Preuves de la discordance de l'Ordovicien supérieur dans la zone axiale des Pyrénées : exemple du dôme de la Garonne (Espagne,France)

The geological mapping of the Garonne Dome had already shown an angular unconformity between the Upper Ordovician and the underlying series. This paper presents data from a nearby location, Planelh deth Pas Estret, southeast of the Garonne Dome, where the unconformity can be seen at outcrop scale. The unconformity angles amount to up to 20°. This unconformity is interpreted as a result of an extensional event of pre-Upper Ordovician age. To cite this article: J. Garc??a-Sansegundo et al., C. R. Geoscience 336 (2004).     

The applicability and limitations of thermodynamic geochemical models to simulate trace element behaviour in natural waters. Lessons learned from natural analogue studies

Natural analogue investigations aim to understand key phenomena and processes in natural systems related to those expected to occur in radioactive waste repositories. One of the key applications of natural analogue studies has been the possibility to test the geochemical models to be used to describe the migration of radionuclides in a future radioactive waste repository system. To this end, several geochemical modelling testing exercises (commonly denoted as blind predictive modelling, BPM) have formed an integral part of these studies over the last decade.

We have reviewed, discussed and compared the results obtained from geochemical modelling BPM exercises carried out within six natural analogue studies: Poços de Caldas, Cigar Lake, Maqarin, El Berrocal, Oklo and Palmottu. To make this comparison meaningful, we present the main geochemical characteristics of each site in order to highlight the most relevant mineralogical and hydrochemical differences. The elements selected for discussion are: Sr, Ba, Sn, Pb, Se, Ni, Zn, REEs, Th and U. We have based our discussion on the results obtained from the calculated aqueous speciation as well as by comparing solubility calculations with the actually observed concentrations.

Results can be differentiated into two categories of elemental behaviour:

1. those elements like Th and U under reducing conditions that can be fairly well described by assuming solubility control exerted by pure solid phases as their oxyhydroxides;

2. elements such as Sr, Zn, REEs and U under oxidising conditions for which the association to major geochemical components of the system must be considered in order to explain their concentrations in groundwaters.

Additionally, we discuss the main improvements made to the thermodynamic databases and the geochemical calculation methodologies due to the BPM exercises. Furthermore, the most important characterisation geochemical data needed to complete predictive solubility and speciation calculations are identified.     

Flow characteristics of a gravity current induced by differential cooling in a small lake

Extensive field data of a density current driven by the differences in the cooling rates between the two lobes of a small lake are presented. These data illustrate the fact that this gravitational motion affects the whole system and dominates its lakewide circulation. Moreover, data are used to evaluate the entrainment into the density current and also to discuss the regime of the flow from a scaling analysis of the horizontal momentum equations. This analysis is specifically applied to the central area of the lake, where the density current flows from one lobe to the other. Results of this study show that in the longitudinal direction there is a balance between the pressure gradient and the turbulent viscous term. Further, it is found that geostrophy correctly describes the transversal pattern of the passage of the gravity current from the northern lobe to the southern, where it flows confined to the western shoreline.     

The ratio between chrysophycean cysts and diatoms in temperate,mountain lakes: some recommendations for its use in paleolimnology

The ratio between chrysophycean cysts and diatom valves (CD ratio) in lake sediments has been suggested as a useful indicator of changing trophic state conditions in oligotrophic lakes. Other environmental factors, however, may influence the CD ratio because chrysophycean cysts usually reflect conditions in the planktonic environment and diatoms reflect benthic conditions. We investigated the CD ratio in 76 mountain lakes in the Pyrenees to determine the environmental drivers that influence the ratio and assess its value for paleoenvironmental inference. The lakes surveyed included a broad range with respect to bedrock type, altitude and surface area, characteristics that cover much of the variability that can be found in cold, oligotrophic mountain lakes. Lake depth and Ca²⁺ concentration explain most of the variation in the CD ratio. Trophic state factors (e.g. total phosphorus, TP) play a secondary role. As a predictor, CD ratio performs primarily as a lake depth indicator. The predictive models can be improved if trophic state (i.e. TP) and chemical conditions (Ca²⁺) are known or can be estimated independently. Use of the CD ratio for inferring Ca²⁺ oscillations only makes sense in lakes with Ca²⁺ <200 µeq/L or in those that oscillate below and above this threshold through time. Other interpretations of the CD ratio (e.g. lake trophic state changes, ice-cover duration) make sense if complementary paleolimnological evidence indicates that neither water depth nor Ca²⁺ concentration changed significantly. Indeed, paleolimnological interpretation of the CD ratio requires considering the particular characteristics of the lake and may vary depending on the temporal scale considered. This study provides some guidelines for evaluating critically the use of the CD ratio.     

Influence of chemistry on the flux-gradient relationships for the NO-O3-NO2 system

It is shown that K-theory has to be modified for chemical systems that react with time scales similar to the turbulence time scale. In such systems, the value of the exchange coefficient depends not only on the turbulence parameters, but also on the chemical reaction rates. As an example, the NO-O₃-NO₂ chemical system is studied. Using second-moment equations, new flux-gradient relationships for the neutral atmospheric surface layer are obtained which depend on the time scale ratios of turbulence ( _t ) and chemical reactions ( _ch), i.e., reactive K-theory. Within the framework of this reactive K-theory, the flux of a chemical species is both a function of the concentration gradients of the three chemical species involved and of the ratio of the time scale of turbulence to the time scale of chemistry. In the special case of slow chemistry ( _{t ch}) inert K-theory is applicable.The reactive exchange coefficients are implemented in a surface-layer model that calculates the flux and concentration profiles of the three chemical species. The results of the calculations of the effective exchange coefficients are different for reactive K-theory and inert K-theory; the differences are largest for nitric oxide, but smaller for ozone and nitrogen dioxide.     

Free allocation rules in the EU emissions trading system: what does the empirical literature show?

This paper analyses the rules for free allocation in the EU Emissions Trading System (EU ETS). The analysis draws on the empirical evidence emerging from two literature strands. One group of studies sheds light on the following questions: how efficient are free allocation rules in minimizing the risk of carbon leakage? Have they become more efficient over the trading periods? What are the technical limits to making them more efficient? Further: is firm behaviour affected by allowance allocation? Did specific provisions induce strategic behaviour with unintended effects? Studies from the second group estimate sectoral pass-through rates for the costs imposed by the EU ETS. Taking cost pass-through into account is necessary for properly targeting free allocation. The difficulty of accurately quantifying sectoral differences in cost pass-through ability, especially in manufacturing sectors (due to limited data availability and market heterogeneity), is the main hindrance to achieving further efficiency in allowance allocation. The new rules defined in the reform for Phase IV (2021–2030) nevertheless make some progress in this direction.

Key policy insights

• The difficulty of accurately quantifying sectoral differences in cost pass-through ability is the main hindrance to efficient free allocation in minimizing carbon leakage risk.

• In Phase IV (2021–2030), carbon leakage risk will be assessed more accurately thanks to: a) carbon intensity and trade intensity considered together through a combined indicator; b) possible use of more disaggregated data, and c) possible consideration of complementary qualitative assessments of abatement potential, market characteristics and profit margins.

• It is expected that benchmarked allocation introduced in Phase III (2013–2020) has induced additional emission abatement, but there is still a lack of empirical evidence.

     

Evaluation of anthropogenic and biogenic inputs into the western Mediterranean using molecular markers

Aliphatic hydrocarbons (AHs), sterols (ST), and lipid classes were determined in suspended particles collected in the Catalan Sea, northwestern Mediterranean. Principal Component Analysis of the data set revealed a clustering of samples depending on the sources of organic matter, i.e., coastal influenced, open sea and frontal zone. Terrestrial inputs were recognized in particles collected in the surface waters, at the vicinities of river outflow (i.e., Rhône and Ebro), by a predominance of C₂₉ and C₃₁ n-alkanes, 24-ethylcholest-5-en-3β-ol (S12), and the anthropogenic 5β(H)-cholestan-3β-ol, coprostanol (S1). Phytoplanktonic molecular markers (n-C₁₇, 27-nor-24-methylcholesta-5,22E-dien-3β-ol, cholesta-5,22-dien-3β-ol and 24-methylcholest-5-en-3β-ol) were widespread but relatively more apparent in the open sea and frontal zones. A similar distribution was observed for lipid classes, with higher concentrations of phospholipids, and an enrichment in free fatty acids in the areas influenced by river discharges. Total sterol, the unresolved complex mixture of hydrocarbons and the pristane–phytane ratio were highest at a persistent frontal zone, possibly reflecting the combination of a higher primary productivity and fossil hydrocarbon absorption on to suspended particles. Moreover, vertical profiles exhibited a subsurface concentration maximum at 20–30 m water depth, concurrently with the chlorophyll.