Metals,arsenic, and sulfur in the Aue and Eibenstock granites,Erzgebirge

Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola, the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO _Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with a KO _Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively. The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition above the cupola in the ore veins of the Schlema and Schneeberg deposits. Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp. 967–982.     

Biofacies of Upper Jurassic and Lower Cretaceous sediments of central West Siberia

Paleontological study of Upper Jurassic and Lower Cretaceous sediments recovered by boreholes in the Agan-Vakh and Nadym-Vengapur interfluves clarified environments of their deposition. As is shown, influx of siliciclastic material to central areas of the West Siberian sea basin varied through time. Taxonomic composition and ecological structure of nektonic and benthic fossil assemblages are analyzed and considered in terms of environmental factors such as hydrodynamics, aeration, temperature, and salinity of seawater.     

The changing role of hydrogeology in semi-arid southern and eastern Africa

Much of southern and eastern Africa is semi-arid and heavily groundwater dependent. Borehole drilling commenced over a hundred years ago with magnetic and electrical resistivity surveys for borehole siting being introduced from 1936. Formalised training of hydrogeologists led in the 1970s to an almost standard approach to hydrogeological investigation and a period of stability followed, during which some major investigations were carried out. A period of decentralisation and fragmentation has since taken place in many parts of southern and eastern Africa, and groundwater monitoring and management are inadequate in many countries. All but six of the 14 SADC (Southern African Development Community) member states reportedly have an adequate monitoring network in place. However, groundwater demand is increasing and hydrogeologists need to promote the use of appropriate methodologies as an essential part of tackling the severe issues now facing the water sector in the region.     

Geochemistry and origin of the ore-forming fluids in hydrothermal-magmatic systems in tectonically active zones

Data on fluid inclusions and stable isotope compositions (O, H, C, and S) in minerals have been summarized for large-and middle-scale mesothermal gold deposits (Nezhdaninsk, Berezovsk, Kochkar’, Svetlinsk, Darasun, and Maisk), cassiterite-silicate-sulfide deposits of Sikhote Alin (Solnechnoe, Arsen’evsk, and Vysokogorsk), vein silver-base metal deposits in the Southern Verkhoyansk region (Prognoz and Kupol’noe), and epithermal copper-bismuth-silver-base metal deposits of the Karamazar district in Tajikistan (Kanimansur, Tary Ekan, and Zambarak). It is shown that ores precipitated from fluids with salinity varying from brines (up to 60 wt % NaCl equiv) to dilute fluids (1–3 wt % NaCl equiv). As a rule, fluids of different compositions entered the hydrothermal-magmatic system. A fluid mixture of H₂O-CO₂-NaCl±CH₄±N₂ predominated in the orogenic (mesothermal) gold-bearing hydrothermal systems, with deposition of the final-stage gold-bearing sulfosalts from aqueous-salt fluid. Brines played a significant role in the formation of cassiterite-silicate-sulfide and vein silver-base metal deposits. The brines often coexisted with a low-density vapor-rich fluid at the ore deposition site. The obtained data suggest a predominant magmatic component in the hydrothermal-magmatic systems, with a significant contribution of meteoric waters.     

Detection of spectral variability of the optical component of the IR source IRAS 20508+2011

Our high-resolution spectral observations have revealed variability of the optical spectrum of the cool star identified with the IR source IRAS 20508+2011. We measured the equivalent widths of numerous absorption lines of neutral atoms and ions at wavelengths 4300–7930 Å, along with the corresponding radial velocities. Over the four years of our observations, the radial velocity derived from photospheric absorption lines varied in the interval V _r⊙ = 15–30 km/s. In the same period, the Hα profile varied from being an intense bell-shaped emission line with a small amount of core absorption to displaying two-peaked emission with a central absorption feature below the continuum level. At all but one epoch, the positions of the metallic photospheric lines were systematically shifted relative to the Hα emission: ΔV _r = V _r(met) ? V _r(Hα, emis) ≈ ?23 km/s. The Na D doublet displayed a complex profile with broad (half-width ≈ 120 km/s) emission and photospheric absorption, as well as an interstellar component. We used model atmospheres to determine the physical parameters and chemical composition of the star’s atmosphere: T _eff = 4800 K, log g = 1.5, ξ_t = 4.0 km/s. The metallicity of the star differs little from the solar value: [Fe/H]_⊙ = ?0.36. We detected overabundances of oxygen [O/Fe]_⊙ = +1.79 (with the ratio [C/O] ≈ ?0.9), and α-process elements, as well as a deficit of heavy metals. The entire set of the star’s parameters suggests that the optical component of IRAS 20508+2011 is an “O-rich” AGB star with luminosity M _v ≈ ?3^m that is close to its evolutionary transition to the post-AGB stage.     

Isotopic signatures of deposition and transformation of Lower Cambrian saliferous rocks in the Irkutsk Amphitheater: Communication 3. Carbon and oxygen isotopic compositions in carbonates

In previous communications based on the study of sulfur and strontium, we showed that Lower Cambrian rocks of the Irkutsk Amphitheater underwent a significant epigenetic transformation. All postsedimentary alterations of rocks are related to the influence of water solutions that provoke the direct (physical) dissolution of material and its chemical transformation. In particular, an appreciable portion of anhydrites disappeared from the section due to reduction. Probably, these processes took place several times in the past and they are continuing at present. A similar conclusion was deduced from the strontium isotopic composition of carbonate rocks. Their strontium isotopic composition is usually shifted relative to the primary composition, although the prevalence of sulfate and carbonate rocks in the section promotes the stability of strontium isotopic composition with respect to secondary alterations. The carbon isotope system is even more stable due to the abundance of carbonate rocks in the section. This circumstance is probably responsible for the incapacity of isotope data to serve as obvious evidence of the epigenetic transformation of carbonates. The major elements of the evolution of carbon isotope signature could be retained since the sedimentation stage.