The effect of seawater magnesium on natural fluorescence during estuarine mixing,and implications for tracer applications

Natural fluorescence, which is thought to result from low molecular weight humic and fulvic compounds, can be used as a tracer to distinguish between individual river waters. Natural fluorescence exhibits conservative mixing with seawater, except for a slight fluorescence increase which is sometimes observed in the low salinity range (0–5‰). This increase is not due to the inner filter effect (internal quenching). Laboratory experiments can reproduce this low-salinity natural fluorescence increase. Of the major seawater ions, only magnesium can cause a similar natural fluorescence increase. Variation in sample pH, ionic strength, or particle content cannot explain the natural fluorescence increase, nor does it appear to be related to the estuarine flocculation of humic material. Addition of seawater magnesium to the fluorescent material with subsequent loss of hydrogen ions could enhance fluorescence by adding crosslinking to the structure. Replacement of a fluorescence-depressing metal like copper or iron by magnesium could also enhance fluorescence, essentially by removing the quenching effect of the metal. Experimental data in this study are consistent with both of these possible mechanisms. Calcium also enhances fluorescence, however the effect of seawater calcium during estuarine mixing is not as apparent as the magnesium effect. The implications of this low-salinity natural fluorescence increase with respect to estuarine and coastal tracer applications depend on whether individual rivers mix in the high or low salinity region of an estuary or coastal area.     

Conduit-vent structures and related proximal deposits in the Las Cañadas caldera, Tenerife, Canary Islands

The Las Cañadas caldera wall and the outer slopes of the caldera provide three-dimensional exposures of numerous proximal-welded fallout deposits and have been mapped in detail. As a result, some parts of the Ucanca and Guajara Formations of the stratigraphy of Martí et al. (1994) have been divided into members that correspond to individual eruptions. Mapping has also revealed the occurrence of conduit-vent structures associated with proximal-welded fallout deposits. Conduit-vent structures consist of an upper flaring area and a lower narrow conduit. Conduit-vent geometry and dimensions include cylindrical plugs and eruptive fissures steeply dipping towards the caldera depression and elongated vents. The flaring area can be rather asymmetric and is usually filled by down-vent rheomorphic flow of the proximal fallout deposit. The lower conduits are filled by lava plug, agglutination of juveniles onto conduit walls and dyke intrusion with eventual dome extrusion. The eruption dynamics of welded fallout deposits and magma fragmentation within the conduit are consistent with an evolution from explosive to effusive. In this context conduit flow regimes evolve from turbulent to annular flow in which the conduit is progressively choked, and laminar flow leading to the final conduit closure.     

Intercomparison of the LASCO-C2, SECCHI-COR1, SECCHI-COR2, and Mk4 Coronagraphs

In order to assess the reliability and consistency of white-light coronagraph measurements, we report on quantitative comparisons between polarized brightness [pB] and total brightness [B] images taken by the following white-light coronagraphs: LASCO-C2 on SOHO, SECCHI-COR1 and -COR2 on STEREO, and the ground-based MLSO-Mk4. The data for this comparison were taken on 16?April 2007, when both STEREO spacecraft were within 3.1^° of Earth??s heliographic longitude, affording essentially the same view of the Sun for all of the instruments. Due to the difficulties of estimating stray-light backgrounds in COR1 and COR2, only Mk4 and C2 produce reliable coronal-hole values (but not at overlapping heights), and these cannot be validated without rocket flights or ground-based eclipse measurements. Generally, the agreement between all of the instruments?? pB values is within the uncertainties in bright streamer structures, implying that measurements of bright CMEs also should be trustworthy. Dominant sources of uncertainty and stray light are discussed, as is the design of future coronagraphs from the perspective of the experiences with these instruments.     

Reanalysing strong-convective wind damage paths using high-resolution aerial images

Natural Hazards - High-resolution aerial imagery may provide very detailed information about strong-convective wind events, which can be very useful to enhance and make more robust severe weather...     

Evaluating functional connectivity in a small agricultural catchment under contrasting flood events by using UAV

Concentrated erosion, a major feature of land degradation, represents a serious problem for soil and water resources management and a threat to ecosystems. Understanding the internal mechanisms (de-)coupling sediment pathways can improve the management and resilience of catchments. In this study, concentrated erosion and deposition forms were mapped accurately through field and aerial unmanned aerial vehicle (UAV) campaigns, in order to assess the evolution of connectivity pathways over a series of three contrasted and consecutive flood events occurring between October 2016 and January 2017 (return period ranging from 0.5 to 25 years) in a small Mediterranean agricultural catchment (Can Revull, Mallorca, Spain; 1.4 km²). In addition, a morphometric index of connectivity (IC) was used to identify the potential trajectories of different concentrated erosion forms and deposition areas. IC predictions were calibrated by identifying the optimal critical thresholds, i.e. those most consistent with field observations after each of the events studied. The results found that the index performed well in predicting the occurrence and the length/area of the different type of landforms, giving kappa (κ) coefficients of variation ranging between 0.21 and 0.92 and linear correlations R² between 0.33 and 0.72. The type of landform affected the correspondence of IC predictions and field observations, with lower thresholds the greater the magnitude of their associated geomorphic processes. Rainfall magnitude proved to be a very important factor controlling the development of erosion and deposition landforms, with large differences in length/area between the contrasted events. The evolution of the observed trajectories revealed feedback dynamics between the structural and functional connectivity of the catchment, in which morphological changes determined the spatial distribution of the processes’ activity in the successive events and vice versa. © 2020 John Wiley & Sons, Ltd.     

A crystal-chemical classification of borate structures with emphasis on hydrated borates

The rules governing formation of hydrated borate polyanions that were proposed by C.L. Christ in 1960 are critically reviewed and new rules added on the basis of recent crystal structure determinations. Principles and classifications previously published by others are also critically reviewed briefly. The fundamental building blocks from which borate polyanions can be constructed are defined on the basis of the number n of boron atoms, and the fully hydrated polyanions are illustrated. Known structures are grouped accordingly, and a shorthand notation using n and symbols Δ = triangle, T = tetrahedron is introduced so that the polyanions can be easily characterized. For example, 3:Δ+2T describes [B₃O₃(OH)₅]^2?. Correct structural formulas are assigned borates with known structures whereas borates of unknown structure are grouped separately.     

Applying Fractal Dimensions and Energy-Budget Analysis to Characterize Fracturing Processes During Magma Migration and Eruption: 2011–2012 El Hierro (Canary Islands) Submarine Eruption

The impossibility of observing magma migration inside the crust obliges us to rely on geophysical data and mathematical modelling to interpret precursors and to forecast volcanic eruptions. Of the geophysical signals that may be recorded before and during an eruption, deformation and seismicity are two of the most relevant as they are directly related to its dynamic. The final phase of the unrest episode that preceded the 2011–2012 eruption on El Hierro (Canary Islands) was characterized by local and accelerated deformation and seismic energy release indicating an increasing fracturing and a migration of the magma. Application of time varying fractal analysis to the seismic data and the characterization of the seismicity pattern and the strain and the stress rates allow us to identify different stages in the source mechanism and to infer the geometry of the path used by the magma and associated fluids to reach the Earth’s surface. The results obtained illustrate the relevance of such studies to understanding volcanic unrest and the causes that govern the initiation of volcanic eruptions.     

Methodology for the computation of volcanic susceptibility: An example for mafic and felsic eruptions on Tenerife (Canary Islands)

A new method to calculate volcanic susceptibility, i.e. the spatial probability of vent opening, is presented. Determination of volcanic susceptibility should constitute the first step in the elaboration of volcanic hazard maps of active volcanic fields. Our method considers different criteria as possible indicators for the location of future vents, based on the assumption that these locations should correspond to the surface expressions of the most likely pathways for magma ascent. Thus, two groups of criteria have been considered depending on the time scale (short or long term) of our approach. The first one accounts for long-term hazard assessment and corresponds to structural criteria that provide direct information on the internal structure of the volcanic field, including its past and present stress field, location of structural lineations (fractures and dikes), and location of past eruptions. The second group of criteria concerns to the computation of susceptibility for short term analyses (from days to a few months) during unrest episodes, and includes those structural and dynamical aspects that can be inferred from volcano monitoring. Thus, a specific layer of information is obtained for each of the criteria used. The specific weight of each criterion on the overall analysis depends on its relative significance to indicate pathways for magma ascent, on the quality of data and on their degree of confidence. The combination of the different data layers allows to create a map of the spatial probability of future eruptions based on objective criteria, thus constituting the first step to obtain the corresponding volcanic hazards map. The method has been used to calculate long-term volcanic susceptibility on Tenerife (Canary Islands), and the results obtained are also presented.     

Community structure and dynamics of deep-water decapod assemblages from Le Danois Bank (Cantabrian Sea, NE Atlantic): Influence of environmental variables and food availability

The community structure of the decapod crustaceans inhabiting Le Danois Bank (Cantabrian Sea, NE Atlantic Ocean) was studied on two cruises performed in October 2003 and April 2004. Otter and beam-trawls were used to collect this fauna. At depths ranging between 455 and 1048 m, we found distinct decapod assemblages on the bank summit and deeper in the inner basin (between the bank and the continental shelf). The faunal discontinuity between these groups appeared at around 600 m (e.g. between 612 and 642 m in the basis of species replacement). The summit assemblage was characterized by low diversity (in terms of number and relative abundances of species) and by the dominance of hermit crabs (Pagurus alatus, Anapagurus laevis, Pagurus excavatus), the crangonid Pontophilus spinosus and the squat lobster Munida sarsi. Species characterizing the deeper assemblage, which was richer in terms of diversity, were Munida tenuimana, Parapagurus pilosimanus, Pontophilus norvegicus, the crab Geryon trispinosus and a number of bathypelagic shrimps (Sergia robusta, Acanthephyra pelagica and Pasiphaea tarda). Changes in decapod composition characterized by multidimensional scaling analyses were correlated with different variables, e.g. %mud and %organic matter (OM), temperature and salinity close to the bottom. Among those the %OM and %mud in sediments affected decapod distributions the most. The summit of the bank was covered by fine sediments with low proportion of mud (13.9–29.3%) and OM (2.55–3.50%). By contrast, sediment of the inner basin had a higher proportion of OM and mud (64.1–84.2%; 6.26–7.00%, respectively). The low proportion of mud at the summit of Le Danois Bank may explain the absence or scarcity of burrowing species (e.g. the lobster Nephrops norvegicus, the shrimps Calocaris macandreae and Alpheus glaber and the crab Goneplax rhomboides), that are dominant at similar depths (400–500 m) in the upper muddy assemblage on the mainland-continental slope in the Bay of Biscay (44–46°N). The dominance of certain species on the summit of submarine mounts can probably be related to their biology and feeding ecology. For example, pagurids are deposit feeders, even consuming marine snow (e.g. Chl-a identified in guts of Pagurus alatus), and they have low gut fullness (probably indicating a capacity to withstand long periods under starvation), that would favour their adaptability to a rather unpredictable habitat such as Le Danois Bank summit. Regarding prey availability, zooplankton/micronekton and infauna distributed around Le Danois Bank showed different depth-related patterns. Among zooplankton, mesopelagic decapods, mysids, and fishes were absent at the bank summit, while euphausiids exhibited high abundances over the summit. No significant trends with depth were found for infauna abundance, and for instance polychaete densities were similar both at the summit and the inner basin. Therefore, prey availability was lower for summit assemblages regarding zooplankton/micronekton. Patterns in mean size vs. depth were species specific for decapods, and the possible role of the bank summit as a recruitment area was not general for the whole decapod assemblage.