Ammonia photolysis and the greenhouse effect in the primordial atmosphere of the earth

Photochemical calculations indicate that in the prebiotic atmosphere of the Earth ammonia would have been irreversibly converted to N₂ in less than 40 years if the ammonia surface mixing ratio were ≤ 10^?4. However, if a continuous outgassing of ammonia were maintained, radiative equilibrium calculations indicate that a surface mixing ratio of ammonia of 10^?5 or greater would provide a sufficient greenhouse effect to keep the surface temperature above freezing. With a 10^?4 mixing ratio of ammonia, 60 to 70% of the present day solar luminosity would be adequate to maintain surface temperatures above freezing. A lower limit to the time constant for accumulation of an amount of nitrogen equivalent to the present day value is 10 my if the outgassing were such as to provide a continuous surface mixing ratio of ammonia ≥ 10^?5.     

Phosphine absorption in the 5-μm window of Jupiter

Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v₄ NH₃ at 6.1 μm and the v₃ CH₄ band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH₃) samples show that PH₃ is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH₃ which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations.     

Photoelectric lightcurves of asteroids 42 Isis, 45 Eugenia, 56 Melete, 103 Hera, 532 Herculina,and 558 Carmen

Photoelectric observations of six asteroids are presented. The following synodic periods of rotation and amplitudes of variation are reported: 42 Isis, P = 13^h.59, Δm = 0.32; 45 Eugenia, P = 5^h.70, Δm = 0.30; 56 Melete, P = 13^h.7 or 19^h.0, Δm = 0.06; 532 Herculina, P = 9^h.408, Δm = 0.15; 558 Carmen, P ≈ 10^h, Δm ≈ 0.25. The asteroid 103 Hera exhibited no periodic variation in excess of about 0.03 magnitude. The period found for 532 Herculina is one half that previously reported by other observers.     

Thermodynamics of selected trace elements in the Jovian atmosphere

The thermochemistry of several hundred compounds of twelve selected trace elements (Ge, Se, Ga, As, Te, Pb, Sn, Cd, Sb, Tl, In, and Bi) has been investigated for solar composition material along a Jupiter adiabat. The results indicate that AsF₃, InBr, TlI, and SbS, in addition to CO, PH₃, GeH₄, AsH₃, H₂Se, HCl, HF, and H₃BO₃ proposed by Barshay and Lewis (1978), may be potential chemical tracers of atmospheric dynamics. The reported observations of GeH₄ is interpreted on the basis of new calculations as implying rapid vertical transport from levels where T ? 800°K. Upper limits are also set on the abundances of many gaseous compounds of the elements investigated.     

A dipole field model for axisymmetric alfvén waves with finite ionosphere conductivities

An axisymmetric model for approximate solution of the magnetospheric Alfvén wave problem at latitudes above the plasmapause is proposed, in which a realistic dipole geometry is combined with finite anisotropic ionosphere conductivities, thus bringing together various ideas of previous authors. It is confirmed that the axisymmetric toroidal and poloidal modes interact via the ionospheric Hall effect, and an approximate method of solution is suggested using previously derived closed solutions of the uncoupled wave equations.A solution for zero Hall conductivity is obtained, which consists of sets of independent shell oscillations, regardless of the magnitude of the Pedersen conductivity. One set reduces to the classical solutions for infinite Pedersen conductivity, while another predicts a new set of harmonics of a quarter-wave fundamental, with longer eigenperiods than the classical solutions for a given L-shell.     

Photoelectric lightcurve and period of rotation of the asteroid 182 Elsa

Photoelectric observations on five consecutive nights yield a period of rotation of 80 ± 2 hr with an amplitude of 0.7 magnitude for 182 Elsa, making it the longest period of rotation known to date. 182 Elsa is classed as an S object with a diameter of 48 km.     

Galilean satellite eclipse studies: III. Jovian methane abundance

The methane abundance in the lower Jovian stratosphere is measured using Galilean satellite eclipse light curves. Spectrally selective observations in and between absorption bands are compared. An average mixing ratio at the locations measured is [CH₄]/[H₂] ～ 1.3 × 10^?3, larger than the value 0.9 × 10^?3 expected for a solar abundance of carbon. Some zenographic variation of the mixing ratio may occur. Observationally compatible values are 1.3–2.0 × 10^?3 in the STZ, 1.3– 2.6 × 10^?3 on the GRS/STrZ edge, and 0.7–1.3 × 10^?3 in the GRS.     

Newtonian cosmology with a varying gravitational constant

Newtonian cosmology is developed with the assumption that the gravitational constantG diminishes with time. The functional form adopted forG(t), a modification of a suggestion of Dirac, isG=A(k+t) ^–1, wheret is the age of the Universe and a small constantk is inserted to avoid a singularity in the two-body problem. IfR is the scale factor, normalized to unity at an epoch time , the differential equation is then . Here ₀ is the mean density at the epoch time. With the above form forG(t), the solution is reducible to quadratures.The scale factorR either increases indefinitely or has one and only one maximum. LetH ₀ be the present value of Hubble's constant /R and _0c the minimum density for a maximum ofR, i.e., for closure of the Universe. The conditions for a maximum lead to a boundary curve of _0c versusH ₀ and the numbers indicate strongly that thisG-variable Newtonian model corresponds to an open universe. An upward estimate of the age of the Universe from 10¹⁰ yr to five times such a value would still lead to the same conclusion.The present Newtonian cosmology appears to refute the statement, sometimes made, that the Dirac model forG necessarily leads to the conclusion that the age of the Universe is one-third the Hubble time. Appendix B treats this point, explaining that this incorrect conclusion arises from using all the assumptions in Dirac (1938). The present paper uses only Dirac's final result, viz,G(k+t)^–1, superposing it on the differential equation .     

Auroral ion velocity distributions for a polarization collision model

We have calculated the effect that convection electric fields have on the velocity distribution of auroral ions at the altitudes where the plasma is weakly-ionized and where the various ion-neutral collision frequencies are much smaller than the ion cyclotron frequencies, i.e. between about 130 and 300 km. The appropriate Boltzmann equation has been solved by expanding the ion velocity distribution function in a generalized orthogonal polynomial series about a bi-Maxwellian weight factor. We have retained enough terms in the series expansion to enable us to obtain reliable quantitative results for electric field strengths as large as 90 mV m^?1. Although we have considered a range of ion-neutral scattering mechanisms, our main emphasis has been devoted to the long-range polarization interaction. In general, we have found that to lowest order the ion velocity distribution is better represented by a two-temperature or bi-Maxwellian distribution than by a one-temperature Maxwellian, with there being different ion temperatures parallel and perpendicular to the geomagnetic field. However, the departures from this zeroth-order bi-Maxwellian distribution become significant when the ion drift velocity approaches (or exceeds) the neutral thermal speed.