Incipient weathering rind development on introduced machine‐polished granite discs in an Arctic alpine environment,northern Scandinavia

Weathering rinds, zones of alteration on the exterior surfaces of rock outcrops and coarse unconsolidated surficial debris are widely used by geomorphologists and Quaternary geologists as indicators of the relative age of landforms and landscapes. Additionally they provide unique insights into the earliest stages of rock and mineral weathering, yet the origin of these alteration zones is relatively poorly understood. This lack of understanding applies especially to the initial stages of rind formation. The study reported in this paper has two principal objectives. The first is to use lightly polished granite discs inserted in soil profiles under several different plant communities in an Arctic alpine environment for a period of four or five years to investigate the nature of incipient weathering rind development. The second is to investigate the factors responsible for spatial variability in the nature and rates of rind formation. Incipient weathering rind development on the outer edges of the granite discs is observable and measurable over a period of time as short as four years in the mild Arctic alpine environment of Swedish Lapland. The earliest stages of rind development involve the development of a porous structure consisting of a combination of pits and fractures which have been solutionally enlarged and modified. Solution appears to be preferentially concentrated on the surfaces of feldspars and, to a lesser extent, quartz. In addition, iron oxides are present along grain boundaries and in grain interiors and are interpreted to have been derived from the oxidation of ferromagnesian minerals. Spatial variability in weathering rind development appears to be particularly driven by differences in moisture but is not related to soil pH. Copyright © 2005 John Wiley & Sons, Ltd.     

Time-Variations of D-Region Electron Densities, and Comparisons With Model Computations

An extensive series of incoherent scatter studies of the ionospheric D-region was carried out at the Arecibo radar facility during 1978 and 1979. They included several full-day sequences of electron density measurements over a range of altitudes, and also included a sequence during the serendipitous occurrence of a large solar flare. For the solar flare event simultaneous data on solar X-ray fluxes in several wavelength bands were available from the GOES-2 and ISEE-3 satellites. In the course of development of a large ionospheric computer model at Los Alamos we have used the solar flare data as a reality check. The solar X-ray flux data were used as inputs for computing ionization rates. The model computer includes 999 chemical reactions, and also includes diffusion and transport processes. In the course of the flare studies we used the data comparisons to adjust the values of three chemical rate coefficients that were poorly known. With those adjustments the model computations fitted the data quite well. Subsequent to the flare analysis we have been using the same model with some minor updates to compute the expected diurnal variations of the ambient D-region under conditions chosen to match those existing at the times of the incoherent scatter measurements. Comparisons of the computations and the data will be shown, and the relative importance of the several separate ionization processes will be discussed. We also compare model results with experimental data on concentrations of NO.     

Overhead Detection of Underground Nuclear Explosions by Multi-Spectral and Infrared Imaging

The Comprehensive Nuclear Test Ban Treaty allows for Multi-Spectral and Infrared Imaging from an aircraft and on the ground to help reduce the search area for an underground nuclear explosion from the initial 1,000 km². Satellite data, primarily from Landsat, have been used as a surrogate for aircraft data to investigate whether there are any multi-spectral features associated with the nuclear tests in Pakistan, India or North Korea. It is shown that there are multi-spectral observables on the ground that can be associated with the nominal surface ground zero for at least some of these explosions, and that these are likely to be found by measurements allowed by the treaty.     

Is the ocean floor a fractal?

The topographic structure of the ocean bottom is investigated at different scales of resolution to answer the question: Can the seafloor be described as a fractal process? Methods from geostatistics, the theory of regionalized variables, are used to analyze the spatial structure of the ocean floor at different scales of resolution. The key to the analysis is the variogram criterion: Self-similarity of a stochastic process implies self-similarity of its variogram. The criterion is derived and proved here: it also is valid for special cases of self-affinity (in a sense adequate for topography). It has been proposed that seafloor topography can be simulated as a fractal (an object of Hausdorff dimension strictly larger than its topological dimension), having scaling properties (self-similarity or self-affinity). The objective of this study is to compare the implications of these concepts with observations of the seafloor. The analyses are based on SEABEAM bathymetric data from the East Pacific Rise at 13°N/104°W and at 9°N/104°W and use tracks that run both across the ridge crest and along the ridge flank. In the geostatistical evaluation, the data are considered as a stochastic process. The spatial continuity of this process is described by variograms that are calculated for different scales and directions. Applications of the variogram criterion to scale-dependent variogram models yields the following results: Although the seafloor may be a fractal in the sense of the definition involving the Hausdorff dimension, it is not self-similar, nor self-affine (in the given sense). Mathematical models of scale-dependent spatial structures are presented, and their relationship to geologic processes such as ridge evolution, crust formation, and sedimentation is discussed.     

Erratum to: Assessment of coastal communities’ vulnerability to floods using indicator-based approach: a case study of Greater Accra Metropolitan Area,Ghana

In this paper, the extent to which the potentially transit-dependent portion of the population is vulnerable to the effects of a hurricane is estimated. The vulnerability of an area is defined as a composite measure of the proportion of disadvantaged persons, distance to transit, and flooding potential of people within an area. Unlike past studies which have focused on the vulnerability of the population in relatively large geographic areas, this study estimates the vulnerability of the population in 30 m × 30 m areas as defined in the National Land Cover Database. Population estimates from the national census at block level are disaggregated to the 30 m × 30 m units using a modified dasymetric mapping method in ArcGIS. The modified mapping method assigns population to each small areal unit using weights estimated by regressing the area of each land use in a census block against the population in that block. The coefficients in the regression analysis are “weights” associating population with each land use, and are used to distribute the population in each census block to the small geographic units based on their land use. In a case study of New Orleans, the results show that some areas are not well served by the existing transit pickup locations, as evidenced by their high vulnerability scores. Reassignment of pickup point locations to cover higher vulnerability score areas was investigated using integer linear programming. The results show that the optimally located pickup points serve areas with a larger average vulnerability score than the current pickup points in the study area. The method appears to be helpful in identifying vulnerable areas that, subsequently, could receive improved hurricane evacuation service in the future.     

Effect of Biofuels on Biodegradation of Benzene and Toluene at Gasoline Spill Sites

The risk that benzene and toluene from spills of gasoline will impact drinking water wells is largely controlled by the natural anaerobic biodegradation of benzene and toluene. Benzene and toluene, as well as ethanol and other biofuels, are degraded under anaerobic conditions to the same pool of degradation products. Biodegradation of biofuels may produce concentrations of degradation products that make the thermodynamics for degradation of benzene and toluene infeasible under methanogenic conditions and produce larger plumes of benzene and toluene. This study evaluated the concentrations of fuel alcohols that are necessary to inhibit the anaerobic degradation of benzene and toluene under methanogenic conditions. At two ethanol spill sites, concentrations of ethanol greater ≥42 mg/L inhibited the anaerobic degradation of toluene. The pH and concentrations of acetate, dissolved inorganic carbon, and molecular hydrogen were used to calculate the Gibbs free energy for the biodegradation of toluene. In general, the anaerobic biodegradation of toluene was not thermodynamically feasible in water with ≥42 mg/L ethanol. In a microcosm study, when the concentrations of ethanol were ≥14 mg/L or the concentrations of n‐butanol were ≥16 mg/L, the biodegradation of the alcohols consistently produced concentrations of hydrogen, dissolved inorganic carbon, and acetate that would preclude natural anaerobic biodegradation of benzene and toluene by syntrophic organisms. In contrast, iso‐butanol and n‐propanol only occasionally produced conditions that would preclude the biodegradation of benzene and toluene.     

Fracture geometry of pseudotachylyte generation zones: a study of shear fractures formed during seismic events

The orientation and movement sense of shear fractures in pseudotachylyte generation zones developed in the Ikertôq shear belt, West Greenland are described, and the fracturing sequence is inferred. The generation zones occur in strongly foliated gneisses, and consist of concordant, usually paired, principal displacement shear fractures (paired shears), on which most melt was generated, and a system of minor shear fractures. Minor shear fracturing was most intense between principal displacement shear fractures, and most melt intruded from these paired shears inwards with respect to the zone. Intrusion of injection veins of pseudotachylyte off the principal displacement shear fractures, is believed to be contemporaneous with minor shear fracturing in the generation zones.Generation zones affect intact rocks, and individual principal displacement shear fractures have a maximum displacement of 4.6 m. Paired principal displacement shear fractures are up to 3 m apart, and have a maximum observed length of 1 km. In all the zones described, the fracturing appears to be the result of a single episode of slip. Both dextral and sinistral generation zones occur within the study area, and have different geometries. In each case the displacement is strike-slip.     

Application of Compositional Techniques in the Field of Crystal Chemistry: A Case Study of Luzonite, a Sn-Bearing Mineral

Out-of-equilibrium crystallization often produces complex compositional variability in minerals, generating zoning and other mixing phenomena. The appropriate microchemical characterization of the resulting out-of-equilibrium patterns is of critical importance in understanding the overall physical and chemical properties of the host crystalline phases. In this framework, the modeling of compositional changes assumes a fundamental role. However, when compositional data are used, their management with standard exploratory, statistical, graphical, and numerical tools may give misleading results attributable to the phenomenon of induced correlations. To avoid these problems, methods able to extract compositional data from their constrained space (the simplex) in order to apply standard statistics, have to be adopted. As an alternative, the use of tools having properties able to work in the simplex geometry has to be considered. A luzonite single crystal (ideal composition, Cu₃AsS₄) exhibiting concentric and sector zoning was studied using electron probe microanalysis in order to understand the mechanisms which give rise to chemical variability and conditions in the developing environment. Compositional variations were determined by collecting data along three different transects. The major and minor elements (Cu, As, S, Fe, Sb, Sn) were analyzed with the aim of characterizing their patterns of association in the crystal and, hence, crystal evolution. The whole covariance structure as well as the chemical relationships between the successive zones was investigated by means of compositional methods, considering both data transformation and the stay in the simplex approach. Results indicate that the crystal grew under quiescent conditions, where chemical control was primarily exercised by the mineral’s surface and only minor effects were due to changes in the composition of the surrounding fluid. Consequently, an oscillatory uptake of chemical components occurred in which a competition between famatinite-like (Cu₃SbS₄) and kuramite-like (Cu₃SnS₄) domains characterized the As-poor zones.     

Recent Rapid Regional Climate Warming on the Antarctic Peninsula

The Intergovernmental Panel on Climate Change (IPCC) confirmed that mean global warming was 0.6 ± 0.2 °C during the 20th century and cited anthropogenic increases in greenhouse gases as the likely cause of temperature rise in the last 50 years. But this mean value conceals the substantial complexity of observed climate change, which is seasonally- and diurnally-biased, decadally-variable and geographically patchy. In particular, over the last 50 years three high-latitude areas have undergone recent rapid regional (RRR) warming, which was substantially more rapid than the global mean. However, each RRR warming occupies a different climatic regime and may have an entirely different underlying cause. We discuss the significance of RRR warming in one area, the Antarctic Peninsula. Here warming was much more rapid than in the rest of Antarctica where it was not significantly different to the global mean. We highlight climate proxies that appear to show that RRR warming on the Antarctic Peninsula is unprecedented over the last two millennia, and so unlikely to be a natural mode of variability. So while the station records do not indicate a ubiquitous polar amplification of global warming, the RRR warming on the Antarctic Peninsula might be a regional amplification of such warming. This, however, remains unproven since we cannot yet be sure what mechanism leads to such an amplification. We discuss several possible candidate mechanisms: changing oceanographic or changing atmospheric circulation, or a regional air-sea-ice feedback amplifying greenhouse warming. We can show that atmospheric warming and reduction in sea-ice duration coincide in a small area on the west of the Antarctic Peninsula, but here we cannot yet distinguish cause and effect. Thus for the present we cannot determine which process is the probable cause of RRR warming on the Antarctic Peninsula and until the mechanism initiating and sustaining the RRR warming is understood, and is convincingly reproduced in climate models, we lack a sound basis for predicting climate change in this region over the coming century.