Phase relationship between sea level and abrupt climate change

Direct traces of past sea levels are based on the elevation of old coral reefs at times of sea level highstands. However, these measurements are discontinuous and cannot be easily correlated with climate records from ice cores. In this study we show a new approach to recognizing the imprint of sea level changes in continuous sediment records taken from the continental slope at locations that were continuously submerged, even during periods of sea level lowstand. By using a sediment core precisely synchronized with Greenland ice cores, we were able to recognize major floods of the Mediterranean continental shelf over the past 270 kyr. During the last glacial period five flooding events were observed at the onset of the warmest Greenland interstadials. Consistent correspondence between warm climate episodes and eustatic sea level rises shows that these global flooding events were generated by pronounced melting of the Northern Hemisphere ice sheets, due to rapid intensification of Atlantic Meridional Overturning Circulation.The method described in this study opens a new perspective for inter-hemispheric synchronization of marine climate records if applied in other continental margins from the Southern Hemisphere or the equatorial regions.     

Speciation and Photochemistry of Mercury in Rainwater

Mercury speciation was determined in rainwater from 76 storms in southeastern North Carolina between September 1, 2003 and September 30, 2005. Volume-weighted average concentrations of total Hg (THg), total dissolved Hg (TDHg), particulate Hg (Hg_part) and dissolved monomethyl Hg (MMHg) were 45.5 pM, 34.8 pM, 12.0 pM and 1.1 pM respectively. TDHg accounted for 77% of THg in precipitation which is similar to Cu but significantly higher than Cr or Fe. Concentrations of the various Hg species were very similar during summer and winter indicating that there was not a dominant seasonal influence on Hg speciation in rainwater at this location. THg, TDHg, and MMHg concentrations were also not significantly impacted by storm origin suggesting that they are relatively well mixed regionally and that air mass back trajectory is not the dominant factor controlling their concentration at this location. Concentrations of TDHg and Hg_part were inversely correlated in rainwater samples subjected to irradiation with simulated sunlight, suggesting the distribution between dissolved and particulate Hg may be controlled by photochemical transformations. Unlike TDHg and Hg_part, no significant changes in MMHg were observed upon photolysis of rainwater indicating that its distribution is not significantly driven by sunlight-mediated reactions, in contrast to what has been observed in surface waters. Results presented in this study indicate that the speciation of Hg in rainwater is dynamic and is driven by a complex combination of natural and anthropogenic processes as well as interactions with sunlight.     

Middle and late Holocene climate change and human impact inferred from diatoms,algae and aquatic macrophyte pollen in sediments from Lake Montcortès (NE Iberian Peninsula)

During the middle and late Holocene, the Iberian Peninsula underwent large climatic and hydrologic changes, but the temporal resolution and regional distribution of available palaeoenvironmental records is still insufficient for a comprehensive assessment of the regional variability. The high sedimentation rate in karstic, meromictic Montcortès Lake (Catalan pre-Pyrenees) allows for a detailed reconstruction of the regional palaeoecology over the last 5,340 years using diatom analysis, aquatic pollen, sedimentological data, and historic documentary records. Results show marked fluctuations in diatom species assemblage composition, mainly between dominant Cyclotella taxa and small Fragilariales. We suggest that the conspicuous alternation between Cyclotella comta and C. cyclopuncta reflects changes in trophic state, while the succession of centric and pennate species most likely reflects changes in the hydrology of the lake. The diatom assemblages were used to identify six main phases: (1) high productivity and likely lower lake levels before 2350 BC, (2) lower lake levels and a strong arid phase between 2350 and 1850 BC, (3) lake level increase between 1850 and 850 BC, (4) relatively high lake level with fluctuating conditions during the Iberian and Roman Epochs (650 BC–350 AD), (5) lower lake levels, unfavourable conditions for diatom preservation, eutrophication and erosion triggered by increased human activities in the watershed during the Medieval Climate Anomaly (900–1300 AD), and (6) relatively higher lake levels during the LIA (1380–1850 AD) and afterwards. The combined study of diatoms, algae and pollen provides a detailed reconstruction of past climate, which refines understanding of regional environmental variability and interactions between climate and socio-economic conditions in the Pyrenees.     

Distribution of extreme solar energetic proton fluxes

The knowledge of the high intensity tails of probability distributions that determine the rate of occurrence of extreme events of solar energetic particles is a critical element in the evaluation of hazards for human and robotic space missions. Here instead of the standard approach based on fitting a selected distribution function to the observed data we investigate a different approach, which is based on a study of the scaling properties of the maximum particle flux in time intervals of increasing length. To find the tail of the probability distributions we apply the “Max-Spectrum” method (Stoev, S.A., Michailidis, G., 2006. On the estimation of the heavy-tail exponent in time series using the Max-Spectrum. Technical Report 447, Department of Statistics, University of Michigan) to 1973–1997 IMP-8 proton data and the 1987–2008 GOES data, which cover a wide range of proton energies. We find that both data sets indicate a power-law tail with the power exponents close to 0.6 at least in the energy range 9–60 MeV. The underlying probability distribution is consistent with the Fréchet type (power-law behavior) extreme value distribution. Since the production of high fluxes of energetic particles is caused by fast Coronal Mass Ejections (CMEs) this heavy-tailed distribution also means that the Sun generates more fast CMEs than would be expected from a Poissonian-type process.     

Trace element concentrations in nesting flatback turtles (Natator depressus) from Curtis Island, Queensland, Australia

The blood and eggs of the flatback turtle (Natator depressus) sampled when nesting at Curtis Island, Queensland, Australia. In the blood, zinc was present at the highest concentration of 151.15 ± 1.45 μg/L followed by copper (7.74 ± 0.09 μg/L). Lead was found only in some individuals. The measured trace elements in the blood were maternally transferred into the eggs. Other metals and metalloids detected in eggs were chromium, manganese, arsenic and selenium. Eggs showed a more complex trace element profile than blood, suggesting that they provided more representative tissues for determining maternal levels of trace element accumulation in N. depressus. Intra-clutch variation was over 15% for most of the studied trace elements suggesting one egg is not in sufficient to determine trace element accumulation within a clutch. Copper was the only element which was positively correlated with breeding age. Furthermore, no detectable levels of tin compound derivates were measured in N. depressus.     

Modelling the physical and chemical changes in roofing slate caused by weathering processes

This research identifies the changes which takes place in roofing slate due to natural exposure and tries to replicate these changes experimentally. Traditional methods of testing, used by the British and other national standards, concentrate on the properties of unweathered samples and give no information on the relative durability of the different slates. Instead of concentrating on the initial properties, this research focuses on changes in the properties in order to assess durability. The effects of natural weathering were assessed by comparing old, used slates with new slates from the same or a similar source. The new slates were then weathered experimentally by repeated cycles of wetting and drying, and the increase in water absorbency compared with that observed in naturally weathering. Mineralogical differences due to both natural and experimental weathering were also measured using X-ray diffraction analysis. It was found that the effects of experimental weathering, using repeated cycles of wetting and drying, are similar to those observed in natural weathering. These include increased water absorbency and loss of crystallinity of the principal minerals. The greatest changes are found in those slates which are the most vulnerable to weathering, making it possible to identify poor quality slates.     

Future variability of droughts in three Mediterranean catchments

This study investigates the intensity change in typhoons and storm surges surrounding the Korean Peninsula under global warming conditions as obtained from the MPI_ECHAM5 climate model using the A1B series. The authors use the Cyclostationary Empirical Orthogonal Function to estimate future background fields for typhoon simulations from twenty-first-century prediction results. A series of numerical experiments applies WRF (Weather Research and Forecasting) and POM (Prinston Ocean Model) models to simulate two historical typhoons, Maemi (2003) and Rusa (2002), and associated storm surges under real historical and future warming conditions. Applying numerical experiments to two typhoons, this study found that their central pressure dropped about 19 and 17 hPa, respectively, when considering the future sea surface temperature (a warming of 3.9 °C for 100 years) over the East China Sea (Exp. 1). The associated enhancement of storm surge height ranged from 16 to 67 cm along the southern coast of the Korean Peninsula. However, when the study considered global warming conditions for other atmospheric variables such as sea-level pressure, air temperature, relative humidity, geopotential height, and wind in the typhoon simulations (Exp. 2), the intensities of the two typhoons and their associated surge heights scarcely increased compared to the results of Exp. 1. Analyzing projected atmospheric variables, the authors found that air temperatures at the top of the storm around 200 hPa increased more than those at the surface in tropical and mid-latitudes. The reduced vertical temperature difference provided an unfavorable condition in the typhoon’s development even under conditions of global warming. This suggests that global warming may not always correlate with a large increase in the number of intense cyclones and/or an increase in associated storm surges.