Large-scale oil-in-ice experiment in the Barents Sea: monitoring of oil in water and MetOcean interactions

A large-scale field experiment took place in the marginal ice zone in the Barents Sea in May 2009. Fresh oil (7000 L) was released uncontained between the ice floes to study oil weathering and spreading in ice and surface water. A detailed monitoring of oil-in-water and ice interactions was performed throughout the six-day experiment. In addition, meteorological and oceanographic data were recorded for monitoring of the wind speed and direction, air temperature, currents and ice floe movements. The monitoring showed low concentrations of dissolved hydrocarbons and the predicted acute toxicity indicated that the acute toxicity was low. The ice field drifted nearly 80 km during the experimental period, and although the oil drifted with the ice, it remained contained between the ice floes.     

Fine sediment dynamics in a shallow lake and implication for design of hydraulic works

Lake Markermeer is a large (680?km²), shallow body of water in the middle of the Netherlands, with a mean water depth of 3.6?m. One of the major problems in the lake is its decreasing ecological value which is, among other reasons, caused by a gradual increase of suspended sediment concentration and associated increase of light attenuation in the water column. A thorough understanding of fine sediment dynamics in the lake is a prerequisite for solving this problem. This paper addresses the 3D nature of near-bed sediment dynamics in Lake Markermeer, based on data sampled from a 1-month field experiment in autumn 2007. The campaign involved the collection of 71 bed samples across the lake. At each location, dual-frequency echo soundings were carried out to assess the thickness of the silt layer, and sediment concentration throughout the water column was measured with an Optical Backscatter Sensor (OBS). Moreover, 2-week time series of wave height, water level, current velocities, and near-bed sediment concentration were collected at a single location. The time series of sediment concentration were measured with a regular OBS and an Argus Surface Meter IV (ASM). During the measurement period, flow velocities ranged between 2 and 15?cm/s, wave heights up to 1.2?m were observed and turbidity levels varied between 40?mg/l to more than 300?mg/l. The ASM data generally showed uniform concentration profiles. However, profiles with steep concentration gradients near the bed were found for wave heights above 0.5?m. The field experiments further revealed pronounced 3D structures near the bed during discrete storms. The results are generalized for a wider range of conditions and across the full water depth through application of a 1DV point model, using a two-fraction representation of the grain size distribution. The fine and coarse fractions are found to resuspend rapidly for wind speeds above 5?m/s and 10??2?m/s, respectively, forming a uniform concentration profile if these wind conditions persists. High-concentration (???g/l) layers near the bed, containing the coarse sediment fraction, only occur at the onset and towards the end of a storm, when wind speed changes rapidly. It is under these conditions that horizontal gradients in layer density or thickness can transport considerable fine sediment. This transport provides an additional mechanism for the infill of, for instance, silt traps and navigation channels.     

V oxidation state in Fe–Ti oxides by high-energy resolution fluorescence-detected X-ray absorption spectroscopy

The oxidation state of vanadium in natural and synthetic Fe–Ti oxides is determined using high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS). Eleven natural magnetite-bearing samples from a borehole of the Main Magnetite Layer of the Bushveld Complex (South Africa), five synthetic Fe oxide samples, and three natural hematite-bearing samples from Dharwar supergroup (India) are investigated. V K edge spectra were recorded on the ID26 beamline at the European Synchrotron Radiation Facility (Grenoble, France), and the pre-edge features were used to determine the local environment and oxidation state of vanadium. In the case of the magnetite samples (natural and synthetic), we show that vanadium is incorporated in the octahedral site of the spinel structure under two oxidation states: +III and +IV. The variations of the pre-edge area are interpreted as various proportions in V³⁺ and V⁴⁺ (between 9.5 and 16.3% of V⁴⁺), V³⁺ being the main oxidation state. In particular, the variations of the V⁴⁺/V³⁺ ratio along the profile of the Main Magnetite Layer seem to follow the crystallization sequence of the layer. In the case of the hematite samples from India, the pre-edge features indicate that vanadium is substituted to Fe and mainly incorporated as V⁴⁺ (between 40 and 72% of V⁴⁺). We also demonstrate the potentiality of HERFD-XAS for mineralogical studies, since it can filter out the unwanted fluorescence and give better resolved spectra than conventional XAS.     

Institutional capacity-building for targeting sea-level rise in the climate adaptation of Swedish coastal zone management. Lessons from Coastby

For coastal areas across the world, sea-level rise and problems of coastal erosion and coastal flooding are expected to increase over the next hundred years. At the same time political pressure for continued waterfront planning and development of coastal areas threatens to increase our societal vulnerability, and necessitating climate adaptation in coastal zone management. The institutional dimension has been identified as important for ensuring a more robust adaptation to both current climate variability and future climate change. In this paper, lessons regarding institutional constraints for climate adaptation are drawn from a Swedish case-study on local coastal zone management, illustrating the diverse and complex nature of institutional capacity-building. The aim of the paper is to illustrate critical factors that from an institutional perspective condition the capacity to achieve a more integrated, strategic and proactive climate adaptation and for turning “rules on paper” to working practice, based on case-study experiences from Coastby. Following and expanding a framework for analysing institutional capacity-building we learnt that a selective few key actors had played a critical role in building a strong external networking capacity with a flip-side in terms of a weak internal coordinating capacity and lack of mutual ownership of coastal erosion between sectoral units e.g. risk-management, planning and environment. We also found a weak vertical administrative interplay and lack of formal coherent policy, procedures and regulations for managing coastal erosion between local, regional and national administrations. Further, tensions and trade-offs between policy-agendas, values and political priorities posed a barrier for capacity-building in coastal zone management which calls for processes to mediate conflicting priorities in policy-making, planning and decision-making. The case-study suggests that the ability of the political administrative system to acknowledge and deal with institutional conflicts is a critical condition for ensuring an integrated and proactive climate adaptation in coastal zone management.     

Warming permafrost in European mountains

Here we present the first systematic measurements of European mountain permafrost temperatures from a latitudinal transect of six boreholes extending from the Alps, through Scandinavia to Svalbard. Boreholes were drilled in bedrock to depths of at least 100 m between May 1998 and September 2000. Geothermal profiles provide evidence for regional-scale secular warming, since all are nonlinear, with near-surface warm-side temperature deviations from the deeper thermal gradient. Topographic effects lead to variability between Alpine sites. First approximation estimates, based on curvature within the borehole thermal profiles, indicate a maximum ground surface warming of +1 °C in Svalbard, considered to relate to thermal changes in the last 100 years. In addition, a 15-year time series of thermal data from the 58-m-deep Murtèl–Corvatsch permafrost borehole in Switzerland, drilled in creeping frozen ice-rich rock debris, shows an overall warming trend, but with high-amplitude interannual fluctuations that reflect early winter snow cover more strongly than air temperatures. Thus interpretation of the deeper borehole thermal histories must clearly take account of the potential effects of changing snow cover in addition to atmospheric temperatures.     

Local galactic evolution

The evolution of the Solar neighbourhood is followed using a unique, magnitude complete and kinematically unbiased sample of 14,000 F, G, and K dwarfs. Metallicity, age, space motion and galactic orbits have been determined for all stars. The result is a detailed view of the complex evolution of the local Milky Way, which must be matched by any model for the chemical and dynamical evolution of the Galactic disk. E.g., such models must explain the shape and large scatter in the age-metallity relation as well as the overall metallicity distribution; the evolution of stellar kinematics with age; the distribution of stars in velocity space; and the contributions from the thick and thin disks to all these relations. This revised version was published online in August 2006 with corrections to the Cover Date.     

Latitudinal Variations of Diurnal Meteor Rates

The presence of a diurnal variation in meteor activity is well established. The sporadic meteor count rates are higher on the local dawn side and lower on the local dusk side. This phenomenon is caused by the Earth’s orbital motion and rotation. Meteor radar measurements have been compared from Esrange, Kiruna, Sweden, at 68° N, from Juliusruh, Germany, at 55° N, and from Ascension Island, at 8° S, to investigate how the diurnal variation depends on season at different latitudes. Data have been used from vernal and autumnal equinoxes and summer and winter solstices to locate the largest seasonal differences.     

Processes controlling solubility of biogenic silica and pore water build-up of silicic acid in marine sediments

Dissolution experiments in batch and flow-through reactors were combined with data on sediment composition and pore water silicic acid profiles to identify processes controlling the solubility of biogenic silica and the build-up of silicic acid in marine sediments. The variability of experimentally determined biogenic silica solubilities is due, in part, to variations in specific surface area and Al content of biosiliceous materials. Preferential dissolution of delicate skeletal structures and frustules with high surface areas leads to a progressive decrease of the specific surface area. This may cause a reduction of the solubility of deposited biosiliceous debris by 10–15%, relative to fresh planktonic assemblages. Dissolution of lithogenic (detrital) minerals in sediments releases dissolved aluminum to the pore waters. This aluminum becomes structurally incorporated into deposited biogenic silica, further decreasing its solubility. Compared to Al-free biogenic silica, the solubility of diatom frustules is lowered by as much as 25% when one out of every 70 Si atoms is substituted by an Al(III) ion.The build-up of silicic acid in pore waters of sediments with variable proportions of detrital matter and biogenic silica was simulated in batch experiments using kaolinite and basalt as model detrital constituents. The steady-state silicic acid concentrations measured in the experiments decreased with increasing detrital-to-opal ratios of the mixtures. This trend is similar to the observed inverse relationship between asymptotic pore water silicic acid concentrations and detrital-to-opal ratios in Southern Ocean sediments. Flow-through reactor experiments further showed that in detrital-rich sediments, precipitation of authigenic alumino-silicates may prevent the pore waters from reaching equilibrium with the dissolving biogenic silica. This agrees with data from Southern Ocean sediments where, at sites containing more than 30 wt.% detrital material, the pore waters remain undersaturated with respect to the experimentally determined in situ solubility of biogenic silica.The results of the study show that interactions between deposited biogenic silica and detrital material cause large variations in the asymptotic silicic acid concentration of marine sediments. The production of Al(III) by the dissolution of detrital minerals affects the build-up of silicic acid by reducing the apparent silica solubility and dissolution kinetics of biosiliceous materials, and by inducing precipitation of authigenic alumino-silicate minerals.