K-Ar Dating of Fault Gouges from the Red River Fault Zone of Vietnam

Constraining the timing of fault zone formation is fundamentally important in terms of geotectonics to understand structural evolution and brittle fault processes.This paper presents the first authigenic illite K-Ar age data from fault gouge samples collected from the Red River Shear Zone at Lao Cai province,Vietnam.The fault gouge samples were separated into three grain-size fractions(0.1 μm,0.1-0.4 μm and 0.4-1.0 μm).The results show that the K-Ar age values decrease from coarser to finer grain fractions(24.1 to 19.2 Ma),suggesting enrichment in finer fraction of morerecently grown authigenic illites.The timing of the fault movement are the lower intercept ages at 0%detrital illite(19.2 ± 0.92 Ma and 19.4 ± 0.49 Ma).In combination with previous geochronological data,this result indicates that the metamorphism of the Day Nui Con Voi(DNCV) metamorphic complex took place before ca.26.8 Ma.At about 26.8 Ma-25 Ma,the fault strongly acted to cause the rapid exhumation of the rocks along the Red River-Ailoa Shan Fault Zone(RR-ASFZ).During brittle deformation,the DNCV slowly uplifted,implying weak movement of the fault.This brittle deformation might have lasted for ca.5 Ma.     

Identification of anthropogenic radionuclides in the Song Hong (Red) and Song Da (Black) river basins of Vietnam

The concentration and distribution of U were measured in zircon samples separated from the streambed sediments collected at different sites along the rivers of northern Vietnam using semiconductor alpha spectrometry and alpha- and fission-track autoradiography. Based on the absolute U content and distribution, we distinguished two groups of zircon grains of different origin. Group 1 zircons have relatively low and uniform U contents ranging from 280 to 440 μg/g. Group 2 zircons are characterized by heterogeneous U distribution and U contents ranging from 490 to 2040μg/g. The determination of absolute alpha activity values and alpha spectrometric characteristics for a number of group 2 zircon grains indicated the presence of relatively short-lived alpha-emitters. These radionuclides are probably ²¹⁰Po, ²³²U, ²³⁶Pu, ²⁴¹Am, and ²⁴³Am, and all of them can originate exclusively from anthropogenic sources. A comparison of the observed alpha activity values for group 2 zircons with those of group 1 zircons and zircons separated from the suspended colloids in river water samples provided conclusive evidence for traces of anthropogenic radioactive contamination in the Lao Cai, Yen Bai, Tuyen Quang, Thac Ba, Viet Tri, and Hanoi streams flowing in the Song Hong (Red) and Song Da (Black) river basins of northern Vietnam and sourced in the southern regions of the neighboring state.     

The sedimentary, magmatic and tectonic evolution of the southwestern South China Sea revealed by seismic stratigraphic analysis

The southwestern South China Sea represents an area of continental crust frozen immediately before the onset of seafloor spreading. Here we compile a grid of multichannel seismic reflection data to characterize the continent-ocean transition just prior to full break-up. We identify a major continental block separated from the shelf margin by a basin of hyperextended crust. Oligocene-Early Miocene rifting was followed by mild compression and inversion prior to 16 Ma, probably linked to collision between the Dangerous Grounds, a continental block to the east of the study area, and Borneo. The timing of inversion supports models of seafloor spreading continuing until around 16 Ma, rather than becoming inactive at 20 Ma. The off-shelf banks experienced uplift prior to 16 Ma in an area, which had previously been a depocenter. The off-shelf banks continued to extend after this time when the rest of the region is in a phase of thermal subsidence. Post-rift magmatism is seen in the form of scattered seamounts (~5–10 km across) within or on the edge of the deeper basins, and are dated as Late Miocene and Pliocene. They are not clearly linked to any phase of tectonic activity. Further inversion of the off-shelf banks occurred in the Pliocene resulting in a major unconformity despite the lack of brittle faulting of that age. We speculate that this is part of a wider pattern of scattered magmatism throughout the South China Sea at this time. Prograding clinoforms are seen to build out from the shelf edge in the south of the study area during the Pliocene, after 5.3 Ma, and then more towards the north and east during the Pleistocene. At the same time a trough south of the off-shelf banks is filled with >1.35 km of mostly Pleistocene sediment. While we expect the bulk of the sediment to come from the Mekong River, we also suggest additional sediment supply from Borneo and the Malay Peninsula via the Molengraaff River and its predecessors.     

Stable isotopes (2H, 18O and 13C) in groundwaters from the northwestern portion of the Guarani Aquifer System (Brazil)

The groundwater flow pattern of the western part of the Guarani Aquifer System (GAS), Brazil, is characterized by three regional recharge areas in the north, and a potentiometric divide in the south, which trends north–south approximately. Groundwater flow is radial from these regional recharge areas toward the center of Paraná Sedimentary Basin and toward the western outcrop areas at the border of the Pantanal Matogrossense, because of the potentiometric divide. The isotopic composition of GAS groundwater leads to understanding the paleoclimatic conditions in the regional recharge areas. The δ¹⁸O and δ²H isotopic ratios of GAS groundwaters vary, respectively, from –9.1 to –4.8‰ V-SMOW and –58.4 to –21.7‰ V-SMOW. In the recharge zones, enriched δ¹⁸O values are observed, while in the confined zone lighter δ¹⁸O values are observed. These suggest that climatic conditions were 10°C cooler than the present during the recharge of these waters. The δ¹³C ratios in groundwater of GAS, in the study area, vary from –19.5 to –6.5‰ VPDB, increasing along the regional flow lines toward the confined zone. This variation is related to dissolution of carbonate cement in the sandstones.