Two-feldspar geothermometry in granulite facies metamorphic rocks

A geothermometric technique based on equilibria between coexisting plagioclase and alkali feldspar was applied to quartzo-feldspathic granulites from Salvador, BA, Brazil. The conditions of metamorphism were determined to be in the range 750 ° C–800 ° C, 4–8 Kb, by comparison with experimental data on the stabilities of sapphirine, phlogopite and other minerals occurring in the associated rocks. Selected feldspar data gives temperatures near, but slightly below, this range. Several variants of the Wood and Banno model, as well as an empirical two-pyroxene geothermometer, were also tested and found to give temperatures which were apparently 50 °–100 ° high. The solubility of Al₂O₃ in orthopyroxene indicates temperatures which are about 200 ° to high, suggesting that Fe in the natural assemblages significantly changes relationships observed experimentally in MgO-Al₂O₃-SiO₂ systems.     

Mechanical twinning in diopside Ca(Mg,Fe)Si2O6: Structural mechanism and associated crystal defects

Diopside twins mechanically on two planes, (100) and (001), and the associated macroscopic twinning strains are identical (Raleigh and Talbot, 1967). An analysis based on crystal structural arguments predicts that both twin mechanisms involve shearing of the (100) octahedral layers (containing Ca²⁺, Mg²⁺ and Fe²⁺ ions) by a magnitude of c/2. Small adjustments or shuffles occur in the adjacent layers containing the [SiO₄]^4? tetrahedral chains. While the (100) twins are conventional with shear parallel to the composition plane, this analysis predicts that (001) twins form by a mechanism closely related to kinking. A polycrystalline diopside specimen was compressed 8% at a temperature of 400° C, a pressure of 16 kilobars, and a compressive strain rate of about 10^?4/s. Transmission electron microscopy on this specimen has revealed four basic lamellar features:

1. (100) mechanical twin lamellae;
2. (100) glide bands containing unit dislocations;
3. (001) twin lamellae;
4. (101) lamellar features, not as yet identified.

The (001) twins often contain remnant (100) lamellae of untwinned host. Twinning dislocations occur in these (100) lamellae and in the (001) twin boundaries with very high densities. Diffraction contrast experiments indicate that the twinning dislocations associated with both twin laws glide on (100) with Burgers vector b=X [001] where X is probably equal to 1/2 on the basis of the structural analysis. Parallels are drawn between mechanical twinning in clinopyroxenes and clinoamphiboles. The exclusive natural occurrence of basal twins in shock-loaded clinopyroxenes and of analogous ( \(\bar 1\) 01) twins in clinoamphiboles is given a simple explanation in terms of the relative difficulty of the “kinking” mechanism as compared to direct glide parallel to the composition plane.     

Fatty acids and Pb-210 geochronology of a sediment core from Buzzards Bay,Massachusetts

Four sections of a Pb-210 dated core of 62 cm length from Buzzards Bay, Massachusetts, were analyzed for fatty acids. A comparison of fatty acids extracted by Soxhlet extraction (unbound fatty acids) with fatty acids extracted by subsequent saponification extraction of the same sample (bound fatty acids) showed the former did not undergo diagenetic loss any faster than the latter. However, compositional differences between bound and unbound fatty acids were apparent in the top section of 1–2 cm and were less apparent in the 54–58 cm section. At least 14% of the bound fatty acids are esterified to non-solvent extractable material. The net conversion of fatty acids to other compounds is 32 μ/g dry weight sediment over the first 30 yr after deposition.     

Armalcolite stability as a function of pressure and oxygen fugacity

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.     

Late-Pleistocene and Holocene remains of Hysterocarpus traski (Tule Perch) from Clear Lake,California, and inferred Holocene temperature fluctuations

The remains of scales of Hysterocarpus traski Gibbons (Tule perch) were found throughout a 27.44-m core from Clear Lake. Most scales occurred between the mud surface and deposits approximately 11,000 years old. Changes in growth rates of the animals were examined by measuring scale annuli and applying an empirically established regression of fish length on scale radius. The data indicate a pattern of accelerating growth rates, reaching a peak between ?4000 and 2800 BP. After ?2800 BP, growth rates decline markedly. Because the growth rates of these animals are essentially dependent on temperature, the changes observed in the patterns of growth probably reflect changes in climate in the northern Coast Range. The general pattern of inferred temperature increase during the early and middle Holocene, ending between ?4000 and 2800 BP, is consistent with evidence from tree-line studies and palynology indicating higher temperatures in parts of the western United States during this period.     

Siltation analysis in the Neyyar reservoir and forest degradation in its catchment: a study from Kerala state, India

 Impact of catchment erosion and the resultant reservoir siltation from a tropical environment is reported here to discuss the effect of a reservoir in the natural degradation of an evergreen-forested segment. While an area of 8.01 km² has been affected by direct inundation at the full reservoir level, another 2.6 km² area once under thick forest cover, had also lost its identity over the last 38 years by indirect degradation. This zone mainly falls in the confluence of tributaries, namely Neyyar and Mullayar, with the reservoir. The capacity of the reservoir was found to be reduced by 28.8 Mm³ during this period and the annual average loss is calculated as 0.75 Mm³ (0.71%), indicating the intensity of erosion from the catchment zone. In case the proposed upper dam in the reservoir comes into existence, an additional area of 2.4 km² from the virgin forest would be submerged and more area would face degradation around the inundated zone. Received: 29 July 1998 · Accepted: 16 November 1998     

A new palaeoenvironmental model for the evolution of the Byzovaya Palaeolithic site,northern Russia

Recently, the sediment stratigraphy and geochronology of the well‐known Palaeolithic site Byzovaya in northern Russia were investigated. New technological analyses of the artefacts suggest a Middle Palaeolithic Mousterian culture, and occupation by Neanderthals, not Modern humans as previously thought. We present here a new and detailed documentation of the stratigraphy, including the geological context of the artefacts and faunal remains. From sedimentological criteria we confidently interpret the find‐bearing strata as debris‐flow deposits, covered by aeolian sediments. The chronology is based on radiocarbon and luminescence (OSL) dates from the find‐bearing and overlying strata. The results are utilized to reconstruct the geological history at the excavation area. The stratigraphy varies considerably across the excavation area. The most intact and undisturbed part of the sequence was found inside the most recent Excavation II. In this part the artefacts and bones appear to have been permanently sealed and protected by aeolian sand. The older Excavation I shows a more complicated stratigraphy, as the finds may have been temporarily exposed during the early Holocene owing to ravine incision and slumping activity. The individual radiocarbon dates that were collected from different parts of the site and from various stratigraphic positions are re‐investigated in this study. By using Bayesian statistics the conclusion is that the site was occupied during a restricted period around 30.6–34.7 ka. A series of partly unpublished OSL dates of coversand from different sites demonstrates a regional aeolian signal during the Lateglacial in northern Russia, 15–14 ka.