Continuous Observation of Groundwater and Crustal Deformation for Forecasting Tonankai and Nankai Earthquakes in Japan

In 2006, we started construction of an observation network of 12 stations in and around Shikoku and the Kii Peninsula to conduct research for forecasting Tonankai and Nankai earthquakes. The purpose of the network is to clarify the mechanism of past preseismic groundwater changes and crustal deformation related to Tonankai and Nankai earthquakes. Construction of the network of 12 stations was completed in January 2009. Work on two stations, Hongu-Mikoshi (HGM) and Ichiura (ICU), was finished earlier and they began observations in 2007. These two stations detected strain changes caused by the slow-slip events on the plate boundary in June 2008, although related changes in groundwater levels were not clearly recognized.     

Deep-learning based projection of change in irrigation water-use under RCP 8.5

Stream water-use is essential for both agricultural and hydrological management and yet not many studies have explored its non-stationarity and nonlinearity with meteorological variables. This study proposed a deep-learning based model to estimate agricultural water withdrawal using hydro-meteorological variables, which projected the changes of agricultural water withdrawal influenced by climate change of future. The relationships between meteorological variables and stream water-use rate (WUR) were quantified using a deep belief network (DBN). The influences of precipitation, potential evapotranspiration, and monthly averaged WUR on the performance of the developed DBN model were tested. As a result, this DBN with potential evapotranspiration (PET) provided better performances than precipitation to estimate the WUR. The PET of multi-model scenarios for Representative Concentration Pathways 8.5 would be increased as time goes by, and thus leads to increase WUR estimated by DBN in three basins, located in South Korea during the future period. On the contrary, water availability expected to decrease compared to the current. Therefore, managing water-uses and improving efficiencies can be prepared for the change in agricultural water-use by climate change in the future.     

A study of igneous rocks related to Zn–Pb mineralization in the Shinyemi and Gagok deposits of the Taebaeksan Basin,South Korea

The Shinyemi and Gagok deposits, located in the Taebaeksan Basin, South Korea, display Zn–Pb mineralization along a contact between Cretaceous granitoids and Cambrian–Ordovician carbonates of the Joseon Supergroup. The Shinyemi mine is one of the largest polymetallic skarn‐type magnetite deposits in South Korea and comprises Fe and Fe–Mo–Zn skarns, and Zn–Cu–Pb replacement deposits. Both deposits yield similar Cretaceous mineralization ages, and granitoids associated with the two deposits displaying similar mineral textures and compositions, are highly evolved, and were emplaced at a shallow depth. They are classified as calc‐alkaline, I‐type granites (magnetite series) and were formed in a volcanic arc. Compositional variation is less in the Shinyemi granites and aplites (e.g., SiO₂ = 74.4–76.6 wt% and 74.4–75.1 wt%, respectively) than in the Gagok granites and aplites (e.g., SiO₂ = 65.6–68.0 wt% and 74.9–76.5 wt%, respectively). Furthermore, SiO₂ vs K/Rb and SiO₂ vs Rb/Sr diagrams indicate that the Shinyemi granitoids are more evolved than the Gagok granitoids. Shinyemi granitoids had been already differentiated highly in deep depth and then intruded into shallow depth, so both granite and aplite show the highly evolved similar chemical compositions. Whereas, less differentiated Gagok granitoids were separated into two phases in the last stage at shallow depth, so granite and aplite show different compositions. The amounts of granites and aplite are similar in the Shinyemi deposit, whereas the aplite appears in an amount less than the granite in the Gagok deposit. For this reason, the Shinyemi granitoids caused not only Fe enrichment during formation of the dolomite‐hosted magnesian skarn but also was associated with Mo mineralization in the Shinyemi deposit. Zn mineralization of the Gagok deposit was mainly caused by granite rather than aplite. Our data suggest that the variation in mineralization displayed by the two deposits resulted from differences in the compositions of their associated igneous intrusions.     

Protective effects of Ecklonia cava extract on the toxicity and oxidative stress induced by hair dye in in-vitro and in-vivo models

Oxidative hair dyes containing p-phenylenediamine(PPD) are reported to induce an allergic reaction by promoting oxidative stress when absorbed through the skin. Despite the associated risk, these hair dyes remain popular owing to their convenience and sharpness of color. This makes it important to minimize the cytotoxicity and oxidative stress induced by PPD-containing hair dyes. Ecklonia cava extract has been evaluated in different studies for its protective effects against external stress in fibroblasts and keratinocytes. Our study was aimed at using in-vitro and in-vivo models to investigate the extract's effects on cytotoxicity of and oxidative stress induced by PPD-containing hair dyes. Analysis of CIEL*a*b* Color space was first used to determine the range of E. cava extract that would not interfere with the coloring ability of the dye upon addition. Subsequently, the set ranges of E. cava extract(5% and 7%) were added to the hair dye and their toxicity assessed by evaluating the viability of fibroblasts and keratinocytes. The effects on developmental phenotypes and induction of oxidative stress by hair dye were evaluated and compared with those of hair dyes containing different contents of E. cava extract using an in-vivo zebrafish model. Our results showed that E. cava extract in hair dye could significantly decrease the cytotoxicity and levels of oxidative stress caused by hair dyes containing PPD in both in-vitro and in-vivo models.These results suggest that the addition of 7% E. cava extract to 250 μg/mL hair dye does not interfere with the coloring ability of the dye while showing significant protective effects against the hair dye. The study proposes that the use of E. cava extract as an adduct to hair dyes containing PPD reduces the cytotoxicity and oxidative stress induced by these hair dyes.     

Spatial variations of small phytoplankton contributions in the Northern Bering Sea and the Southern Chukchi Sea

Phytoplankton size classes (hereafter, PSCs) were derived from satellite ocean color data using a present phytoplankton abundance-based optical algorithm in the northern Bering and southern Chukchi Seas to characterize the spatial and seasonal variations of the different PSC and investigate the contributions of small phytoplankton to the total phytoplankton biomass. The comparison results showed that the phytoplankton abundance-based method approach could reasonably classify the three PSCs (pico-, nano-, and micro phytoplankton). The satellite maps of the dominant PSCs were derived using long-term satellite ocean color data. The general spatial distribution showed that the large (micro-) phytoplankton were dominant in the coastal waters and the west side of the Bering strait, while the small size (nano- or pico-) phytoplankton were dominant in the open ocean waters. Nano- and microphytoplankton were dominant in May and October in most of the study area, while pico-phytoplankton were dominant in the summer months in the open ocean waters. The annual variation in small phytoplankton dominance had a strong positive relationship with the annual mean sea surface temperature (SST), which is consistent with the increasing dominance of small phytoplankton biomass as water temperature increases. Microphytoplankton have an apparent increasing trend in the southeastern Chukchi Sea but slightly decreasing trends in Chirikov and St. Lawrence Island Polynya (SLIP). In contrast, there were increasing trends in picophytoplankton in Chirikov and SLIP, which seems to be related to increasing annual SST. It is crucial to monitor changes in dominant groups of phytoplankton community in the Bering and Chukchi Seas as important biological hotspots responding to the recent changes in environmental conditions.     

Gas hydrates in the western deep-water Ulleung Basin, East Sea of Korea

Geophysical surveys and geological studies of gas hydrates in the western deep-water Ulleung Basin of the East Sea off the east coast of Korea have been carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM) since 2000. The work included a grid of 4782 km of 2D multi-channel seismic reflection lines and 11 piston cores 5–8 m long. In the piston cores, cracks generally parallel to bedding suggest significant in-situ gas. The cores showed high amounts of total organic carbon (TOC), and from the southern study area showed high residual hydrocarbon gas concentrations. The lack of higher hydrocarbons and the carbon isotope ratios indicate that the methane is primarily biogenic. The seismic data show areas of bottom-simulating reflectors (BSRs) that are associated with gas hydrates and underlying free gas. An important observation is the numerous seismic blanking zones up to 2 km across that probably reflect widespread fluid and gas venting and that are inferred to contain substantial gas hydrate. Some of the important results are: (1) BSRs are widespread, although most have low amplitudes; (2) increased P-wave velocities above some BSRs suggest distributed low to moderate concentration gas hydrate whereas a velocity decrease below the BSR suggests free gas; (3) the blanking zones are often associated with upbowing of sedimentary bedding reflectors in time sections that has been interpreted at least in part due to velocity pull-up produced by high-velocity gas hydrate. High gas hydrate concentrations are also inferred in several examples where high interval velocities are resolved within the blanking zones. Recently, gas hydrate recoveries by the piston coring and deep-drilling in 2007 support the interpretation of substantial gas hydrate in many of these structures.     

Physiological and biochemical responses of <Emphasis Type="Italic">Prorocentrum minimum</Emphasis> to high light stress

Prorocentrum minimum is a common bloomforming photosynthetic dinoflagellate found along the southern coast of Korea. To investigate the adaptive responses of P. minimum to high light stress, we measured growth rate, and generation of reactive oxidative species (ROS), superoxide dismutase (SOD), catalase (CAT), and malondialdehyde (MDA) in cultures exposed to normal (NL) and high light levels (HL). The results showed that HL (800 μmol m^?2 s^?1) inhibited growth of P. minimum, with maximal inhibition after 7–9 days. HL also increased the amount of ROS and MDA, suggesting that HL stress leads to oxidative damage and lipid peroxidation in this species. Under HL, we first detected superoxide on day 4 and H₂O₂ on day 5. We also detected SOD activity on day 5 and CAT activity on day 6. The level of lipid peroxidation, an indicator of cell death, was high on day 8. Addition of diphenyleneiodonium (DPI), an NAD(P)H inhibitor, decreased the levels of superoxide generation and lipid peroxidation. Our results indicate that the production of ROS which results from HL stress in P. minimum also induces antioxidative enzymes that counteract oxidative damage and allow P. minimum to survive.     

Stability Assessment of a Pit Slope Under Blast Loading: A Case Study of Pasir Coal Mine

In Pasir mine, coal seams and host rocks of varying thickness have been uniquely deposited with an average dip angle of 85°. The host rocks are weak and mainly composed of mudstone and sandstone comprising of 90–95% of the total pit volume. The thickness of coal seams and host rocks ranges from sub-metric to few tenths of meter. The overall safe pit slope angle was evaluated to be 27° for mining depth of 50–150 m. Several slopes failure incidents have occurred in the mine causing considerable disruption in production and monetary loss. It is envisaged that slope failures may be triggered due to blasting conducted in steeply dipping stratified deposit. In order to investigate the causes of slope failures, peak particle velocity (PPV) and accelerations at various locations from the blast site have been measured. In addition, finite element models of pit slope have been analyzed by applying static or gravity loading as well as blasting or dynamic loading. This paper elaborates the results of in situ measurements of ground vibration and numerical investigation and suggests possible causes of slope failures in Pasir mine.