Origin of siderite mineralisation in Petrova and Trgovska Gora Mts., NW Dinarides

The Petrova and Trgovska Gora Mts. (Gora=Mountain) are Variscan basement units incorporated into the northwestern Dinarides during the Alpine orogeny. They host numerous siderite-quartz-polysulphide, siderite-chalcopyrite, siderite-galena and barite veins, as well as stratabound hydrothermal-replacement ankerite bodies within carbonates in non-metamorphosed, flysch-like Permo-Carboniferous sequences. The deposits have been mined for Cu, Pb, Ag and Fe ores since Medieval times. Fluid inclusion studies of quartz from siderite-polysulphide-quartz and barite veins of both regions have shown the presence of primary aqueous NaCl?CaCl₂±MgCl₂?H₂O±CO₂ inclusions. The quartz-sulphide stage of both regions show variable salinities; 2.7–26.2 wt% NaCl eq. for the Trgovska Gora region and 3.4–23.4 wt% NaCl eq. for the Petrova gora region, and similar homogenisation temperatures (100–230°C). Finally, barite is precipitated from low salinity-low temperature solutions (3.7–15.8 wt % NaCl equ. and 115–145°C). P-t conditions estimated via isochore construction yield formation temperatures between 180–250°C for the quartz-sulphide stage and 160–180°C for the barite stage, using a maximum lithostatic pressure of 1 kbar (cc. 3 km of overburden). The sulphur isotope composition of barite from both deposits indicates the involvement of Permian seawater in ore fluids. This is supported by the elevated bromium content of the fluid inclusion leachates (120–660 ppm in quartz, 420–960 ppm in barite) with respect to the seawater, indicating evaporated seawater as the major portion of the ore-forming fluids. Variable sulphur isotope compositions of galena, pyrite and chalcopyrite, between ?3.2 and +2.7‰, are interpreted as a product of incomplete thermal reduction of the Permian marine sulphate mixed with organically- and pyrite-bound sulphur from the host sedimentary rocks. Ore-forming fluids are interpreted as deep-circulating fluids derived primarily from evaporated Permian seawater and later modified by interaction with the Variscan basement rocks. ⁴⁰Ar/³⁹Ar data of the detrital mica from the host rocks yielded the Variscan age overprinted by an Early Permian tectonothermal event dated at 266–274 Ma. These ages are interpreted as those reflecting hydrothermal activity correlated with an incipient intracontinental rifting in the Tethyan domain. Nevertheless, 75 Ma recorded at a fine-grained sericite sample from the alteration zone is interpreted as a result of later resetting of white mica during Campanian opening/closure of the Sava back arc in the neighbouring Sava suture zone (Ustaszewski et al. 2008).     

Estimation of potential pollution from mine tailings in the San Pedro River (1993–2005), Mexico–US border

The San Pedro River (SPR) is located in northern Sonora (Mexico) and southeastern Arizona (USA). SPR is a transboundary river that develops along the Sonora (Mexico) and Arizona (USA) border, and is considered the main source of water for a variety of users (human settlements, agriculture, livestock, and industry). The SPR originates in the historic Cananea mining area, which hosts some of the most important copper mineralizations in Mexico. Acid mine drainage derived from mine tailings is currently reaching a tributary of the SPR near Cananea City, resulting in the contamination of the SPR with heavy metals and sulfates in water and sediments. This study documents the accumulation and distribution of heavy metals in surface water along a segment of the SPR from 1993 to 2005. Total concentrations of Cd, Cu, Fe, Mn, Pb, and Zn in surface waters are above maximum permissible levels in sampling sites near mine tailing deposits. Nevertheless, a significant decrease in the Fe and SO₄ ²⁻ in surface water (SO₄ ²⁻: 7,180–460.39 mg/L; Fe: 1,600–9.51 mg/L) as well as a gradual decrease in the heavy and transition metal content were observed during the period from 1994 to 2005. Approximately 2.3 km downstream of the mine tailings, the heavy metal content of the water drops quickly following an increase in pH values due to the discharging of wastewater into the river. The attenuation of the heavy metal content in surface waters is related to stream sediment precipitation (accompanied by metal coprecipitation and sorption) and water dilution. Determining the heavy metal concentration led to the conclusion that the Cananea mining area and the San Pedro River are ecosystems that are impacted by the mining industry and by untreated wastewater discharges arising from the city of Cananea (Sonora, Mexico).     

Wind wave climate change: Impacts on the littoral processes at the Northern Buenos Aires Province Coast, Argentina

Several works reported wind-wave climate changes at Buenos Aires Province continental shelf. The aim of this work is to investigate the impact of these changes in the coastal processes of the region. This study is carried out by means of visual wave parameters gathered at the surf zone of Pinamar and by a conveniently implemented and validated numerical wave model (SWAN). Numerical results corresponding to a grid point located 30 km off Pinamar show a significant increase of wave heights from the S and SSE directions and in the frequency of occurrence of waves coming from the S, SSE and E. It is shown that these slight offshore appreciated trends would not have significant effects on the breaker heights observed at the surf zone at Pinamar. On the contrary, the slight positive trend observed offshore in the frequency of occurrence could be affecting the incidence of waves onshore, producing an increase in the number of cases of normal incidence at the surf zone and, consequently, a significant decrease in the alongshore wave energy flux assessed at Pinamar. This reduction in the alongshore wave energy flux could be responsible for some coastal changes detected in the region as, for instance, the remarkable shortening of Punta Rasa spit located 70 km northward Pinamar.     

Generalized extreme wind speed distributions in South America over the Atlantic Ocean region

Statistical analysis of extreme values is applied to wind data from National Centers for Environmental Prediction and National Center for Atmospheric Research reanalysis grid points over the ocean region bounded at 23°S and 40°W and 42°W towards the south and southeastern Brazilian coast. The period of analysis goes from 1975 to 2006. The generalized extreme value and generalized Pareto distributions are employed for annual and daily maxima, respectively. The Pareto?CPoisson point process characterization is also used to analyze peaks over threshold. Return levels for 10, 25, 50, and 100?years are calculated at each grid point. However, most of the reanalysis data fall within 1?C10-year return periods, suggesting that hazardous wind speed with low probability (return periods of 50?C100) have rarely measured in this period. Wide confidence intervals on these levels show that there is not enough information to make predictions with any degree of certainty to return periods over 100?years. Low extremal index (??) values are found for excess wind speeds over a high threshold, indicating the occurrence of consecutively high peaks. In order to obtain realistic uncertainty information concerning inferences associated with threshold excesses, a declustering method is performed, which separates the excesses into clusters, thereby rendering the extreme values more independent.     

On the design and seismic response of RC frame buildings designed with Eurocode 8

Performance-Based Seismic Design is now widely recognized as the pre-eminent seismic design and assessment methodology for building structures. In recognition of this, seismic codes may require that buildings achieve multiple performance objectives such as withstanding moderate, yet frequently occurring earthquakes with minimal structural and non-structural damage, while withstanding severe, but rare earthquakes without collapse and loss of life. These objectives are presumed to be satisfied by some codes if the force-based design procedures are followed. This paper investigates the efficacy of the Eurocode 8 force-based design provisions with respect to RC frame building design and expected seismic performance. Four, eight, and 16-storey moment frame buildings were designed and analyzed using the code modal response spectrum analysis provisions. Non-linear time-history analyses were subsequently performed to determine the simulated seismic response of the structures and to validate the Eurocode 8 force-based designs. The results indicate the design of flexural members in medium-to-long period structures is not significantly influenced by the choice of effective member stiffness; however, calculated interstorey drift demands are significantly affected. This finding was primarily attributed to the code’s enforcement of a minimum spectral ordinate on the design spectrum. Furthermore, design storey forces and interstorey drift demand estimates (and therefore damage), obtained by application of the code force-based design procedure varied substantially from those found through non-linear time-history analysis. Overall, the results suggest that though the Eurocode 8 may yield life-safe designs, the seismic performance of frame buildings of the same type and ductility class can be highly non-uniform.     

First record of a clupeomorph fish in the Neuquén Group (Portezuelo Formation), Upper Cretaceous of Patagonia, Argentina

A new genus and species of clupeomorph fish, Leufuichthys minimus, is described from the fluvial deposits of the Portezuelo Formation, Upper Cretaceous (Turonian-Coniacian) of the Neuquén Group, Patagonia, Argentina. It is a small-sized fish with an estimated body length up to 46 mm. Among other characters, the new species shows the following: abdominal scutes; abdomen moderately convex; anal fin elongate-based; three uroneurals; two epurals; caudal fin bearing very elongate rays; and cycloid scales. Leufuichthys minimus gen. et sp. nov. shows a greater similarity with Kwangoclupea dartevellei, a clupeomorph described from a marine Cenomanian deposit of the Democratic Republic of Congo (Africa), mainly due to the presence of an elongate-based anal fin, bearing more than 20 fin-rays, differing from it by the presence of a not hypertrophied abdomen. As far as known, L. minimus gen. et sp. nov. is the first clupeomorph described in the Upper Cretaceous of Patagonia and represents one fortuitous preservation of an articulated fish in fluvial deposits.     

Evolution of a coastal alluvial deposit in response to the last Quaternary marine transgression, Bahía Blanca estuary, Argentina

The purpose of this research is to analyze the seismostratigraphic and paleoenvironmental features of an ancient fluvial deposit characterized by the presence of paleochannels and sedimentary structures in Bahía Blanca estuary, Argentina. To this end, high-resolution seismic methods were used. Paleochannels exhibiting v-shaped cuts were found at different topographic positions at the base of this deposit. It was observed that channel silting is indicative of the relative change of river base level and the consequent migration of fluvial tributaries. This alluvial deposit is composed of low compacted fine sand and its middle–upper facies is characterized by the presence of horizontal and discontinuous wavy reflectors. The upper boundary of this deposit is an erosive discontinuity resulting from Holocene sea-level rise during which the mouth of old fluvial courses underwent changes. The deposit was subsequently buried by sandy and clayey silt sediments. The paleodrainage at subbottom indicates that this deposit is associated with an ancient river mouth. Based on the seismostratigraphic and lithological characteristics and the paleochannel structures found in the study area, it can be concluded that the deposit analyzed is an alluvial sequence formed in the period from the Middle-Late Pleistocene to Holocene marine transgression.     

Applicability of Newmark method at regional, sub-regional and site scales: seismically induced Bullas and La Paca rock-slide cases (Murcia, SE Spain)

In this paper, the applicability of the Newmark method at regional, sub-regional and site scales has been investigated in the Lorca Basin (Murcia). This basin is located in one of the most seismically active regions of Spain. The area is very interesting for studying earthquake-induced slope instabilities as there are well-known cases associated with specific earthquakes. For the regional and sub-regional scales, a geographic information system has been used to develop an implementation of Newmark sliding rigid block method. Soil and topographic amplification effects have been particularly considered. Subsequently, ‘Newmark displacement’ maps for deterministic seismic scenarios have been produced. Some specific studies have also been performed using limit equilibrium methods to estimate the safety factor and the critical acceleration of certain slope instabilities at a site scale. These instabilities were the rock slides related to recent seismic series at the Lorca Basin: 2002 Bullas (M _w = 5.0) and 2005 La Paca (M _w = 4.8). Finally, the safety factor, critical acceleration and Newmark displacement values estimated at different scales have been compared to determine which scale is most suitable for the Newmark method.