Respiration and denitrification in permeable continental shelf deposits on the South Atlantic Bight: Rates of carbon and nitrogen cycling from sediment column experiments

Nitrogen (N) cycling and respiration rates were measured in sediment columns packed with southeastern United States continental shelf sands, with high permeability (4.66×10⁻¹¹ m²) and low organic carbon (0.05%) and nitrogen (0.008%). To simulate porewater advection, natural shelf seawater was pumped through columns of different lengths to achieve fluid residence times of approximately 3, 6, and 12 h. Experiments were conducted seasonally at in situ temperature. Fluid flow was uniform in nearly all columns, with minimal dead zones and channeling. Significant respiration (O₂ consumption and ∑CO₂ production) occurred in all columns, with highest respiration rates in summer. Most (78–100%) remineralized N was released as N₂ in the majority of cases, including columns with oxic porewater throughout, with only a small fraction released as NO₃⁻ from some oxic columns. A rate of 0.84–4.83×10¹⁰ mol N yr⁻¹, equivalent to 1.06–6.09×10⁻⁶ mmol N cm⁻² h⁻¹, was calculated for benthic N₂ production in the South Atlantic Bight, which can account for a large fraction of new N inputs to this shelf region. Metal and sulfate reduction occurred in long residence time columns with anoxic outflow in summer and fall, when respiration rates were highest. Because permeable sediments dominate continental shelves, N₂ production in high permeability coastal sediments may play an important role in the global N cycle.     

NEW CHEMICAL ANALYSES OF SIX ACHONDRITES AND ONE CHONDRITE

Quantitative analytical data on 11 elements in chondrite Pampa del Infierno and achondrites Manegaon, Chassigny, Goalpara, Nakhla, Lakangaon and Shergotty are given. To our knowledge, Manegaon and Lakangaon have not been analysed before. Composition, assignment and origin of each meteorite are briefly discussed.     

Measuring Space–Time Access to Food Retailers: A Case of Temporal Access Disparity in Franklin County,Ohio

Typical measures of food access use spatial-only methods to identify nearby food outlets and the quantity, quality, and variety of food available. This measure of spatial access falls short in explaining the effect that the operating hours of food retailers have on food access. Our study aims to complement the spatial dimension of access measures by bringing time in as a new constraint on food access. To this end, we developed three measures of spatial, temporal, and spatiotemporal access and correlated these measures with socioeconomic status (SES) in a case in Columbus, Ohio. Findings from our analysis of food access disparity suggest that low-SES neighborhoods in Columbus are not at a disadvantage of spatial access, but their limited temporal access is a more pressing concern. Implications drawn from the study would assist community advocates, local governments, and other stakeholders in deriving a better understanding of the local foodscape that are not only mediated by space but also time.     

The immediate effects of Hurricane Iniki on intertidal fauna on the south shore of O'ahu

When Hurricane Iniki struck the Hawaiian Islands in September 1992, it provided a rare opportunity to examine the immediate effects of a hurricane on two intertidal benthic communities off the reefs of O'ahu, Hawai'i. The Niu Beach site contained large, obvious aggregations of the tube building polychaete Diopatra dexiognatha, and the Wailupe Beach site was without obvious tubiculous fauna at the surface. Ten replicate sediment cores were taken before and after the hurricane with a 7.6 cm PVC corer and organisms were identified to family and enumerated. There were no substantial depletions or loss of taxa after the hurricane. Oligochaetes were the most dominant taxa pre-and post-hurricane. The abundance of all dominant polychaete families increased post-hurricane. The three most abundant polychaetes were capitellids and D. dexiognatha (Onuphidae) at Niu Beach and Pygospio muscularis (Spionidae) at Wailupe Beach. We suggest that D. dexiognatha and P. muscularis help stabilize the sediments since they both form dense tube mats while capitellids and oligochaetes are considered highly adaptive surface burrowers that can take advantage of newly disturbed sediments. Overall, there was no substantial effect observed on the intertidal fauna exposed to this severe disturbance. It is suggested here that invertebrate communities in this area are adapted to survive and thrive in high-energy environments and possibly benefit from dense aggregations of tube building polychaetes.     

The organic geochemistry of ancient sediments—Part II

Several shales and oils ranging in age from 3 million to 2·7 billion years have been investigated for their hydrocarbon content using gas chromatography and mass spectrometry as primary analytical tools. From the Soudan Shale from Minnesota (2·7 × 10⁹yr) the C₁₈, C₁₉, C₂₀ and C₂₁ isoprenoid-alkanes were obtained. The Antrim shale from Michigan (about 265 × 10⁶ yr) yielded the C₁₆, C₁₈, C₁₉, C₂₀ and C₂₁ isoprenoids, as well as a C₁₆ iso-alkane and the C₁₈ and C₁₉ cyclohexyl n-alkanes. The San Joaquin Oil (30 × 10⁶ yr) and the Abbott Rock Oil (3 × 10⁶ yr) contained the C₁₆, C₁₈, C₁₉, C₂₀ and the C₁₈, C₁₉, C₂₀ and C₂₁ isoprenoids respectively. In addition, a series of iso-alkanes (C₁₆−C₁₈), anteiso-alkanes (C₁₆−C₁₈) and n-alkylcyclohexanes (C₁₆−C₁₉) as well as a C₂₁ isoprenoid were obtained from the Nonesuch Seep Oil (1 × 10⁹ yr). This analysis provides a comprehensive picture of the types of biogenic hydrocarbons found in oils and shales of widely differing ages, and in particular, the finding of isoprenoid alkanes in the Soudan Shale furnishes evidence for life processes at that period of geological time.     

The significance of groundmass ilmenite and megacryst ilmenite in kimberlites

Criteria are suggested for distinguishing xenocrystic ilmenites from those indigenous to the host kimberlite. For instance, in contrast to groundmass grains, ilmenite xenocrysts usually are larger, have reaction rims of leucoxene and perovskite, exhibit strong magnesium enrichment outward, and sometimes have exsolution lamellae and deformation features. Most of the abundant ilmenite macrocrysts found in kimberlite appear to have been phenocrysts in a crystal mush unrelated to kimberlite. On the other hand, kimberlitic groundmass ilmenite is rare, but consistently more magnesian than the cores of macrocrysts. Strong Mg-enrichment patterns evident in the ilmenite macrocrysts probably developed during their attempt to equilibrate with the more magnesian, fractionating kimberlitic liquid. The hypothesis of extensive reaction of ilmenite with kimberlite melt/ fluid has implications with regard to the following: (1) the degree of differentiation of kimberlite melts; (2) the genesis of mantle megacrysts; (3) the reactivity of kimberlite; and (4) the usefulness of groundmass ilmenite as a petrogenetic indicator.     

Understanding satellite-derived bathymetry using Sentinel 2 imagery and spatial prediction models

ABSTRACT

Optical satellite data is an efficient and complementary method to hydrographic surveys for deriving bathymetry in shallow coastal waters. Empirical approaches (in particular, the models of Stumpf and Lyzenga) provide a practical methodology to derive bathymetric information from remote sensing. Recent studies, however, have focused on enhancing the performance of such empirical approaches by extending them via spatial information. In this study, the relationship between multibeam depth and Sentinel-2 image bands was analyzed in an optically complex environment using the spatial predictor of kriging with an external drift (KED), where its external drift component was estimated: a) by a ratio of log-transformed bands based on Stumpf’s model (KED_S) and b) by a log-linear transform based on Lyzenga’s model (KED_L). Through the calibration of KED models, the study objectives were: 1) to better understand the empirical relationship between Sentinel-2 multispectral satellite reflectance and depth, 2) to test the robustness of KED to derive bathymetry in a multitemporal series of Sentinel-2 images and multibeam data, and 3) to compare the performance of KED against the existing non-spatial models described by Stumpf et al. and Lyzenga. Results showed that KED could improve prediction accuracy with a decrease in RMSE of 89% and 88%, and an increase in R² of 27% and 14%, over the Stumpf and Lyzenga models, respectively. The decrease in RMSE provides a worthwhile improvement in accuracy, where results showed effective prediction of depth up to 6 m. However, the presence of higher concentrations of suspended materials, especially river plumes, can reduce this threshold to 4 m. As would be expected, prediction accuracy could be improved through the removal of outliers, which were mainly located in the channel of the river, areas influenced by the river plume, abrupt topography, but also very shallow areas close to the shoreline. These areas have been identified as conflictive zones where satellite-derived bathymetry can be compromised.