在某污染的工业废物填埋场环境水文 地质评价中的同位素水文学研究

本文论述了某污染的工业废物填埋场场址的地质、水文地质条件,应用水化学方法、环境同位素技术(地下水中氚及氢、氧稳定同位素)和同位素单孔示踪技术等同位素水文学领域中的新方法对区内地下水的活动条件以及填埋场场址区分布的第四系孔隙潜水和第三纪红层孔隙-裂隙水的成因进行了分析,测量并确定了填埋场下部地下水的流速及流向。研究结果表明场区地下水的运动与地表水无直接水力联系。污染的工业废物填埋后不会通过地下水的迁移造成对地表水的污染,进而证实填埋场的地质、水文地质条件对处置污染的工业废物是安全可靠的。     

贵州二叠纪与南华纪锰矿主要矿床地质特征对比及意义

贵州南华纪古天然气渗漏沉积型锰矿通过成矿理论和找矿预测方法的创新,近年来不断取得巨大的找矿成果,在国内外产生重要影响,已成为国内最重要的锰矿床类型。本文通过对贵州二叠纪锰矿与南华纪锰矿矿床地质特征的对比研究发现:二者在成矿构造背景、同沉积断层(控矿构造)、成矿物质来源、矿石与地球化学特征、锰矿成矿系统特征等方面十分相似,在结构构造特征、沥青球特征、盖帽白云岩和冷泉碳酸盐岩等方面也存在一些差别。在此基础上,贵州二叠纪锰矿通过借鉴和运用贵州南华纪古天然气渗漏沉积成矿理论和找矿预测方法,已在遵义锰矿国家整装勘查区取得重大进展。说明"内生外成"的古天然气渗漏沉积型锰矿成矿理论和找矿预测方法,在相似的成矿地质背景条件下,具有普适性和推广意义。     

Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit,NE China

The Chalukou porphyry Mo deposit, located in the Great Hinggan Range, is the largest Mo deposit in northeast China, although the age and genesis of the associated magmatic intrusions remain debated.Here we report zircon U-Pb ages and trace elements, whole rock geochemistry and Sre Nd isotope data with a view to understand the relationship between the magmatism and molybdenum mineralization.Zircon U-Pb analysis yield an age of 475 Ma for rhyolite in the older strata, 168 Ma for the premineralization monzogranite, and 154 Ma for the syn-mineralization granite porphyry. The granite porphyry and quartz porphyry are considered as the ore-forming intrusions. These rocks are peraluminous, alkali-calcic, and belong to high-K to shoshonitic series with a strong depletion of Eu. They also display characteristics of I-type granites. The rocks exhibit wide variations of(87 Sr/86 Sr)iin the range of 0.705426 -0.707363, and ε_(Nd)(t) of -3.7 to 0.93. Zircon REE distribution patterns show characteristics between crust and the mantle, implying magma genesis through crust-mantle interaction. The Fe_2O_3/FeO values(average 1) for the whole rock and EuN/Eu*Nvalues(average 0.45), Ce~(4+)/Ce~(3+) values(average 301)for zircon grains from the granite porphyry are higher than those from other lithologies. These features suggest that the ore-forming intrusions(syn-mineralization porphyry) had higher oxygen fugacity conditions than those of the pre-mineralization and post-mineralization rocks. The Chalukou Mo deposit formed in relation to the southward subduction of the Mongol-Okhotsk Ocean. Our study suggests that the subduction-related setting, crust-mantle interaction, and the large-scale magmatic intrusion were favorable factors to generate the super-large Mo deposits in this area.     

Decrepitation Thermometry and Compositions of Fluid Inclusions of the Damoqujia Gold Deposit,Jiaodong Gold Province,China:Implications for Metallogeny and Exploration

The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃(2) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO2-4-K type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na /Ca2 type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.     

乳化植物油强化土著微生物修复中高浓度Cr(Ⅵ)污染地下水

以天然细砂为微生物来源,模拟研究了乳化植物油强化原位生物修复中高浓度Cr（Ⅵ）污染地下水的可行性,考察了修复效果及修复过程中地下水质变化及产物的稳定性。结果表明,反应77 d后,Cr（Ⅵ）质量浓度分别从20.0、30.0、50.0、80.0、110.0 mg/L降低到0.0、5.8、19.0、43.6、65.8 mg/L,去除率分别为100.0%、80.7%、61.9%、45.5%、40.2%。反应后介质中Cr形态分析表明,其主要以能在自然条件下稳定存在的铁锰结合态和有机结合态形式存在。此外,随反应进行,实验体系逐渐呈弱酸性环境,pH为5.80~6.70。当Cr被完全还原后,体系会发生异化铁还原,Fe（Ⅱ）质量浓度逐渐升高,最高可达117.0 mg/L,最终形成二价铁矿物。综上所述,天然细砂介质中的土著微生物能够利用乳化植物油强化并还原地下水中的中、高浓度Cr（Ⅵ）,且产物能够在自然状态下稳定存在,修复过程对地下环境的影响较小。     

Sedimentary Facies Architectures of Third-Order Sequences from Early to Middle Triassic in Nanpanjiang Basin

There are complex and regular changes on sedimentary facies from the Early to the Middle Triassic in the Nanpanjiang basin. After the obvious drowned event of carbonate platforms in the transitional period between Permian and Triassic, carbonate platforms have evolved into the ramp type from the rimmed-shelf type. The differentiation of sedimentary facies becomes dearer in space, which are marked by the changes from an attached platform to a turbidity basin and several isolated platforms in the basin. The striking characteristics are the development of oolitic banks on isolated platforms in Nanning and Jingxi and the reef- and bank-limestones in the margin of the attached platform in the Early Triassic. Despite the difference of the time-span and the architectnre of fades succession of third-order sedimentary sequences, the process of the third-order relative sea-level changes reflected by the sedimentary facies succession of the third-order sequences is generally synchronous. Therefore, six third-order sequences could be discerned in the strata from the Early to the Middle Triassic in the Nanpanjiang basin. Using two types of facies changing surfaces and two types of diachronisms in stratigraphic records as the key elements, the sedimentary facies architectures of the third-order sequences that represent sequence stratigraphic frameworks from the Early to the Middle Triassic in the Nanpanjiang basin could be constructed.     

华夏古陆活动大陆边缘的探讨

本文阐述了华南中元古代晚期活动陆缘特征。根据带内前寒武纪地层分布、古地磁、侵入作用、构造变形、深部构造、中元古代晚期沉积作用及火山岩岩石化学特征,证明活动陆缘是南华洋壳向南部古大陆俯冲的产物。武陵运动是华南最重要的运动,华夏古陆与扬子地块碰撞,形成统一的“华南古大陆”。     

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.     

Shear Alteration, Mass Transfer and Gold Mineralization: An Example from Jiaodong Ore Deposit Concentrating Area, Shandong, China

Since Ramsay and Graham (1970 ) system atically deliv-ered study results of ductile shear zone,the study on shearzone has been put forward rapidly and has obtained greatachievements.After the“gold- bearing shear zone” type ofmetallogenic model proposed by Bonnemaison(1986 ) ,lots ofstudies showed that large gold- bearing shear zone system,which underwent multi- stage and multi- level tectonic- m inerl-ization evolution,is a complex deformational metam orphic ge-ological body with different d…     

银根-额济纳旗及邻区石炭-二叠系的沉积特征及石油地质意义

长期以来,由于埋藏深、地质复杂及自然条件恶劣等原因,银根-额济纳旗及邻区石炭系-二叠系的油气勘查程度低,相关研究成果少.鉴于此,本文充分利用研究区的周缘露头,借助近30条剖面的详细调查,分析了本区石炭系-二叠系的沉积特征.研究表明,本区石炭系-二叠系包括了泥岩、砂岩、砂砾岩、碳酸盐岩和火山岩(或火山碎屑岩)等,海相生物丰富.暗色泥岩是石炭系-二叠系的主体,是潜在的烃源岩和盖层;火山岩(或火山碎屑岩)发育,碳酸盐岩多呈透镜状且硅化普遍,砂砾岩相对较少,三者构成石炭系-二叠系重要储层.岩石组成及展布特征表明,石炭纪-二叠纪期间,本区张裂频繁,火山作用强烈,远离陆源区,水体深而宁静,利于生烃物质发育.期间,区内主要发育了浅海相、广海海岸相、碳酸盐台地相、辫状三角洲相、扇三角洲相和火山喷发相等沉积类型.其中,浅海相和局限海岸相主要形成了烃源岩和盖层,其他沉积则形成了储层,为区内石炭系-二叠系造就了良好的油气地质条件.