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811.
812.
Richard B. Wheeler John B. Anderson Rudy R. Schwarzer Claudia L. Hokanson 《Environmental Geology》1980,3(3):163-175
Sediments are the ultimate sink for contaminants in the marine environment, and physical processes of sedimentation influence
the distribution and accumulation of these contaminants. Evaluation of contaminant levels in sediments is one approach to
assessing environmental impact; data interpretation depends on consideration of sediment texture and mineralogy, however,
which profoundly influence chemical composition. In this study, comparison of potentially contaminated sediments from the
production field with control populations was done only within the context of similar (as to texture and organic carbon and
carbonate content) sample groups as determined by cluster analysis. Ba, Cd, and Sr are identified as contaminants. Supported
by the identification of a well-crystallized expandable clay—possibly bentonite—drilling fluids are a potential source of
Ba. Ba and Sr may be unnaturally high because of their abundance in discharged produced formation waters, but may also be
naturally controlled by the unique faunal assemblage associated with the structures. Cd is probably derived from corrosion
of the structures and assorted debris on the seafloor. In general, contamination is limited to an area within 100 m of the
platforms. Furthermore, substantial erosion around platforms has probably effectively removed and dispersed the bulk of the
contaminants introduced into the marine environment by the offshore exploration/production operations. 相似文献
813.
William A. Bassett John M. Bird Maura S. Weathers D.L. Kohlstedt 《Physics of the Earth and Planetary Interiors》1980,23(4):255-261
Josephinite, a complex, metal-bearing rock from the region of the Josephine Peridotite in southwest Oregon, contains FeNiCo metal alloy phases having exsolution textures. Scanning and transmission electron microscopy have revealed Widmanstaetten patterns in which the lamellae are polysynthetically twinned, ordered, face-centered-cubic FeNi3 surrounded by untwinned, ordered, face-centered-cubic FeNi3 and body-centered-cubic FeCo. These exsolution textures require a temperature in excess of 500°C for their formation. This is consistent with a mantle derivation of josephinite prior to obduction of the peridotite in one of the Klamath ophiolites. 相似文献
814.
Rare earth element distribution in some hydrothermal minerals: evidence for crystallographic control 总被引:1,自引:0,他引:1
Rare earth element (REE) abundances were measured by neutron activation analysis in anhydrite (CaSO4), barite (BaSO4), siderite (FeCO3) and galena (PbS). A simple crystal-chemical model qualitatively describes the relative affinities for REE substitution in anhydrite, barite, and siderite. When normalized to ‘crustal’ abundances (as an approximation to the hydrothermal fluid REE pattern), log REE abundance is a surprisingly linear function of (ionic radius of major cation—ionic radius of REE)2 for the three hydrothermal minerals, individually and collectively. An important exception, however, is Eu, which is anomalously enriched in barite and depleted in siderite relative to REE of neighboring atomic number and trivalent ionic radius. In principle, REE analyses of suitable pairs of co-existing hydrothermal minerals, combined with appropriate experimental data, could yield both the REE content and the temperature of the parental hydrothermal fluid.The REE have only very weak chalcophilic tendencies, and this is reflected by the very low abundances in galena—La, 0.6 ppb; Sm, 0.06 ppb; the remainder are below detection limits. 相似文献
815.
Chemical equilibrium between sodium-aluminum silicate minerals and chloride bearing fluid has been experimentally determined in the range 500–700°C at 1 kbar, using rapid-quench hydrothermal methods and two modifications of the Ag + AgCl acid buffer technique. The temperature dependence of the thermodynamic equilibrium constant (K) for the reaction Albite Andalusite Qtz. can be described by the following equation: log k = ?4.437 + 5205.6/T(K) The data from this study are consistent with experimental results reported by Montoya and Hemley (1975) for lower temperature equilibria defined by the assemblages albite + paragonite + quartz + fluid and paragonite + andalusite + quartz + fluid. Values of the equilibrium constants for the above reactions were used to estimate the difference in Gibbs free energy of formation between NaClo and HClo in the range 400–700°C and 1–2 kbar. Similar calculations using data from phase equilibrium studies reported in the literature were made to determine the difference in Gibbs free energy of formation between KClo and HClo. These data permit modelling of the chemical interaction between muscovite + kspar + paragonite + albite + quartz assemblages and chloride-bearing hydrothermal fluids. 相似文献
816.
Swan Island is a Honduran possession in the western Caribbean, located on the southeastern side of the Cayman Trench. Two sedimentary assemblages are found on the island: an older bedded sequence of mid-Tertiary age (Aquitanian or Burdigalian) and a younger sedimentary sequence of Late Pleistocene age. The older sequence is composed of a series of calcarenites, calcilutites, and siliciclastic mudstones; capping these are cliff-forming reefal carbonates of the younger sequence.The rocks of the older bedded sequence accumulated in deep water. Sedimentation consisted of a constant rain of pyroclastic debris interrupted by the episodic introduction of upslope carbonate material by turbidity currents. Uplift and deformation of this sequence was initiated sometime after the Early Miocene. By the Late Pleistocene, uplift had brought the rocks into water depths conducive to coral growth. Pleistocene sedimentation on the island was controlled by the interaction between tectonic uplift and eustatic sea-level changes. The primary controlling force on the tectonic history of the island is its proximity to the boundary between the North American and Caribbean plates. 相似文献
817.
Massive, nearly holocrystalline dolerites from DSDP Hole 417D contain from 0.5 to 1.5% of granophyric patches composed mainly of Na-plagioclase and quartz. These patches are compositionally similar to other crystalline silicic rocks from oceanic spreading centers and differ from rarer abyssal silicic glasses. Crystalline varieties withSiO260wt.% generally haveNa/K>10, whereas silicic glasses have Na/K in the range 3–6. While crystal fractionation readily accounts for the Na2O and K2O contents of abyssal silicic glasses, both the 417D granophyres and other crystalline abyssal silicic rocks have much lower K2O than that predicted by any reasonable crystal-liquid fractionation model. We propose that high-temperature vapor phase transport is responsible for removal of potassium during late-stage crystallization of these rocks. This allows for the formation of cogenetic silicic glassy and crystalline rocks with greatly different Na/K ratios. These observations and interpretations lead to a more confident assignment of high Na/K silicic rocks of oceanic and ophiolitic environments to a cogenetic origin with basaltic oceanic crust. 相似文献
818.
John Logan Member NWWA 《Ground water》1964,2(1):35-37
819.
Paul N. Swarztrauber David L. Williamson John B. Drake 《Dynamics of Atmospheres and Oceans》1998,27(1-4)
Cartesian coordinates are used to solve the nonlinear shallow-water equations on the sphere. The two-dimensional equations, in spherical coordinates, are first embedded in a three-dimensional system in a manner that preserves solutions of the two-dimensional system. That is, solutions of the three-dimensional system, with appropriate initial conditions, also solve the two-dimensional system on the surface of the sphere. The higher dimensional system is then transformed to Cartesian coordinates. Computations are limited to the surface of the sphere by projecting the equations, gradients, and solution onto the surface. The projected gradients are approximated by a weighted sum of function values on a neighboring stencil. The weights are determined by collocation using the spherical harmonics in trivariate polynomial form. That is, the weights are computed from the requirement that the projected gradients are near exact for a small set of spherical harmonics. The method is applicable to any distribution of points and two test cases are implemented on an icosahedral geodesic grid. The method is both vectorizable and parallelizable. 相似文献