Undrained Shear Strength from Field Vane Test on Busan Clay

An unusually thick and soft clay, which is called Busan clay, has been deposited throughout the Nakdong River estuary, South Korea. Although many reclamation works have been carried out in the area since early 1990s, large- and small-scale slope failures have taken place mostly during the soil placement on the clay. A case history briefly describes failure of a breakwater resulting from overestimation of the undrained strength, obtained from laboratory testing. An attempt has been made to examine the methods for determining the undrained strength from field vane testing. For this, the undrained strengths from field vane testing were obtained using different correction factors and compared with each other at five sites in the area. An alternative correction method applicable especially for Busan clay was found, using a range of corrected strength ratios. Further, relationships between the depositional environment and the undrained strength of the clay have also been investigated.     

Uranium isotopes as a tracer of sources of dissolved solutes in the Han River,South Korea

The uranium (U) content and ²³⁴U/²³⁸U activity ratio were determined for water samples collected from Korea's Han River in spring, summer, and winter 2006 to provide data that might constrain the origin of U isotope fractionation in river water and the link between U isotope systematics in river waters and the lithological nature of the corresponding bedrock. The large difference in the major dissolved loads between the two major branches of the Han River, the North Han River (NHR) and South Han River (SHR), is reflected in the contrasting U content and ²³⁴U/²³⁸U activity ratio between the tributaries: low U content (0.08–0.75 nM; average, 0.34 nM) and small ²³⁴U/²³⁸U activity ratio (1.03–1.22; average, 1.09) in the NHR; and high U content (0.65–1.98 nM; average, 1.44 nM) and large ²³⁴U/²³⁸U activity ratio (1.05–1.45; average, 1.24) in the SHR. The large spatial differences in U content and ²³⁴U/²³⁸U activity ratio are closely related to both lithological differences between the two tributaries and groundwater input. The low U content and small ²³⁴U/²³⁸U activity ratio in the NHR arise mainly from a combination of surface and meteoric weathering of the dominant silicate rocks in this branch and congruent dissolution of already weathered (secular equilibrium) materials. In contrast, the high U content and large ²³⁴U/²³⁸U activity ratio in the SHR are ascribed to the dissolution of carbonates and black shales along with significant inputs of deep groundwater.     

Sulfur biogeochemistry and isotopic fractionation in shallow groundwater and sediments of Owens Dry Lake, California

Groundwater and sediment samples (∼ 1 m depth) at sites representative of different groundwater pathways were collected to determine the aqueous speciation of sulfur and the fractionation of sulfur isotopes in aqueous and solid phases. In addition, selected sediment samples at 5 depths (from oxic to anoxic layers) were collected to investigate the processes controlling sulfur biogeochemistry in sedimentary layers. Pyrite was the dominant sulfur-bearing phase in the capillary fringe and groundwater zones where anoxic conditions are found. Low concentrations of pyrite (< 5.9 g kg^− 1) coupled with high concentrations of dissolved sulfide (4.81 to 134.7 mg L^− 1) and low concentrations of dissolved Fe (generally < 1 mg L^− 1) and reducible solid-phase Fe indicate that availability of reactive Fe limits pyrite formation. The relative uniformity of down-core isotopic trends for sulfur-bearing mineral phases in the sedimentary layers suggests that sulfate reduction does not result in significant sulfate depletion in the sediment. Sulfate availability in the deeper sediments may be enhanced by convective vertical mixing between upper and lower sedimentary layers due to evaporative concentration. The large isotope fractionation between dissolved sulfate and sedimentary sulfides at Owens Lake provides evidence for initial fractionation from bacterial sulfate reduction and additional fractionation generated by sulfide oxidation followed by disproportionation of intermediate oxidation state sulfur compounds. The high salinity in the Owens Lake brines may be a factor controlling sulfate reduction and disproportionation in hypersaline conditions and results in relatively constant values for isotope fractionation between dissolved sulfate and total reduced sulfur.     

Geological and Geotechnical Characteristics of Marine Clays at the Busan New Port

Despite a number of geotechnical investigations that have been carried out in the Busan new port area of South Korea, the local practicing engineers have been unable to deduce successfully the geotechnical properties of the clays due to their spatial variation. In the area, clay deposits, so-called Pusan clays, are unusually thick, varying from 20 m to 70 m in thickness. For this study, comprehensive geological and geotechnical investigations were carried out with sophisticated sampling techniques, in situ and laboratory tests as well as geological analyses at an additional three locations. As a result of the investigations, it was found that depositional environments are closely related to the relative changes in sea level and have different features depending on location and depth. The clays consist of soft and stiff clays in the upper and the lower layers, respectively, which are classified as normally consolidated and cemented clay. Moreover, most of the geotechnical properties undergo small changes due to their depositional environment. Information about these effects would be quite helpful to understand the spatial variation of geotechnical properties as well as the effect of sample disturbance. Some correlations which reflect the geological history of the deposts were conducted for physical indexes and mechanical properties.     

Changes in spatial variations of sap flow in Korean pine trees due to environmental factors and their effects on estimates of stand transpiration

It is difficult to scale up measurements of the sap flux density (Js) for the characterization of tree or stand transpiration (E) due to spatial variations in JS and their temporal changes. To assess spatial variations in the sap flux density of Korean pine (Pinus koraiensis) and their effects on E estimates, we measured the Js using Granier-type sensors. Within trees, the Js decreased exponentially with the radial depth, and the Js of the east aspects were higher than those of the west aspects. Among trees, there was a positive relationship between Js and the tree diameter at breast height, and this positive relationship became stronger as the transpiration demand increased. The spatial variations that caused large errors in E estimates (i.e., up to 110.8 % when radial variation was ignored) had varied systematically with environmental factors systematic characteristics in relation to environmental factors. However, changes in these variations did not generate substantial errors in the E estimates. For our study periods, the differences in the daily E (E _D) calculated by ignoring radial, azimuthal and tree-to-tree variations and the measured E _D were fairly constant, especially when the daily vapor pressure deficit (D__D) was higher than 0.6 kPa. These results imply that the effect of spatial variations changes on sap flow can be a minor source of error compared with spatial variations (radial, azimuthal and tree-to-tree variations) when considering E estimates.     

The X-ray pulse profile of BG CMi

We present an analysis of the X-ray data of a magnetic cataclysmic variable, BG CMi, obtained with ROSAT in March 1992 and with ASCA in April 1996. We show that four peaks clearly exist in the X-ray pulse profile, unlike a single peak found in the optical profile. The fluxes of two major pulses are 2–5 times larger than those of two minor pulses. The fraction of the total pulsed flux increases from 51% to 85% with increasing energy in 0.1–2.0 keV, whereas it decreases from 96% to 22% in 0.8–10 keV. We discuss the implications of our findings for the origin of the pulse profile and its energy dependence.     

Understanding the sources of Caribbean precipitation biases in CMIP3 and CMIP5 simulations

We assess the ability of Global Climate Models participating in phases 3 and 5 of the Coupled Model Intercomparison Project (CMIP3 and CMIP5) to simulate observed annual precipitation cycles over the Caribbean. Compared to weather station records and gridded observations, we find that both CMIP3 and CMIP5 models can be grouped into three categories: (1) models that correctly simulate a bimodal distribution with two rainfall maxima in May–June and September–October, punctuated by a mid-summer drought (MSD) in July–August; (2) models that reproduce the MSD and the second precipitation maxima only; and (3) models that simulate only one precipitation maxima, beginning in early summer. These categories appear related to model simulation of the North Atlantic Subtropical High (NASH) and sea surface temperature (SST) in the Caribbean Sea and Gulf of Mexico. Specifically, models in category 2 tend to anticipate the westward expansion of the NASH into the Caribbean in early summer. Early onset of NASH results in strong moisture divergence and MSD-like conditions at the time of the May–June observed precipitation maxima. Models in category 3 tend to have cooler SST across the region, particularly over the central Caribbean and the Gulf of Mexico, as well as a weaker Caribbean low-level jet accompanying a weaker NASH. In these models, observed June-like patterns of moisture convergence in the central Caribbean and the Central America and divergence in the east Caribbean and the Gulf of Mexico persist through September. This analysis suggests systematic biases in model structure may be responsible for biases in observed precipitation variability over the Caribbean and more confidence may be placed in the precipitation simulated by the GCMs that are able to correctly simulate seasonal cycles of SST and NASH.     

Holocene environmental history of a freshwater wetland in southern Louisiana: a sedimentary record of delta development,coastal evolution and human activity

The world's most extensive and active deltas, Louisiana's wetlands, are deteriorating rapidly due to multiple stressors. Their ecological and anthropogenic histories on a multimillennial timescale have not been thoroughly documented. This study investigates hydrological and anthropogenic impacts on southern Louisiana wetlands to guide future efforts toward environmental restoration. A 3.6 m sediment core (JOYWMA) extracted from a freshwater wetland adjacent to Lake Pontchartrain yielded a 5000-year record. Multiproxy data indicate four distinct stages, with the earliest period representing an oyster reef (~4.5 cal yr bp ) marked by elevated Ca and Sr concentrations. Evolution to a freshwater marsh occurred 4.5–4.0 cal yr bp during the St. Bernard delta progradation, marked by increased Zr and Br concentrations. The site transitioned to a lake due to the isolation from the St. Bernard delta and local subsidence (4.0–2.0 cal yr bp ), marked by increased Ti, Fe, Mn and K concentrations. The site altered to a cypress swamp after 2.0 cal yr bp due to increased sediment supply during the St. Bernard subdelta progradation. Both natural (delta progradation and subsidence) and anthropogenic (fire, deforestation) stressors have impacted the site over the last 4500 years. Delta-switching of the Mississippi River caused the significant geomorphological and ecological changes.