Estimating the longevity of limestone drains in treating acid mine drainage containing high concentrations of iron

Limestone drains are often implemented in the treatment of acid mine drainage (AMD), but when the AMD contains high levels of dissolved Fe their lifetime is dependent on the rate of precipitation of Fe hydroxide on the limestone surface. This study used a small-scale laboratory experiment to define the longevity of a limestone drain by determining the thickness of the Fe coating encapsulating the limestone particles when the system lost its maximum neutralising potential. Synthetic AMD (100 mg/L Fe, pH 4–4.8) was pumped through a column containing limestone particles for 1110 h, when the effluent pH had dropped from a maximum of 6.45–4.9. The decline in neutralisation during the experiment was due to the formation of Fe hydroxide coatings on the limestone grains. These coatings are composed of lepidocrocite/goethite in three distinct layers: an initial thick porous orange layer, overlain by a dense dark brown crust, succeeded by a layer of loosely-bound, porous orange globules. After 744 h, a marked increase in the rate of pH decline occurred, and the system was regarded as having effectively failed. At this time the Fe hydroxide crust effectively encapsulated the limestone grains, forming a diffusion barrier that slowed down limestone dissolution. Between the coating and the limestone substrate was a 60 μm wide void, so that agitation of the limestone sample would readily remove the coating from the limestone surface.     

Rb-Sr dating of Paleozoic glauconite from the Llano region,central Texas

Glauconite from eight stratigraphic horizons (Cambrian to Pennsylvanian) in the Llano Uplift, central Texas and two Cretaceous glauconites were analyzed by the Rb-Sr method. Only two untreated samples provide ages in agreement with those anticipated from current best estimates of the geologic time scale. With one exception all the other apparent ages fall short of the estimated age of deposition by as much as 22%. Low ages, the pattern customarily observed, are attributed to postdepositional loss of radiogenic ⁸⁷Sr from expandable layers by weathering or during diagenesis.Detailed leaching experiments using a variety of reagents were performed to characterize the behavior of glauconite. The most promising treatment, which we recommend as standard procedure in all future studies, is with ammonium acetate which is able to purge the mineral of loosely-bound Rb and Sr while leaving tightly-bound components intact. After appropriate leach, three other Rb-Sr ages were brought into coincidence with their estimated ages of deposition.In contrast an Upper Cambrian glauconite was found to be extremely resistant to further alteration by chemical attack′, providing an age of 429 ± 17 M yr. Although 17% short of the age of deposition, this age is interpreted as the time of a real event: diagenetic recrystallization induced by burial. Comparison of data from four samples indicates that for Paleozoic glauconite, conditions exist in which the Rb-Sr system is less susceptible to mild disturbance than is the K-Ar system.     

PHYSIOGRAPHY,FORAMINIFERA AND SEDIMENTATION IN THE Dovey Estuary (Wales)

A study of the chemistry, circulation and sedimentation is followed by an outline account of the living and dead communities (particularly foraminifera) characteristic of the main physiographic subenvironments. On the basis of the relationships established these results are used in an interpretation of the vertical sequence.     

Anasazi (Pre-Columbian Native-American) Migrations During The Middle-12Th and Late-13th Centuries – Were they Drought Induced?

Severe droughts in the middle-12th and late-13th centuries appear to have affected Anasazi (pre-Columbian Native American) populations. During the first drought most of the great houses in the central San Juan Basin were vacated; the second drought resulted in the abandonment of the Four Corners region. During the first drought, villages may not have been completely abandoned. The multi-year drought periods probably were characterized by reductions in both winter and summer precipitation. Maize is dependent on winter precipitation for its germination and initial growth and on summer (monsoonal) precipitation for its continued growth. Reductions in precipitation are hypothesized to have resulted in low yields of maize, the dietary staple of the Anasazi. A comparison of historic climate data and tree-ring-based reconstructions of precipitation in the Four Corners region with tree-ring-based reconstructions of the Pacific Decadal Oscillation (PDO) and the Atlantic Multidecadal Oscillation (AMO) indicate that severe and persistent drought in the Four Corners region occurs when the PDO is negative and the AMO is positive. Historic climate data from the greater San Juan Basin indicate that a negative PDO is characterized by reductions in both water-year and summer precipitation, reinforcing the concept that at least some multi-year droughts involved weakening of the summer monsoon with attendant decreases in the yields of maize.     

Climate Suitability for Stable Malaria Transmission in Zimbabwe Under Different Climate Change Scenarios

Climate is one factor that determines the potential range of malaria. As such, climate change may work with or against efforts to bring malaria under control. We developed a model of future climate suitability for stable Plasmodium falciparum malaria transmission in Zimbabwe. Current climate suitability for stable malaria transmission was based on the MARA/ARMA model of climatic constraints on the survival and development of the Anopheles vector and the Plasmodium falciparum malaria parasite. We explored potential future geographic distributions of malaria using 16 projections of climate in 2100. The results suggest that, assuming no future human-imposed constraints on malaria transmission, changes in temperature and precipitation could alter the geographic distribution of malaria in Zimbabwe, with previously unsuitable areas of dense human population becoming suitable for transmission. Among all scenarios, the highlands become more suitable for transmission, while the lowveld and areas with low precipitation show varying degrees of change, depending on climate sensitivity and greenhouse gas emission stabilization scenarios, and depending on the general circulation model used. The methods employed can be used within or across other African countries.     

Some Insights into Topographic,Elastic and Self-gravitation Interaction in Modelling Ground Deformation and Gravity Changes in Active Volcanic Areas

Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.     

The ammonite faunas of the Osmington Oolite Formation (Jurassic, Middle Oxfordian) of the Dorset coast

A detailed study of the lithologies of each of the beds present in the Osmington Oolite Formation of south Dorset is used to allocate numerous loose-collected ammonites to their correct stratigraphic horizons. Much new material has been collected by the author in addition to the limited amount of material available in museum collections. The age of the faunas of the three constituent members of the Osmington Oolite Formation is each assessed and placed into the context of Middle Oxfordian ammonite sequences elsewhere in England and in Europe.