Groundwater flow and velocity in a 500 ka pre-Illinoian till, eastern Iowa

Few hydrology studies have investigated glacial till older than Illinoian time (> 300,000 BP) despite these older tills overlying a large portion of North America. An 8- and 6-well monitoring well nest installed into a 31 m thick pre-Illinoian till sequence near Cedar Rapids, Iowa was characterized using traditional hydrologic methods and chemical tracers. The aquitard system consists of about 9 m of fine-grained oxidized pre-Illinoian till overlying 22 m of unoxidized till and Devonian dolomite bedrock. Hydraulic conductivity ranged from 10⁻⁷ m/s in oxidized till and 10⁻¹⁰ m/s in unoxidized till. Hydraulic head relations indicated downward groundwater flow through the till profile with hydraulic gradients steepest near the unoxidized till/bedrock interface. Tritium and nitrate concentrations indicated recent (< 50 years old) recharge to a depth of 9–12 m below land surface. ¹⁸O and ²H results ranged between −6.2 to −7.9% and −38.0 to −50.9%, respectively, and plotted near the local Meteoric Water Line. A 1 per mil shift toward less negative ¹⁸O values with depth may suggest a climate change signal contained in the till water but more data are needed to verify this trend. Vertical groundwater velocity through the unoxidized till was estimated to range from 0.4 to 5.7 cm/year. The thickness of unoxidized pre-Illinoian till in Linn County was estimated from available records and contoured against vertical travel times to evaluate the effectiveness of pre-Illinoian till in preventing nitrate migration to underlying bedrock aquifers.     

The Earthquake Readiness Scale: The Development of a Valid and Reliable Unifactorial Measure

Preparedness is a key dependent variable in many studies examining people’s response to disasters such as earthquakes. A feature of many studies on this issue, however, is the lack of attention given to psychometric issues when constructing measures of preparedness. With regard to earthquake preparation, for example, many studies could be greatly improved by the use of a valid and reliable measure of preparedness. This research developed such a measure that assessed both low-level preparedness, such as having an emergency kit, and high-level preparedness, such as altering home structures to mitigate damage. Studies of Wellington (New Zealand) residents using two samples totalling n=652 showed that 23 items measuring these different aspects of earthquake preparation could be combined into a reliable, valid, unifactorial scale. This brief scale should have utility in multivariate studies of earthquake preparation, either as a dependent variable, where preparation is the outcome variable of primary interest, or as one of several independent variables, where preparation and other measures predict another outcome variable.     

Compressibility and shear strength of a residual soil

A detailed study was performed to investigate the compressibility and the shear strength of a residual soil in Omdurman, Sudan. The soil resulted from weathering of sandstone and mudstone. The soil is classified as sandy clayey silt (MH-CH) and is generally partially saturated. Consolidation tests were performed to study the compressibility of the soil and UU, CIU and insitu tests (CPT and SPT) were performed to study the shear strength characteristics of the soil. The characteristics of this residual soil can generally be predicted using correlations proposed in the literature for transported soils. The soil is of low to medium compressibility and exhibits slight apparent overconsolidation behavior. The soil dilates during shear and shows no long term effective cohesion. Problems associated with open cuts in this soil are attributed to loss of strength upon saturation.     

Computer microtomography of zircon: A new approach to the selection of targets for U-Pb geochronologic studies

The paper reports results obtained by the complex studying of zircon crystals from rocks of various genesis. Zircon is one of the minerals most often used as geochronometers. It also provides genetic information on superimposed processes that is “recorded” in the external and internal morphology of its crystals. This mineral is thoroughly examined to select its unaltered crystals for U-Pb dating by the single-grain method. Zircon grains are selected with the use of optical and electron microscopy and cathodoluminescence. This publication presents the first results obtained by examining zircon by computer microtomography (μCT) and the results of the studying of the external and internal structure by conventional techniques ([optical microscopy and SEM (SE and CL)]. The paper demonstrates the advantages of the application of the μCT techniques to the selection of targets for U-Pb zircon dating: there is no need for the special preparation of the samples and no material is destructed. However, this technique may be not informative enough if the zircon contains inherited core whose density does not differ from the density of the surrounding mineral.     

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.     

Diffusion-limited REE uptake by eclogite garnets and its consequences for Lu–Hf and Sm–Nd geochronology

Garnets from the Zermatt-Saas Fee eclogites contain narrow central peaks for Lu + Yb + Tm ± Er and at least one additional small peak towards the rim. The REE Sm + Eu + Gd + Tb ± Dy are depleted in the cores but show one prominent peak close to the rim. These patterns cannot be modeled using Rayleigh fractionation accompanied by mineral breakdown reactions. Instead, the patterns are well explained using a transient matrix diffusion model where REE uptake is limited by diffusion in the matrix surrounding the porphyroblast. Observed profiles are well matched if a roughly linear radius growth rate is used. The secondary peaks in the garnet profiles are interpreted to reflect thermally activated diffusion due to temperature increase during prograde metamorphism. The model predicts anomalously low ¹⁷⁶Lu/¹⁷⁷Hf and ¹⁴⁷Sm/¹⁴⁴Nd ratios in garnets where growth rates are fast compared to diffusion of the REE, and these results have important implications for Lu–Hf and Sm–Nd geochronology using garnet.     

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

3D behaviour of contamination in landfill sites using 2D resistivity/IP imaging: case studies in Portugal

Aiming at defining a valid spatial contamination model, resistivity and induced polarization (IP) measurements were used to investigate contamination plumes in the vicinity of two municipal landfills (Ovar and ílhavo). Previous geophysical surveys and underground water samples confirmed the contamination. However 2D resistivity/IP surveys enabled in obtaining a more accurate spatial model. The Ovar survey consisted of two profiles with nine Wenner soundings each; the ílhavo survey was carried out along two individual lines using a Wenner standard pseudo-section. In both situations, negative IP values were found associated with positive IP values, which can be explained mainly by 2D or 3D geometric effects caused by the presence of the conductive plumes. The data were modelled using a 2D inversion program (RES2DINV) and the resulting resistivity and chargeability distributions were displayed as pseudo-sections. The resistivity and chargeability pseudo-sections define the contamination plumes and the sedimentary structure. These case studies illustrate the advantages of 2D resistivity/IP surveys for the mapping of shape and dimension of contamination associated with landfills.