三江平原西部土壤硒分布特征及其影响因素

近年来在黑龙江三江平原局部地区发现有珍贵的富硒土地,但对三江平原土壤硒的分布以及土壤硒含量的控制因素研究较少.三江平原西部地区土地质量地球化学调查发现,该区表层土壤主要以足硒为主,未见硒中毒土壤,富硒土壤主要分布于完达山山前至沿挠力河之间的冲湖积低平原地区,少量分布于萝北县城北部的湖成剥蚀台地,硒不足或硒潜在不足地区主...     

时间域激电法在浅覆盖区萤石矿勘查中的应用—以河南省方城县铁炉萤石矿床为例

河南省方城县独树镇一带萤石矿区属于第四系浅层覆盖区。为寻找该区隐伏萤石矿床,对区域成矿条件、邻近同类型萤石矿床特征进行了分析研究,将该地区萤石矿赋矿地质体及接触带作为地球物理探测目标体,开展了时间域激发极化法(TDIP)测量。激电中梯与激电测深高低阻之间的电性变化带(或过渡带)和对应的弱极化异常特征,有效地定位和预测了覆盖区萤石矿赋矿地质体、接触带的空间分布特征及蚀变矿化特征,为钻探工程布置提供良好的地球物理信息,经钻探验证,取得了较好的找矿效果。勘查表明：时间域激发极化法在独树镇一带浅覆盖区寻找隐伏萤石矿是行之有效的,可为矿区外围或相似地区进行类比寻找同类型萤石矿床提供重要的指导或示范作用。     

Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

准噶尔盆地吉木萨尔凹陷芦草沟组甜点页岩油微观赋存特征及成因机制

准噶尔盆地吉木萨尔页岩油是中国典型的陆相页岩油。通过场发射扫描电镜、激光共聚焦、纳米CT、核磁共振等实验技术联合对微纳米孔隙中页岩油赋存特征进行研究,结果表明甜点储层具有纳米—亚微米—微米全尺度含油特征。在微纳米尺度,油、水赋存特征表现为重质组分油附着于2~5 μm以上孔隙的孔壁及充填于2~5 μm以下的孔隙中,中质组分油赋存于2~5 μm以上孔隙的中央,孔隙水含量较少,呈孤立状赋存于2~5 μm以上孔隙的中央,并被中质组分油包裹。页岩油在微纳米孔隙中的赋存不仅受生烃超压充注控制,还受吸附作用及多期次成藏影响。孔隙表面润湿性由亲水润湿反转为亲油润湿是烃类发生吸附的主要原因,多期次成藏造成微纳米孔隙中油质差异及高的含油饱和度。早期生烃超压充注进储层的重质组分油在孔隙表面亲油润湿下吸附于孔隙表面,随着吸附层变厚,纳米级孔隙逐渐被充满,孔隙水被驱替到较大的孔隙中间;后期成熟的中质组分油以此方式进一步充注和调整。研究认为埋深较大的凹陷西部是有利勘探方向。微纳米孔隙中的重质组分油是未来页岩油提高采收率的方向。吉木萨尔页岩油微观赋存特征及成因机制可能具有普遍性,对于中国陆相页岩油的深入研究具有借鉴意义。     

The relationship between groundwater and natural vegetation in Qaidam Basin

To accurately evaluate ecological risks trigged by groundwater exploitation, it must be clarified the relationship between vegetation and groundwater. Based on remote sensing data sets MOD13Q1, groundwater table depth (WTD) and total dissolved solids (TDS), the relationship between groundwater and natural vegetation was analyzed statistically in the main plain areas of Qaidam Basin. The results indicate that natural vegetation is groundwater-dependent in areas where WTD is less than 5.5 m and TDS is less than 7.5 g/L. Aquatic vegetation, hygrophytic vegetation and hygrophytic saline-alkali tolerant vegetation are mainly distributed in areas with WTD <1.1 m. Salt-tolerant and mesophytic vegetation mainly occur in areas with WTD of 1.4-3.5 m, while the xerophytic vegetation isprimarily present in areas where WTD ranges from 1.4 m to 5.5 m. Natural vegetation does not necessarily depend on groundwater in areas with WTD >5.5 m. For natural vegetation, the most suitable water TDS is less than 1.5 g/L, the moderately suitable TDS is 1.5-5.0 g/L, the basically suitable TDS is 5.0-7.5 g/L, and the unsuitable TDS is more than 7.5 g/L.     

早古生代阿拉善地块与华北地块之间的关系:来自阿拉善东缘中奥陶统碎屑锆石的信息

阿拉善东缘奥陶纪地层位于鄂尔多斯(华北地块)与北祁连早古生代造山带之间的过渡地区,该区的构造背景一直是长期争论的问题,它涉及到阿拉善地块是否与华北地块相连、奥陶系的物源以及"贺兰拗拉槽"是否存在等问题。分布于阿拉善地块东缘的中奥陶统米钵山组的碎屑锆石LA-ICP-MSU-Pb年龄测试表明,样品中数量最多的锆石年龄为900～950Ma,Alxa-1的峰值年龄为916Ma,Alxa-2的峰值年龄为953Ma,次者在494～623Ma之间,这个区间内存在多个峰值,如Alxa-1存在505Ma和588Ma两个主要峰值,Alxa-2则存在494Ma、517Ma、623Ma等几个峰值。在2.5Ga左右两个样品都存在一个弱的峰值,Alxa-1峰值为2517Ma,而Alxa-2峰值为2552Ma和2670Ma。除此之外,两个样品都有个别大于3.0Ga的成分,Alxa-1样品中最年轻的锆石为451±8Ma,Alxa-2样品则为483±4Ma。这些年龄以及沉积特征表明:(1)传统认为的奥陶纪"贺兰拗拉槽"并不存在,鄂尔多斯西南缘地区以及阿拉善东部地区当时属于北祁连早古生代周缘前陆盆地系统;(2)早古生代主要物源来自北祁连造山带,新元古代物源来自阿拉善地块;(3)鄂尔多斯西缘整个米钵山组的锆石年龄分布及其变化,指示出北祁连造山带(岛弧)逐渐靠近阿拉善地块,其间洋盆逐渐消失的过程;(4)阿拉善地块基底与华北有明显差别,阿拉善地块明显受到新元古代和古生代构造热事件的影响,两者可能是在中奥陶世或之后才拼贴在一起。     

色谱法在稀土元素分离分析研究中的应用进展

稀土作为一种重要的不可再生资源,在各行业的应用正逐渐被人们所重视。色谱技术以其快速、高效、自动化程度高等优势已成为稀土元素分离分析的主要方法。文章总结了纸色谱法、薄层色谱法、气相色谱法、超临界色谱法、高效液相色谱法、毛细管电泳法等色谱法在稀土元素分离分析中的应用及研究概况。其中,纸色谱法因展开时间过长,分离效果不理想已很少应用;薄层色谱法因其操作方便、设备简单、显色容易等优点,可用于稀土元素分离分析的初步检测;气相色谱法由于对样品热稳定性的限制,以及因常用的β-二酮类稀土螯合物配体存在分辨率差和吸附等问题也很少应用;超临界色谱法在分离稀土元素络合物中分离效果较好,但是仪器难以普及,限制了技术的发展;高效液相色谱法因分离效率高、重复性好、自动化操作等优点已成为目前稀土元素分离分析的主要方法;毛细管电泳法具有高效、样品及试剂用量少、操作模式灵活等优点,在稀土元素分离分析方面更具有广阔的发展空间。     

青藏高原东北部共和盆地风成沉积地球化学特征及其揭示的气候变化

通过对共和盆地东部风成沉积的地球化学分析,并结合14C和OSL年代,重建了区域末次盛冰期以来气候变化过程。21 ka BP之前气候寒冷偏湿,21～15.82 ka BP为末次盛冰期(LastGlacial Maximum,LGM),气候极为寒冷干燥;15.82～9.5 ka BP气候转暖且偏干,其中14.5～13.6ka BP和11.9～9.5 ka BP气候明显冷干,分别为老仙女木时期(Oldest Dryas,OD)和新仙女木时期(Younger Dryas,YD),而15.82～14.5 ka BP和13.6～11.9 ka BP(BФlling-AllerФd暖期,B/A)相对温暖;9.5～7.2 ka BP暖湿程度明显提高,7.2～5.1 ka BP气候波动频繁,相对冷干和相对暖湿多次更替。5.1～2.7 ka BP暖湿程度基本稳定,之后气候趋于寒冷但湿度明显较大。这些气候变化过程与青藏高原大量的古气候信息记录具有良好的一致性,表明共和盆地气候变化与青藏高原气候变化的高度一致性。     

Risk evaluation of China’s natural disaster systems: an approach based on triangular fuzzy numbers and stochastic simulation

To deal effectively with the evaluation problem of natural disaster risk system affected by many uncertain factors, a multivariate connection number expression is presented. This expression is based on the index samples and evaluation grade criterions of natural disaster risk system and is capable of describing the hierarchy property and fuzziness of membership relationship between index samples and evaluation grade criterions. In this proposed method, the fuzzy evaluation grade criterion problem is resolved by combining triangular fuzzy numbers with multivariate connection number theory, and triangular fuzzy numbers are used to express the discrepancy degree coefficients of connection number and evaluation index weights. Accordingly, a connection number-based evaluation method for the natural disaster system of China (named CN-TFN for short) is established using triangular fuzzy numbers and stochastic simulation. The application results show that the spatial distribution of natural disaster risk grades of China has the trend of aggrandizement from west to east of China. The economically developed and densely populated coastal areas are very likely to have a high level of natural disaster risk grade or above; thus, these areas are the key regions of the natural disaster risk management of China. The results also show that the CN-TFN is able to reflect practical conditions of the evaluation problem of natural disaster system and to provide more reliability information as compared to the existing evaluation methods. This is as a result of its comprehensive usage of various information of subjective and objective uncertainties in the evaluation process of natural disaster risk system and its expression by confidence intervals. Due to the simplicity and generalization, the CN-TFM is applicable to comprehensive risk grade evaluation of various natural disaster systems.     

黄河流域夏季有效降水转化率

利用NCEP/NCAR再分析资料及中国实测雨量资料,分析发现黄河流域夏季整层降水转化率普遍较低,因考虑到整层中应有某一气压层具有最有利的水汽输送、抬升凝结和垂直运动条件,由此将该气压层定义为有效降水转化率层(简称有效层),降水与有效层可降水量之比称为有效降水转化率。通过分析黄河流域夏季各分区垂直速度与水汽等因子,确定上、中、下游夏季有效层分别为地面~500hPa、600~400hPa、850~600hPa。对比分析表明:夏季各区平均水汽收支与降水转化率,各自在整层和有效层上的逐年演变趋势均一致,峰谷相对应,且49年间降水转化率在有效层上的数值均大于整层的。夏季有效降水转化率在青藏高原上空及中游东部最高,高原东北侧最低,旱、涝年与多年平均状况下的分布形式虽然一致,但涝年的数值明显大于旱年。