Large-scale ionization fronts and the nature and distribution of light scattering particles in the orion nebula

Image-tube filter photographs calibrated against photoelectric filter photometry have been used to give maps of M42 in absolute flux units over the central 15 arc min of the nebula in Hα, [Nii] (λ 6584 Å), Hβ and continuum at λ 4700 Å. Maps of the ratios Hα/[Nii] and (for the first time) of continuum/Hβ have been produced with unprecedented spatial resolution. These show that the gas to dust ratio is high near the exciting stars and falls strongly in the vicinity of large scale ionization fronts marked by minima in the Hα/[Nii] ratio. These results are interpreted in terms of detailed shell models containing either ice or graphite or silicate scattering particles. In all models there must be a central hole in the distribution of scattering particles. The effect of neutral globules and intrusions is investigated. It is found that all types of grain are trapped inside neutral intrusions near the centre of the nebula by the pressure of the Lα light surrounding the globule, but in the early evolution of the nebula particles can escape into the ionized medium when fronts are R-type. Ice grains escaping at this time will be destroyed for distances to the exciting stars less than 1 pc. These results can explain both the central hole in dust and the underabundance of oxygen in the ionized gas observed earlier. Arguments depending on colour index of the scattered light indicate that mixtures of scattered light from ice in the globules and from ice in the ionized medium can explain the observations, but that the graphite and silicate particles fail. A schematic model of the Orion Nebula is presented to attempt to explain the large scale phenomena observed here. It demonstrates that simple shell models for this nebula are dubious.     

Boulder 1, Station 2, Apollo 17: Petrology and petrogenesis

Boulder 1, Station 2, Apollo 17 is a stratified boulder containing dark clasts and dark-rimmed light clasts set in a light-gray friable matrix. The gray to black clasts (GCBx and BCBx) are multigenerational, competent, high-grade metamorphic, and partially melted breccias. They contain a diverse suite of lithic clasts which are mainly ANT varieties, but include granites, basaltic-textured olivine basalts, troctolitic and spinel troctolitic basalts, and unusual lithologies such as KREEP norite, ilmenite (KREEP) microgabbro, and the Civet Cat norite, which is believed to be a plutonic differentiate. The GCBxs and BCBxs are variable in composition, averaging a moderately KREEPy olivine norite. The matrix consists of mineral fragments derived from the observed lithologies plus variable amounts of a component, unobserved as a clast-type, that approximates a KREEP basalt in composition, as well as mineral fragments of unknown derivation. The high-temperature GCBxs cooled substantially before their incorporation into the friable matrix of Boulder 1. The light friable matrix (LFBx) is texturally distinct from the competent breccia clasts and, apart from the abundant ANT clasts, contains clasts of a KREEPy basalt that is not observed in the competent breccias. The LFBx lacks such lithologies as the granites and the Civet Cat norite observed in the competent breccias and in detail is a distinct chemical as well as textural entity. We interpret the LFBx matrix as Serenitatis ejecta deposited in the South Massif, and the GCBx clasts as remnants of an ejecta blanket produced by an earlier impact. The source terrain for the Serenitatis impact consisted of the competent breccias, crustal ANT lithologies, and the KREEPy basalts, attesting to substantial lunar activity prior to the impact. The age of the older breccias suggests that the Serenitatis event is younger than 4.01±0.03 b.y.     

The role of prokaryotes in subsurface weathering of hydrothermal sediments: A combined geochemical and microbiological investigation

A detailed geochemical and microbiological study of a ∼2 m sediment core from the inactive Alvin mounds within the TAG hydrothermal field was conducted to examine, for the first time, the role of prokaryotes in subsurface weathering of hydrothermal sediments. Results show that there has been substantial post-depositional remobilisation of metal species and diagenetic overprinting of the original high-temperature hydrothermal minerals, and aspects have involved prokaryotic processes. Prokaryotic enumeration demonstrates the presence of a population smaller than the average for deep sea sediments, probably due to the low organic carbon content, but not inhibited by (and hence adapted to) the metal rich environment. There was a small but significant increase in population size associated with the active redox boundary in an upper metal sulphide layer (50-70 cm) around which active metal remobilisation was concentrated (Cu, Au, Cd, Ag, U, Zn and Zn). Hence, subsurface prokaryotes were potentially obtaining energy from metal metabolism in this near surface zone. Close association of numbers of culturable Mn and Fe reducing prokaryotes with subsurface Fe²⁺ and Mn²⁺ pore water profiles suggested active prokaryotic metal reduction at depth in core CD102/43 (to ∼175 cm). In addition, a prokaryotic mechanism, which is associated with bacterial sulphate reduction, is invoked to explain the U enrichment on pyrite surfaces and Zn and Pb remobilisation in the upper sediment. Although prokaryotic populations are present throughout this metalliferous sediment, thermodynamic calculations indicated that the inferred low pH of pore waters and the suboxic/anoxic conditions limits the potential energy available from Fe(II) oxidation, which may restrict prokaryotic chemolithotrophic biomass. This suggests that intense prokaryotic Fe oxidation and weathering of seafloor massive sulphide deposits may be restricted to the upper portion of the deposit that is influenced by near neutral pH and oxic seawater unless there is significant subsurface fluid flow.     

Potential for irradiation of methane to form complex organic molecules in impact craters: Implications for Mars, Titan and Europa

The release of methane from crater sites following meteorite impact is a possible consequence of the thermal alteration of organic matter, or tapping of reservoired gas of biogenic or abiogenic origin. At least the latter is feasible on Mars. Methane and higher hydrocarbons are susceptible to polymerization and precipitation by radioactive minerals. Where such minerals are present in impact target rocks, the craters can be a preferred site for carbon concentration, and the formation of complex organic molecules. On icy bodies, such as Titan and Europa, methane released by impact could be a fuel for prebiotic chemistry involving other forms of irradiation.     

Temperature–composition–time (T–X–t) data from authigenic K-feldspar: An integrated methodology for dating fluid flow events

Integration of fluid inclusion analysis with high spatial resolution Ar–Ar dating of K-feldspar cements has been used to resolve and reconstruct palaeo-fluid flow. Fluid inclusion analysis allows discrimination of distinct cement phases, thereby identifying discrete episodes of fluid flow. Ar–Ar dating of the same cements via high spatial resolution laserprobe establishes absolute age constraints on the framework previously constructed. Integration of these two datasets yields temperature–composition–time data.     

The Geography of Certified Trade‐Induced Manufacturing Job Loss in New England*

The article analyzes patterns in the distribution of manufacturing job losses that have been certified as trade‐induced by the U.S. Department of Labor. Spatial patterns in the likelihood of job loss are examined in the United States for the period from 1994 to 2002, with particular emphasis on county‐level patterns in New England. The findings demonstrate that the pattern of losses was correlated with measures of economic vitality and competitiveness including per capita income, educational attainment, occupational structure, and inventiveness. These results suggest that trade‐induced deindustrialization is borne most heavily by places ill‐equipped to compete in a more open, integrated international economy.