Our study examined the effects of Corexit 9500 and sediment on microbial mineralization of specific aliphatic and aromatic hydrocarbons found in crude oil. We also measured gross mineralization of crude oil, dispersed crude oil and dispersant by a marine microbial consortium in the absence of sediment. When provided as carbon sources, our consortium mineralized Corexit 9500 the most rapidly, followed by fresh oil, and finally weathered oil or dispersed oil. However, mineralization in short term assays favored particular components of crude oil (2-methyl-naphthalene > dodecane > phenanthrene > hexadecane > pyrene) and was not affected by addition of nutrients or sediment (high sand, low organic carbon). Adding dispersant inhibited hexadecane and phenanthrene mineralization but did not affect dodecane and 2-methyl-naphthalene mineralization. Thus, the effect of dispersant on biodegradation of a specific hydrocarbon was not predictable by class. The results were consistent for both high and low oiling experiments and for both fresh and weathered oil. Overall, our results indicate that environmental use of Corexit 9500 could result in either increases or decreases in the toxicity of residual oil through selective microbial mineralization of hydrocarbons. 相似文献
Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)2+(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented. 相似文献
The paper deals with different kinds of invariant motions (periodic orbits, 2D and 3D invariant tori and invariant manifolds of periodic orbits) in order to analyze the Hamiltonian direct Hopf bifurcation that
takes place close to the Lyapunov vertical family of periodic orbits of the triangular equilibrium point L4 in the 3D restricted three-body problem (RTBP) for the mass parameter, μ greater than (and close to) μR (Routh’s mass parameter). Consequences of such bifurcation, concerning the confinement of the motion close to the hyperbolic
orbits and the 3D nearby tori are also described. 相似文献
We have used the S-056 X-ray data from Skylab to determine quantitative values for the coronal conditions characterizing a new bipolar magnetic region (BMR). In particular, we include: (a) the time variation of the total soft X-ray flux from the BMR as a function of time; (b) the temporal and spatial variation of the temperature and emission measure; (c) the variation with time of thermal energy density; (d) the (calculated) magnetic field configuration and magnetic flux density in the corona; and (e) the temporal variation of the magnetic field energy in the corona. Detailed comparisons are made between the configuration of X-ray features and the magnetic field topology. 相似文献
Lifestyle, indicating preferences towards a particular way of living, is a key driver of the decision of where to live. We
employ latent class choice models to represent this behavior, where the latent classes are the lifestyles and the choice model
is the choice of residential location. Thus, we simultaneously estimate lifestyle groups and how lifestyle impacts location
decisions. Empirical results indicate three latent lifestyle segments: suburban dwellers, urban dwellers, and transit-riders.
The suggested lifestyle segments have intriguing policy implications. Lifecycle characteristics are used to predict lifestyle
preferences, although there remain significant aspects that cannot be explained by observable variables.
Five compositional-textural types of ilmenite can be distinguished in nine kimberlites from the Eastern Dharwar craton of southern India. These ilmenite generations record different processes in kimberlite history, from mantle to surface. A first generation of Mg-rich ilmenite (type 1) was produced by metasomatic processes in the mantle before the emplacement of the kimberlite. It is found as xenolithic polycrystalline ilmenite aggregates as well as megacrysts and macrocrysts. All of these ilmenite forms may disaggregate within the kimberlite. Due to the interaction with low-viscosity kimberlitic magma replacement of pre-existing type 1 ilmenite by a succeeding generation of geikielite (type 2) along grain boundaries and cracks occurs. Another generation of Mg-rich ilmenite maybe produced by exsolution processes (type 3 ilmenite). Although the identity of the host mineral is unclear due to extensive alteration and possibility includes enstatite. Type 4 Mn-rich ilmenite is produced before the crystallization of groundmass perovskite and ulvöspinel. It usually mantles ilmenite and other Ti-rich minerals. Type 5 Mn-rich ilmenite is produced after the crystallization of the groundmass minerals and replaces them. The contents of Cr and Nb in type 2, 4 and 5 ilmenites are highly dependent on the composition of the replaced minerals, they may not be a good argument in exploration. The highest Mg contents are recorded in metasomatic ilmenite that is produced during kimberlite emplacement, and cannot be associated with diamond formation. The higher Mn contents are linked to magmatic processes and also late processes clearly produced after the crystallization of the kimberlite groundmass, and therefore ilmenite with high Mn contents cannot be considered as a reliable diamond indicator mineral (DIM) and kimberlite indicator mineral (KIM).
Abstract Mediterranean rivers are characterized by the irregularity of flow, harsh hydrological fluctuations and a profound transformation as the result of human activity. In this study, we investigate the streamflow response of a Mediterranean temporary river in which different groundwater, agriculture and urban contributions play an important role. Streamflow was measured at three nested gauging stations installed along Na Borges River, a lowland agricultural catchment (319 km2) on the island of Mallorca. Based on two hydrological years (2004/05 and 2005/06), potential evapotranspiration and surface water–groundwater interaction generated a succession of four different hydrological periods playing an important role in baseflow dynamics. The runoff coefficients were very low (<5%). At the event scale, groundwater also controlled runoff response, being very different according to hydrogeology, antecedent conditions and human impacts. During dry seasons, wastewater and karstic spring discharges maintain an influent regime into some streams. As a result, intense rainstorms in late summer generated water volumes over the impervious urban surfaces involved, with the result that quickflow was significant because the hydrological pathways were active. Citation Estrany, J., Garcia, C. & Alberich, R. (2010Estrany, J., Garcia, C. and Batalla, R. J.2010. Hydrological response of a small Mediterranean agricultural catchment. J. Hydrol., 380(1-2): 180–190. doi:10.1016/j.jhydrol.2009.10.035[Crossref], [Google Scholar]) Streamflow dynamics in a Mediterranean temporary river. Hydrol. Sci. J. 55(5), 717–736.相似文献