Distribution and thickness of sedimentary facies in the coastal dune, beach and nearshore sedimentary system at Maspalomas, Canary Islands

Numerous studies have shown that most beaches and coastal dune systems of the world are currently eroding but very few have investigated the combined sediment budgets of subaerial and nearshore submarine systems. In the case of the dune field of the Maspalomas Natural Special Reserve (in the south of Gran Canaria), the adjacent Maspalomas and El Inglés beaches and the adjacent submarine platform, the sediment budgets have been severely affected by erosion over the past few decades. The objectives of this study were to investigate the availability of sand within the modern sedimentary system, including the coastal dunes, the beaches and the submerged shelf, but also to assess local sediment sinks. An isopach map generated on the basis of topo-bathymetric data and seismic-reflection profiles revealed that sediment thickness varies from 0–22 m in the study area. Expanses of relatively low sediment thickness were identified in the south-western sector of the coastal dune field along Maspalomas beach, and in the nearshore region to the south of this beach. These localized sediment-deficit areas earmark Maspalomas beach as the most vulnerable shore strip threatened by erosion. The shallow seismic data also revealed that the submarine platform south of Maspalomas represents a marine terrace cut into an ancient alluvial fan, thus documenting an influence of the geomorphological heritage on the present-day morphodynamics. A side-scan sonar mosaic of this nearshore platform enabled the delimitation of areas covered by rock, boulders and gravel, vegetated sand patches and a mobile sand facies, the latter including ripple and megaripple fields. The megaripple field in a valley close to the talus of the marine terrace has been identified as a major sediment sink of the Maspalomas sedimentary system. It is fed by south-westerly storm-wave events. The sediment deficit in the coastal dune field and along Maspalomas beach can therefore only be explained by a currently faster loss of sediment to an offshore sink than can be compensated by the supply of sand from outside the system.     

Degradation of Monoazo Pigments Red 53:1 and Red 48:2 by Fenton,Photo‐Fenton and UV/Peroxide Reactions

The degradation reactions of two monoazo pigments, namely, Red 53:1 and Red 48:2, by Fenton, photo‐Fenton and UV/H₂O₂ systems have been studied. The efficiencies of the Fenton reactions increased with temperature, but the formation of solid agglomerates was observed when the reactions were carried out above 50°C indicating a coagulant action of Fe⁺² or Fe⁺³. Photo‐Fenton reactions irradiated by sunlight presented the best rate constants for cleavage of the azo bond and the naphthalene rings. The UV/H₂O₂ system exhibited the highest efficiency with respect to the consumption of H₂O₂. The presence of a carbonyl group in the ortho position of the naphthol ring hampered the oxidation of pigment Red 48:2 by hydroxyl radicals. This finding may be explained in terms of the acceptor character of the COOH group, and suggests the formation of a complex containing two six‐membered rings between Fe⁺³ and the pigment molecule.     

Assessment of 80 years of ancient‐badlands restoration in Saldaña,Spain

This paper presents the history of badland generated in the Saldaña region, Spain; as well as the main responses eight decades after the start of restoration – in terms of vegetation, soil and erosive processes. The restoration consisted of intense reforestation and construction of more than 100 check dams and numerous wattle fences. Presently, the dense vegetation (87% cover) contrasts markedly with the degraded landscape from the early 20th century (5% cover). The thickness of litter and the natural presence of some species (Quercus pyrenaica, Paeonia broteroi and Lactarius deliciosus) clearly indicate the recovery of the site. The development of the forest cover shows that the intervention has the potential to recover almost 90% of the area. There is also evidence of soil regeneration, although some properties (erodibility, resistance to penetration and shear‐strength resistance) are not that different between the forested and degraded areas. In the restored zones, runoff is negligible, since a thick layer of moss covers the spillways of all the check dams. Erosion has almost been stopped by the effects of vegetation cover, litter and higher infiltration rates (infiltration rate in forested slopes is 43.4 times greater than in bare slopes). Sediment detachment, such as landslides, mudflows and piping, still occur, but are restricted to the degraded zones. Furthermore, even when sediments are mobilized from the upper degraded hillslopes during the larger storms events (2000–2010), check dams and the lower elevation restored forest‐buffers effectively work to reduce the sediment yield into the Carrión River by almost three orders of magnitude (<10² mg L^‐1), compared with data from the 1930s and 1940s (>10⁵ mg L^‐1). Copyright © 2014 John Wiley & Sons, Ltd.     

Kriging with external drift for functional data for air quality monitoring

Functional data featured by a spatial dependence structure occur in many environmental sciences when curves are observed, for example, along time or along depth. Recently, some methods allowing for the prediction of a curve at an unmonitored site have been developed. However, the existing methods do not allow to include in a model exogenous variables that, for example, bring meteorology information in modeling air pollutant concentrations. In order to introduce exogenous variables, potentially observed as curves as well, we propose to extend the so-called kriging with external drift—or regression kriging—to the case of functional data by means of a three-step procedure involving functional modeling for the trend and spatial interpolation of functional residuals. A cross-validation analysis allows to choose smoothing parameters and a preferable kriging predictor for the functional residuals. Our case study considers daily PM₁₀ concentrations measured from October 2005 to March 2006 by the monitoring network of Piemonte region (Italy), with the trend defined by meteorological time-varying covariates and orographical constant-in-time variables. The performance of the proposed methodology is evaluated by predicting PM₁₀ concentration curves on 10 validation sites, even with simulated realistic datasets on a larger number of spatial sites. In this application the proposed methodology represents an alternative to spatio-temporal modeling but it can be applied more generally to spatially dependent functional data whose domain is not a time interval.     

Magma chamber growth models in the upper crust: A review of the hydraulic and inertial constraints

Finite volumes of magma moving in confinement, store hydraulic potential energy for the generation,control and transmission of power. The Pascal's principle in a hydraulic jack arrangement is used to model the vertical and lateral growth of sills. The small input piston of the hydraulic jack is equivalent to the feeder dike, the upper large expansible piston equivalent to the magmatic chamber and the inertial force of the magma in the dike is the input force. This arrangement is particularly relevant to the case of sills expanding with blunt tips, for which rapid fracture propagation is inhibited. Hydraulic models concur with experimental data that show that lateral expansion of magma into a sill is promoted when the vertical ascent of magma through a feeder dike reaches the bottom contact with an overlying, flat rigid-layer. At this point, the magma is forced to decelerate, triggering a pressure wave through the conduit caused by the continued ascent of magma further down(fluid-hammer effect). This pressure wave can provide overpressure enough to trigger the initial hydraulic lateral expansion of magma into an incipient sill, and still have enough input inertial force left to continue feeding the hydraulic system. The lateral expansion underneath the strong impeding layer, causes an area increase and thus, further hydraulic amplification of the input inertial force on the sides and roof of the incipient sill, triggering further expansion in a self-reinforcing process. Initially, the lateral pressure increase is larger than that in the roof allowing the sill to expand. However, expansion eventually increases the total integrated force on the roof allowing its uplift into either a laccolith, if the roof preserves continuity, or into a piston bounded by a circular set of fractures. Hydraulic models for shallow magmatic chambers, also suggest that laccolith-like intrusions require the existence of a self-supported chamber roof. In contrast, if the roof of magmatic chambers loses the self-supporting capacity, lopoliths and calderas should be expected for more or less dense magmas, respectively, owing to the growing influence of the density contrast between the host rock and the magma.     

Sampling Strategies for Uncertainty Reduction in Categorical Random Fields: Formulation,Mathematical Analysis and Application to Multiple-Point Simulations

Mathematical Geosciences - The task of optimal sampling for the statistical simulation of a discrete random field is addressed from the perspective of minimizing the posterior uncertainty of...     

Treatment of Acid Mine Drainage (AMD) in South Brazil: Comparative active processes and water reuse

This work describes AMD techniques of neutralization, with lime, flocculation of the precipitates and comparative flocs/liquid separation by flotation with microbubbles or by lamellar settling (LS). The AMD treated water was characterized by its quality for recycling in terms of inorganic or organic elements, suspended or dissolved solids, among others. Two types of flocs were formed, “aerated” or not, in a special flocculation reactor, patented by this research group (RGF^®). Aerated flocs formed (within seconds) entered into contact with microbubbles under high shearing and raised-up at rates > 120 mh^− 1 allowing a rapid solid–liquid separation by flotation (HR-high rate), at about 13–15 m³m^− 2 h^− 1 loading capacity. Conversely, the non-aerated flocs settled at about 5–6 m h^− 1 in a lamella settler. Both AMD treatment techniques showed similar efficiencies (removal of ions > 90%) but the separation by lamella settling presented advantages, namely less reagents (no flotation collector required), lower power requirements and easier to operate. The operating costs (approximate values) of the AMD treatment by LS at pH 9 reaches about 0.3 US$ m^− 3 against 0.6 US$ m^− 3 for the HR-flotation process. Results found were proved to be similar to those found in recent ADM treatment installations in South Brazil. The quality of the treated water is fairly good, nearly free of heavy metals ion, low BOD (biological oxygen demand) and TOC (total organic content), low solids content and may be readily reused for irrigation, industrial processes and as wash water (among others, streets, vehicles, dust control). However, there is a need to extend the use of this treated water resource, but this, at least in Brazil, has not been legislated properly. It is concluded that this research will contribute in the discussion of this old and complex problem in acid mining effluents worldwide.     

Organic and inorganic geochemistry of Ljubija siderite deposits,NW Bosnia and Herzegovina

The Ljubija siderite deposits, hosted by a Carboniferous sedimentary complex within the Inner Dinarides, occur as stratabound replacement-type ore bodies in limestone blocks and as siderite–sulfides veins in shale. Three principal types of ore textures have been recognized including massive dark siderite and ankerite, siderite with zebra texture, and siderite veins. The ore and host rocks have been investigated by a combination of inorganic (major, trace, and rare earth element concentrations), organic (characterization of hydrocarbons including biomarkers), and stable isotope geochemical methods (isotope ratios of carbonates, sulfides, sulfates, kerogen, and individual hydrocarbons). New results indicate a marine origin of the host carbonates and a hydrothermal–metasomatic origin of the Fe mineralization. The differences in ore textures (e.g., massive siderite, zebra siderite) are attributed to physicochemical variations (e.g., changes in acidity, temperature, and/or salinity) of the mineralizing fluids and to the succession and intensity of replacement of host limestone. Vein siderite was formed by precipitation from hydrothermal fluids in the late stage of mineralization. The equilibrium fractionation of stable isotopes reveals higher formation temperatures for zebra siderites (around 245°C) then for siderite vein (around 185°C). Sulfur isotope ratios suggest Permian seawater or Permian evaporites as the main sulfur source. Fluid inclusion composition confirms a contribution of the Permian seawater to the mineralizing fluids and accord with a Permian mineralization age. Organic geochemistry data reflect mixing of hydrocarbons at the ore site and support the hydrothermal–metasomatic origin of the Ljubija iron deposits.     

Groundwater overexploitation and soil subsidence monitoring on Recife plain (Brazil)

Facing natural disasters is a priority challenge for cities, exacerbated by increases in urban population and climate change. Improving the resilience of cities is a critical need for the international community and especially for territories exposed to multiple risks, such as Chile. Although disasters are always tragic, the recovery and reconstruction post-disaster may provide a unique opportunity to prevent future suffering, enhancing the resilience of local communities. This paper presents the analysis of two Chilean reconstruction programmes applied in Mehuin and Dichato, after the earthquake and tsunami of 22 May 1960 and 27 February 2010, respectively. In both cases, reconstruction programmes were supported by the Chilean Government, but using different approaches: one focused on providing housing for people injured in the earthquake, while the other also included urban amenities and services. This article proposes an urban morphology analysis framework; in addition, it presents the assessment of the two case studies before and after a disaster, thus evaluating their resilience. By comparing urban morphology resilience pre- and post-disaster, a discussion about the effectiveness of two reconstruction approaches is presented. Finally, conclusions and recommendations to better integrate resilience into urban planning are proposed, with the aim of opening the discussion about how to make cities more resilient to natural disasters.