黑龙江嘉荫地区白垩纪-第三纪界线初步观察

本文报道了黑龙江嘉荫白山头地区一条新的地层剖面及其K／T界线的初步研究。新命名的“白山头段”代表乌云组下部的早古新世地层,含以Tiliaephyllum tsagajanicum等为代表的达宁早期植物化石。在白山头剖面上,作者发现可能为白垩纪末期的凝灰岩。结合与俄罗斯布列亚盆地含K／T界线的查加扬群标准剖面的对比,推测嘉荫地区的K／T界线可能位于白山头段底部与上述凝灰岩之上的一层炭质泥岩之间。     

Iron isotopes constrain biologic and abiologic processes in banded iron formation genesis

The voluminous 2.5 Ga banded iron formations (BIFs) from the Hamersley Basin (Australia) and Transvaal Craton (South Africa) record an extensive period of Fe redox cycling. The major Fe-bearing minerals in the Hamersley-Transvaal BIFs, magnetite and siderite, did not form in Fe isotope equilibrium, but instead reflect distinct formation pathways. The near-zero average δ⁵⁶Fe values for magnetite record a strong inheritance from Fe³⁺ oxide/hydroxide precursors that formed in the upper water column through complete or near-complete oxidation. Transformation of the Fe³⁺ oxide/hydroxide precursors to magnetite occurred through several diagenetic processes that produced a range of δ⁵⁶Fe values: (1) addition of marine hydrothermal , (2) complete reduction by bacterial dissimilatory iron reduction (DIR), and (3) interaction with excess that had low δ⁵⁶Fe values and was produced by DIR. Most siderite has slightly negative δ⁵⁶Fe values of ∼ −0.5‰ that indicate equilibrium with Late Archean seawater, although some very negative δ⁵⁶Fe values may record DIR. Support for an important role of DIR in siderite formation in BIFs comes from previously published C isotope data on siderite, which may be explained as a mixture of C from bacterial and seawater sources.Several factors likely contributed to the important role that DIR played in BIF formation, including high rates of ferric oxide/hydroxide formation in the upper water column, delivery of organic carbon produced by photosynthesis, and low clastic input. We infer that DIR-driven Fe redox cycling was much more important at this time than in modern marine systems. The low pyrite contents of magnetite- and siderite-facies BIFs suggests that bacterial sulfate reduction was minor, at least in the environments of BIF formation, and the absence of sulfide was important in preserving magnetite and siderite in the BIFs, minerals that are poorly preserved in the modern marine record. The paucity of negative δ⁵⁶Fe values in older (Early Archean) and younger (Early Proterozoic) BIFs suggests that the extensive 2.5 Ga Hamersley-Transvaal BIFs may record a period of maximum expansion of DIR in Earth’s history.     

Microbial mass-dependent fractionation of chromium isotopes

Mass-dependent fractionation of Cr isotopes occurs during dissimilatory Cr(VI) reduction by Shewanella oneidensis strain MR-1. Cells suspended in a simple buffer solution, with various concentrations of lactate or formate added as electron donor, reduced 5 or 10 μM Cr(VI) to Cr(III) over days to weeks. In all nine batch experiments, ⁵³Cr/⁵²Cr ratios of the unreacted Cr(VI) increased as reduction proceeded. In eight experiments covering a range of added donor concentrations up to 100 μM, isotopic fractionation factors were nearly invariant, ranging from 1.0040 to 1.0045, with a mean value somewhat larger than that previously reported for abiotic Cr(VI) reduction (1.0034). One experiment containing much greater donor concentration (10 mM lactate) reduced Cr(VI) much faster and exhibited a lesser fractionation factor (1.0018). These results indicate that ⁵³Cr/⁵²Cr measurements should be effective as indicators of Cr(VI) reduction, either bacterial or abiotic. However, variability in the fractionation factor is poorly constrained and should be studied for a variety of microbial and abiotic reduction pathways.     

Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes: A review

An overview is presented on possible mechanisms that control the leaching behaviour of the oxyanion forming elements As, Cr, Mo, Sb, Se, V and W in cementituous systems and alkaline solid wastes, such as municipal solid waste incinerator bottom ash, fly ash and air pollution control residues, coal fly ash and metallurgical slags. Although the leachability of these elements generally depends on their redox state, speciation measurements are not common. Therefore, experimental observations available in the literature are combined with a summary of the thermal behaviour of these elements to assess possible redox states in freshly produced alkaline wastes, given their origin at high temperature. Possible redox reactions occurring at room temperature, on the other hand, are reviewed because these may alter the initial redox state in alkaline wastes and their leachates. In many cases, precipitation of oxyanions as a pure metalate cannot provide a satisfactory explanation for their leaching behaviour. It is therefore highly likely that adsorption and solid solution formation with common minerals in alkaline waste and cement reduce the leachate concentration of oxyanions below pure-phase solubility.     

Deposition and preservation of fluvio-tidal shallow-marine sandstones: A re-evaluation of the Neoproterozoic Jura Quartzite (western Scotland)

The 2 to 5 km thick, sandstone-dominated (>90%) Jura Quartzite is an extreme example of a mature Neoproterozoic sandstone, previously interpreted as a tide-influenced shelf deposit and herein re-interpreted within a fluvio-tidal deltaic depositional model. Three issues are addressed: (i) evidence for the re-interpretation from tidal shelf to tidal delta; (ii) reasons for vertical facies uniformity; and (iii) sand supply mechanisms to form thick tidal-shelf sandstones. The predominant facies (compound cross-bedded, coarse-grained sandstones) represents the lower parts of metres to tens of metres high, transverse fluvio-tidal bedforms with superimposed smaller bedforms. Ubiquitous erosional surfaces, some with granule–pebble lags, record erosion of the upper parts of those bedforms. There was selective preservation of the higher energy, topographically-lower, parts of channel-bar systems. Strongly asymmetrical, bimodal, palaeocurrents are interpreted as due to associated selective preservation of fluvially-enhanced ebb tidal currents. Finer-grained facies are scarce, due largely to suspended sediment bypass. They record deposition in lower-energy environments, including channel mouth bars, between and down depositional-dip of higher energy fluvio-ebb tidal bars. The lack of wave-formed sedimentary structures and low continuity of mudstone and sandstone interbeds, support deposition in a non-shelf setting. Hence, a sand-rich, fluvial–tidal, current-dominated, largely sub-tidal, delta setting is proposed. This new interpretation avoids the problem of transporting large amounts of coarse sand to a shelf. Facies uniformity and vertical stacking are likely due to sediment oversupply and bypass rather than balanced sediment supply and subsidence rates. However, facies evidence of relative sea level changes is difficult to recognise, which is attributed to: (i) the areally extensive and polygenetic nature of the preserved facies, and (ii) a large stored sediment buffer that dampened response to relative sea-level and/or sediment supply changes. Consideration of preservation bias towards high-energy deposits may be more generally relevant, especially to thick Neoproterozoic and Lower Palaeozoic marine sandstones.     

Place and people: spatializing degrees of bonding and bridging social capital in Lisbon (Portugal)

GeoJournal - Broad academic interest in measuring social relationships within an urban context has grown over recent decades. Significant research attention is focused on where social synergies...     

New constraints on granulite facies metamorphism and melt production in the Lewisian Complex,northwest Scotland

In this study, we investigate the metamorphic history of the Assynt and Gruinard blocks of the Archean Lewisian Complex, northwest Scotland, which are considered by some to represent discrete crustal terranes. For samples of mafic and intermediate rocks, phase diagrams were constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCKFMASHTO) system using whole‐rock compositions. Our results indicate that all samples equilibrated at similar peak metamorphic conditions of ~8–10 kbar and ~900–1,000°C, consistent with field evidence for in situ partial melting and the classic interpretation of the central region of the Lewisian Complex as representing a single crustal block. Melt‐reintegration modelling was employed in order to estimate probable protolith compositions. Phase equilibria calculated for these modelled undepleted precursors match well with those determined for a subsolidus amphibolite from Gairloch in the southern region of the Lewisian Complex. Both subsolidus lithologies exhibit similar phase relations and potential melt fertility, with both expected to produce orthopyroxene‐bearing hornblende granulites, with or without garnet, at the conditions inferred for the Badcallian metamorphic peak. For fully hydrated protoliths, prograde melting is predicted to first occur at ~620°C and ~9.5 kbar, with up to 45% partial melt predicted to form at peak conditions in a closed‐system environment. Partial melts calculated for both compositions between 610 and 1,050°C are mostly trondhjemitic. Although the melt‐reintegrated granulite is predicted to produce more potassic (granitic) melts at ~700–900°C, the modelled melts are consistent with the measured compositions of felsic sheets from the central region Lewisian Complex.     

Electrical resistivity mapping of oil spills in a coastal environment of Lagos,Nigeria

Three years after the oil spillage and pipeline explosion that claimed about 100 human lives at Ijegun Community of Lagos–Nigeria, a combination of carefully designed 2D Electrical Resistivity Profilling and Vertical Electrical Sounding methods was deployed to map and characterise the subsurface around the contaminated site. Data acquired were processed, forward modelled and tomographically inverted to obtain the multi-dimensional resistivity distribution of subsurface. The results of the study revealed high resistivity structures that indocate the presence of contaminant (oil plumes) of different sizes and shapes around the oil leakage site. These high resistivity structures are absent in the tomograms and resistivity-depth slices computed for Iyana—a linear settlement not affected by oil spillage. The five geo-electric layers and the resistivities delineated in the area are the top soil layer, 220–670 Ωm; clayey sand layer, 300–1072 Ωm; top sand layer, 120–328 Ωm; mudstone/shale layer, 25–116 Ωm and the bottom sand layer, 15–69 Ωm. The base of the first four geo-electric layers corresponds to 3.9, 8.4, 27.2 and 34.6 m respectively. The two groundwater aquifers delineated correspond to the third and fifth geo-electric layers. The top aquifer has been infiltrated by oil plumes. The depth penetrated by the oil plume decreases from 32 m to about 24 m across the survey profiles from the two ends. It was concluded that the contaminant plumes from the oil spillage are yet to be completely degraded as at the time of the study. It is recommended that the contaminated site be remediated to remove or reduce the contaminant oil in the subsurface.     

Grampian migmatites in the Buchan Block,NE Scotland

Rocks exposed along the Scottish coast between Fraserburgh and Inzie Head contain information critical to understanding the evolution of the Buchan Block, the type locality for low‐P, high‐T regional metamorphism, and its relationship with the rest of the Grampian terrane, one of the major tectonostratigraphic components of the Scottish Caledonides. The ~8 km long section traverses a regional network of shear zones and, at the highest grades around Inzie Head, passes into the core of the Buchan Anticline, a large‐scale open fold that is commonly regarded as a late structure, post‐dating metamorphism. The metasedimentary rocks increase in grade from upper amphibolite to granulite facies and preserve unequivocal evidence for partial melting. The diatexite migmatites around Inzie Head, along with other gneissose units within the Buchan Block, have been regarded as allochthonous Precambrian basement rocks that were thrust into their current position during the Grampian orogenesis. However, field observations show that the onset of in situ partial melting in metapelitic rocks, which was associated with the formation of garnet‐bearing aplites and associated pegmatites, occurred around Fraserburgh, where shear fabrics are absent. Thus, the rocks preserve a continuous metamorphic field gradient that straddles the shear zone network. This observation supports an alternative interpretation that anatexis was the result of mid‐Ordovician (Grampian) metamorphism, rather than an older tectonothermal event, and that the Inzie Head gneisses are autochthonous. Using an average mid‐Dalradian pelite as a plausible representative protolith, phase equilibria modelling satisfactorily reproduces the observed appearance and disappearance of key minerals providing that peritectic garnet produced with the first formed melts (represented by the garnet‐bearing aplites) depleted the source rocks in Mn. The modelled metamorphic field gradient records a temperature increase of at least 150 °C (from ~650 °C near Fraserburgh to in excess of 800 °C at Inzie Head) but is isobaric at pressures of 2.7–2.8 kbar, suggesting the Buchan Anticline developed synchronous with partial melting. The Buchan Anticline is likely an expression of crustal thinning and asthenospheric upwelling, which produced voluminous gabbroic intrusions that supplied the heat for Buchan metamorphism.     

The bedrock topography of the botany basin,New South Wales

The bedrock topography of the Botany Basin has been determined from seismic‐sparker records made in Botany Bay and Bate Bay, and from seismic‐refraction and gravity measurements on the Kurnell Peninsula. Supplementary information has been obtained from boreholes both on land and in the sea.

The Cooks and Georges Rivers formerly constituted the main drainage of the Basin and flowed generally southeastwards (beneath the present Kurnell Peninsula) and joined the Port Hacking River east of Cronulla. The depth of the bedrock channel of the former Georges River is 75–80 m b.s.l. at Taren Point, 90–95 m beneath the Kurnell Peninsula and 110–115 m at its junction with the Port Hacking River channel. The bedrock channel of the former Cooks River is about 30 m b.s.l. at Kyeemagh, its present entrance to Botany Bay, and it joined the Georges River at a location now 90 m b.s.l. beneath the Kurnell Peninsula.

A second drainage system existed in the north and east of Botany Bay and generated the present mouth beneath which the bedrock is now 110 m b.s.l. This channel followed a southeasterly course parallel to the present northern shore of Botany Bay and was separated from that of the ‘Cooks and Georges Rivers’ by a bedrock ridge which extended from beneath Sydney Airport to the northern extremity of the Kurnell Peninsula. Over much of its length this divide had a depth of about 30 m b.s.l.

The formation of the Kurnell Peninsula tombolo led to the diversion of the ‘Cooks/Georges River’ through the mouth of Botany Bay and subsequently led to the development of the bay. This change in the drainage system occurred when the sea was less than 30 m below the present sea level.