconcentration and Determination of Nickel in Water

A method for the determination of nickel in water was developed. The procedure involves preconcentration of nickel by using dispersive liquid–liquid microextraction. The Ni(II) ions were extracted in chloroform in the form of complex with the reagent 2‐(2′‐benzothiazolylazo)‐p‐cresol. Ethanol was used as the disperser solvent. After injection of the extracting mixture in a solution of nickel, a cloudy mixture was observed. A quick centrifugation induces phase separation and thus the settling of rich phase. The nickel content in the rich phase is measured by flame atomic absorption spectrometry. Under optimal conditions, the limit of detection and quantification obtained were 1.4 and 4.7 µg L^?1, respectively. Some parameters used to characterize preconcentration systems, such as enrichment factor and consumption index were calculated and resulted in 29 and 0.34 mL, respectively. After optimization of variables and determination of analytical characteristics, the method was used for the analysis of certified reference materials (BCR‐713: wastewater, effluent and BCR‐414: plankton) and real water samples.     

Steric and mass-induced Mediterranean sea level trends from 14 years of altimetry data

Long-term series of almost 14 years of altimetry data (1992–2005) have been analysed along with Sea Surface Temperature (SST) and temperature and salinity profiles to investigate sea level trends over the Mediterranean Sea. Although sea level variations are mainly driven by the steric contribution, the mass-induced component plays some role in modulating its oscillation. A spatially averaged positive trend of 2.1 ± 0.6 mm/year has been observed, but a change in sign in 2001 seems to appear. Steric effects (mainly on thermal origin) account for  55% of sea level trend. Although Mediterranean Sea is a semi-enclosed basin, this value is comparable to that reported for the global ocean. Sea level rise is particularly important in the Levantine basin south of Crete with values up to 10 ± 1 mm/year. Other areas of sea level rise are localised throughout the Levantine basin and in the Adriatic and Alboran Seas, with more moderate values. Sea level drop areas are localised in the Algerian basin, between the Balearic Islands and the African coasts and, particularly, in the Ionian basin. In this area, negative trends as high as − 10 ± 0.8 mm/year are detected mainly due to the mass-induced contribution, which suggests decadal changes of surface circulation. The inferred sea level trends have been correlated with North Atlantic Oscillation (NAO) indices and a low but significant correlation has been detected between sea level in the Levantine and Balearic basins and NAO index.     

A regularized fiber element model for reinforced concrete shear walls

Reinforced concrete shear walls are used because they provide high lateral stiffness and resistance to extreme seismic loads. However, with the increase in building height, these walls have become slenderer and hence responsible of carrying larger axial and shear loads. Because 2D/3D finite element inelastic models for walls are still complex and computationally demanding, simplified but accurate and efficient fiber element models are necessary to quickly assess the expected seismic performance of these buildings. A classic fiber element model is modified herein to produce objective results under particular loading conditions of the walls, that is, high axial loads, low axial loads, and nearly constant bending moment. To make it more widely applicable, a shear model based on the modified compression field theory was added to this fiber element. Consequently, this paper shows the formulation of the proposed element and its validation with different experimental results of cyclic tests reported in the literature. It was found that in order to get objective responses in the element, the regularization techniques based on fracture energy had to be modified, and nonlinearities because of buckling and fracture of steel bars, concrete crushing, and strain penetration effects were needed to replicate the experimental cyclic behavior. Thus, even under the assumption of plane sections, which makes the element simple and computationally efficient, the proposed element was able to reproduce the experimental data, and therefore, it can be used to estimate the seismic performance of walls in reinforced concrete buildings. Copyright © 2016 John Wiley & Sons, Ltd.     

Determination of Hydraulic Conductivity from Grain‐Size Distribution for Different Depositional Environments

Over 400 unlithified sediment samples were collected from four different depositional environments in global locations and the grain‐size distribution, porosity, and hydraulic conductivity were measured using standard methods. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations (e.g., Hazen, Carman‐Kozeny) commonly used to estimate hydraulic conductivity from grain‐size distribution. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly to the measured hydraulic conductivity values with errors ranging to over 500%. To improve the empirical estimation methodology, the samples were grouped by depositional environment and subdivided into subgroups based on lithology and mud percentage. The empirical methods were then analyzed to assess which methods best estimated the measured values. Modifications of the empirical equations, including changes to special coefficients and addition of offsets, were made to produce modified equations that considerably improve the hydraulic conductivity estimates from grain size data for beach, dune, offshore marine, and river sediments. Estimated hydraulic conductivity errors were reduced to 6 to 7.1 m/day for the beach subgroups, 3.4 to 7.1 m/day for dune subgroups, and 2.2 to 11 m/day for offshore sediments subgroups. Improvements were made for river environments, but still produced high errors between 13 and 23 m/day.     

Dark matter halo creation in moving barrier models

In hierarchical models of structure formation, the time derivative of the halo mass function may be thought of as the difference of two terms – a creation term, which describes the increase in the number of haloes of mass m from mergers of less massive objects, and a destruction term, which describes the decrease in the number of m -haloes as these merge with other haloes, creating more massive haloes as a result. The first part of this paper focuses on estimating the distribution of times when these creation events take place. In models where haloes form from a spherical collapse, this distribution can be estimated from the same formalism which is used to estimate halo abundances: the constant-barrier excursion-set approach. In the excursion-set approach, moving rather than constant barriers are necessary for estimating halo abundances when the collapse is triaxial. First, we generalize the excursion-set estimate of the creation time distribution by incorporating ellipsoidal collapse. Then, we show that these moving barrier based predictions are in better agreement with measurements in numerical simulations than are the corresponding predictions of the spherical collapse model. In the second part of the paper, we link the creation time distribution to the creation term mentioned above. For this quantity, the improvement provided by the ellipsoidal collapse model is more evident. These results should be useful for studies of merger-driven star formation rates and active galactic nucleus activity. We also present a similar study of the creation of haloes conditioned on belonging to an object of a certain mass today, and reach similar conclusions – the moving barrier based estimates are in substantially better agreement with the simulations. This part of the study may be useful for understanding the tendency for the oldest stars to exist in the most massive objects, and for star formation to only occur in lower mass objects at late times.     

Charmed meson pair production in high-energy pp collisions within the QCD color dipole approach

A study of double-charmed meson production in high-energy proton–proton collisions at the Large Hadron Collider is presented. Considering the color dipole formalism developed in the transverse momentum representation along with the double parton scattering mechanism, predictions are made for the transverse momentum differential cross section for different pairs of -mesons. The theoretical results cover the center-of-mass energy and forward rapidities available by the LHCb experiment. The proton–proton results considering different unintegrated gluon distributions are compared to the respective data collected at the LHC.     

Atmospheric stabilization and the timing of carbon mitigation

Stabilization of atmospheric CO₂ concentrations below a pre-industrial doubling (~550 ppm) is a commonly cited target in climate policy assessment. When the rate at which future emissions can fall is assumed to be fixed, the peak atmospheric concentration – or the stabilization “frontier” – is an increasing and convex function of the length of postponement. Here we find that a decline in emissions of 1% year^?1 beginning today would place the frontier near 475 ppm and that when mitigation is postponed, options disappear (on average) at the rate of ~9 ppm year^?1, meaning that delays of more than a decade will likely preclude stabilization below a doubling. When constraints on the future decline rate of emissions are relaxed, a particular atmospheric target can be realized in many ways, with scenarios that allow longer postponement of emissions reductions requiring greater increases in the intensity of future mitigation. However, the marginal rate of substitution between future mitigation and present delay becomes prohibitively large when the balance is shifted too far toward the future, meaning that some amount of postponement cannot be fully offset by simply increasing the intensity of future mitigation. Consequently, these results suggest that a practical transition path to a given stabilization target in the most commonly cited range can allow, at most, one or two decades of delay.