Controls on dissolved inorganic carbon and δC in cave waters from DeSoto Caverns: Implications for speleothem δC assessments

Unraveling the factors controlling the carbon chemistry and transport of carbon within extant karst systems has important implications concerning the assessment of time-series δ¹³C records of speleothems. Here we report the results of a 3-year study of total dissolved inorganic carbon [DIC] and δ¹³C_DIC from cave waters at DeSoto Caverns (Southeastern USA) that offer valuable insight on carbon transport and the accompanied isotope fractionations from end-member sources to speleothems.[DIC] and δ¹³C_DIC values of cave waters range from 0.2 to 6.0 mM and 2.7 to −12.9 (‰ VPDB), respectively. [DIC] and δ¹³C_DIC of “seasonal drips” show seasonal, albeit noisy, variability and are inversely related (δ¹³C_DIC = −2.49[DIC] + 0.64, r² = 0.84). A shallow pool fed by multiple drips shows a bimodal δ¹³C_DIC distribution with an isotopically heavier mode during winter (−4‰ to −5‰ VPDB) relative to summer months (−9‰ to −10‰ VPDB). A multi-year trend of decreasing water availability during the study period is not reflected in a response of cave water carbon chemistry suggesting that rainfall amount may not be a significant controlling factor of the carbon chemistry. Coupled cave air winter ventilation/summer stagnation and varying CO₂ fluxes through the soil horizon and epikarst exert the strongest influence on seasonal [DIC] and δ¹³C_DIC variability. Measured values of high [DIC] and low δ¹³C_DIC from cave waters collected during the summer/early fall closely approximate isotopic equilibrium conditions. Conversely, low [DIC] and high δ¹³C_DIC values during winter/early months indicate kinetically enhanced isotopic fractionations within the cave waters. The kinetically enhanced isotopic fractionation of partitioned between degassed CO₂ and precipitated CaCO₃(1000lnα_{[(CO2-HCO3)+(CaCO3(AR)-HCO3)]/2}) is greater by about a factor of two (−6.7 ± 0.3‰) relative to the same isotopic fractionation under equilibrium conditions (−3.1‰).On the basis of ¹⁴C mass balance and paired ¹⁴C-U/Th measurements we estimate that on average about ∼23% of C delivered annually by the drips to the aragonite stalagmites is derived from ¹⁴C-dead dolomite cap while the remainder of ∼77% is derived from ¹⁴C-live biomass. δ¹³C measurements of aragonite (n = 12) sampled from the tips of active speleothems during the summer months are consistent with theoretical aragonite δ¹³C values calculated using the shallow pool summer/early fall data thus confirming the δ¹³C seasonality in both drips and coeval aragonite. δ¹³C values of an active stalagmite section spanning the last 200 years show a normal distribution with a mean of −7.1 ± 1.2‰ (n = 81) and a mode of −7‰ to −8‰ that are statistically indistinguishable from the annual mean and mode of all dripwaters. Thus secular time-series δ¹³C records of stalagmites at DeSoto Caverns with resolving power >10⁻¹ year will likely carry the imprints of drip annual means that record climate-driven δ¹³C seasonal biases.     

Spectroscopic Observations of the 2011 Draconids Meteor Shower

Some past October Draconid shower meteoroids fell apart in a spray of fragments at the end of their trajectory before slowing down, from which it was concluded that these were among the most fragile meteoroids known. In those instances, the dust could not be reliably traced to a particular return of the parent comet 21P/Giaconini-Zinner. On October 8th, 2011, Earth was predicted to transverse the 1900 A.D. dust ejecta of the comet. In 1900, the comet’s perihelion distance first moved significantly inwards to the Sun and ejection conditions could have been unusual. An airborne observing campaign was organized, with several teams contributing imaging and spectrographic cameras to study the manner in which these meteoroids released the volatile element sodium during the ablation process in the Earth’s atmosphere. IMCCE, ESA, and the SETI Institute contributed spectrographic cameras based on low-light WATEC 902H2 Ultimate, low-light LCC1, and GenII XX1332 image intensified cameras. An outburst was observed, much as predicted. Despite a lack of bright meteors, a total of 15 Draconid spectra were recorded. All show evidence of an early release of sodium. The loss of sodium was observed to coincide with the formation of a distinct wake of fragments. The observations show that 21P/Giacobini-Zinner ejected fragile meteoroids during the return in 1900. Those grains may have lost some sodium even before impacting Earth.     

Application of kinematic wave theory for predicting flash flood hazards on coupled alluvial fan–piedmont plain landforms

A rainstorm that caused a severe flash flood on the piedmont plain at the toe positions of two alluvial fans located to the west of the Organ Mountains in Dona Ana County, New Mexico, USA, is analysed. The space–time distributions of rainfall are evaluated from the Next Generation Weather Radar (NEXRAD) and overland flow is modelled as kinematic wave. The spatial distribution of rainfall shows a topographic control. The greatest rainfall depth, duration, and intensity occurred at the higher elevation mountain slopes and decreased with decreasing elevation from the alluvial fans to the piedmont plain. The alluvial fan–piedmont plain system is modelled by coupling divergent and rectangular overland flow planes. Explicit finite difference approximations, hybridized with the analytical method of characteristics, are made to the kinematic wave equations to account for the spatial and temporal distribution of the rainfall and variable boundary conditions. Simulation results indicate that sheet‐flow floodwater elevations rise (1) in a nonlinear fashion from the apex to toe positions of the alluvial fans, and (2) near linearly from the toe positions of the alluvial fans onto the piedmont plains with the formation of kinematic shocks near the middle to the upstream end of the plane at times between the initiation of the rainstorm and the time of concentration of the plane. Thus, the maximum flooding occurs at the middle or upstream sections of the piedmont plains regardless of the pattern of space–time variability of rainfall. These results are in agreement with observed geomorphologic features suggesting that piedmont plains are naturally flood‐prone areas. This case study demonstrates that flood hazards on piedmont plains can exceed those on alluvial fans. The models presented in this study suggest that the flood hazard zones on coupled alluvial fan–piedmont plain landforms should be delineated transverse to the flow directions, as opposed to the flood hazard zones with boundaries in the longitudinal direction of the axis of an alluvial fan. Copyright © 2003 John Wiley & Sons, Ltd.     

3D seismic technology: the geological 'Hubble'

The proliferation of three‐dimensional (3D) seismic technology is one of the most exciting developments in the Earth Sciences over the past century. 3D reflection seismic data provide interpreters with the ability to map structures and stratigraphic features in 3D detail to a resolution of a few tens of metres over thousands of square kilometres. It is a geological ‘Hubble’, whose resolving power has already yielded some fascinating (and surprising) insights and will continue to provide a major stimulus for research into geological processes and products for many decades to come. Academic and other research institutions have a major role to play in the use of this data by exploiting the enormous volume of geological information contained in 3D seismic surveys. This paper reviews some of the recent advances in basin analysis made using the medium of 3D seismic data, focusing on the fields of structural and sedimentary geology, fluid–rock interactions and igneous geology. It is noted that the increased resolution of the 3D seismic method provided the essential catalyst necessary to stimulate novel observations and discover new geological structures such as mud diapir feeders, km‐long gas blow‐out pipes, giant pockmarks and sandstone intrusions, and to capture the spatial variability of diagenetic fronts. The UKs first impact crater was also discovered using 3D seismic data. The potential for future developments in this field of geophysical interpretation is considerable, and we anticipate that new discoveries will be made in many years to come.     

Evaluation of Vapor Intrusion Risk from Ethylene Dibromide Using the Vertical Screening Distance Approach

Vapor intrusion (VI) occurs when volatile contaminants in the subsurface migrate through the vadose zone into overlying buildings. The 2015 U.S. EPA petroleum VI guidance recommends that additional investigation of the VI risk from gasoline hydrocarbons at the underground storage tank (UST) sites is not necessary where the vertical distance between a building and a vapor source exceeds a recommended vertical screening distance. However, due to the lack of soil-gas data on the attenuation of ethylene dibromide (EDB), additional VI investigations to evaluate VI risk from EDB are recommended at UST sites with leaded gasoline releases containing EDB. We analyzed soil-gas and groundwater concentrations of EDB from eight petroleum UST sites using a new analytical method with soil-gas detection limit <0.16 μg/m³ EDB (VI screening level at the 10⁻⁶ risk level). The analysis included (1) assessing the frequency of EDB detections ≤0.16 μg/m³ at various vertical separation distances and (2) predicting vertical screening distances for EDB using the U.S. EPA PVIScreen model for different soil types in the vadose zone above dissolved-phase and LNAPL sources. Ranges of estimated aerobic biodegradation rate constants for EDB, air exchange rates for residential buildings, and source vapor concentrations for other constituents were combined with conservative estimates of EDB source concentrations as model inputs. Concentrations of EDB in soil-gas indicated that the U.S. EPA recommended vertical screening distances are protective of VI risk from EDB. Conversely, vertical screening distances predicted by modeling were >6 ft (1.8 m) for sites with sand and loam soil above dissolved phase sources and >15 ft (4.6 m) for sites with sand soil above LNAPL sources. This predicted dependence on the vapor source type and soil type in the vadose zone highlights the importance of soil characterization for VI screening at sites with EDB sources.     

Neil Smith, 1954–2012: “The Future is Indeed Radically Open”

Investors in single-family residential properties have played a crucial role in the United States foreclosure crisis. In this paper, we analyze investor behavior in the diverse urban housing market of Fulton County, Georgia. We examine the composition of buyers of lender-owned properties at two different stages of the foreclosure crisis, and analyze the intrametropolitan geography of investment. Results indicate that large-scale investors are most active in low-value housing submarkets with high poverty and vacancy rates.     

Probabilistic assessment of wildfire hazard and municipal watershed exposure

The occurrence of wildfires within municipal watersheds can result in significant impacts to water quality and ultimately human health and safety. In this paper, we illustrate the application of geospatial analysis and burn probability modeling to assess the exposure of municipal watersheds to wildfire. Our assessment of wildfire exposure consists of two primary components: (1) wildfire hazard, which we characterize with burn probability, fireline intensity, and a composite index, and (2) geospatial intersection of watershed polygons with spatially resolved wildfire hazard metrics. This effort enhances investigation into spatial patterns of fire occurrence and behavior and enables quantitative comparisons of exposure across watersheds on the basis of a novel, integrated measure of wildfire hazard. As a case study, we consider the municipal watersheds located on the Beaverhead-Deerlodge National Forest (BDNF) in Montana, United States. We present simulation results to highlight exposure across watersheds and generally demonstrate vast differences in fire likelihood, fire behavior, and expected area burned among the analyzed municipal watersheds. We describe how this information can be incorporated into risk-based strategic fuels management planning and across the broader wildfire management spectrum. To conclude, we discuss strengths and limitations of our approach and offer potential future expansions.     

A subsurface evacuation model for submarine slope failure

Analysis of three-dimensional (3D) seismic reflection data from the Norwegian continental margin provides an insight into an unusual, buried submarine slope failure, which occurred adjacent to the later Holocene-age Storegga Slide. The identified failure, informally named the 'South Vøring Slide' (SVS), occurs in fine-grained hemipelagic and contourite sediments on a slope of 0.5°, and is characterised by a deformed seismic facies unit consisting of closely spaced pyramidal blocks and ridges bound by small normal faults striking perpendicular to the slope. The SVS contrasts with other previously described submarine slope failures in that it cannot be explained by a retrogressive model. The defining characteristic is the high relative volume loss. The area affected by sliding has thinned by some 40%, seen in combination with very modest extension in the translation direction, with line length balancing yielding an extension value of only 4.5%. The volume loss is explained by the mobilisation of an approximately 40 m thick interval at the lower part of the unit and its removal from beneath a thin overburden, which subsequently underwent extensional fragmentation. Evidence for the mobilisation of a thick fine-grained interval in the development of a submarine slope failure from a continental margin setting may have implications for the origins of other large-scale slope failures on the Norwegian margin and other glacially influenced margins worldwide.     

Architecture of the deep critical zone in the Río Icacos watershed (Luquillo Critical Zone Observatory,Puerto Rico) inferred from drilling and ground penetrating radar (GPR)

In the critical zone, surficial bedrock interactions result in the formation of a mantle of chemically‐ and physically‐altered material defined here as regolith. In the watershed of the Río Icacos, an upland river draining the Luquillo Mountains in tropical Puerto Rico, we explored the influence of lithology (quartz diorite versus hornfels‐facies volcaniclastic rock) on weathering. Regolith profiles were studied by drilling boreholes and imaging the subsurface using ground penetrating radar (GPR). Overall, the regolith structure is not laterally continuous but rather is punctuated by zones of deep fractures that host in situ weathering, corestones, and colluvial material. GPR images of these vertical zones show reflectors at 15–20 m depth. Thus, the architecture of the critical zone in the upper Luquillo Mountains is highly dependent on lithology and its influence on fracture development. At the highest elevations where hornfels overlies quartz diorite, positive feedbacks occur when the water table drops so that oxidative weathering of biotite in the more felsic rock creates microfractures and allows deeper infiltration of meteoric waters. Such exposure results in some of the fastest weathering rocks in the world and may contribute to formation of the knickpoint in the Río Icacos watershed. This work represents the first study combining GPR and drilling to look at the structure of the deep critical zone and demonstrates: (1) the importance of combining direct methods (such as drilling) with indirect methods (such as GPR) to understand the architecture of the critical zone in tropical systems; (2) the interplay of the surficial stress regime, lithology and climate in dictating the architecture of weathering. Copyright © 2016 John Wiley & Sons, Ltd.