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91.
探讨了在地图投影的最小二乘二元多项式拟合中参考点的分布对拟合误差的影响,提出了一种基于矩阵的秩亏的方法来判断参考点是否在指定次数的二元多项式空间的代数曲线上,并导出在极小范数最小二乘意义下的拟合多项式的误差估计式,公式表明拟合误差和参考点的最小二乘误差无关。 相似文献
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Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between 10B and 11B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ 11Bcarb), and then calculation of the past pCO2 have become important issues for the international isotope geochemistry community, and are called the δ 11B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ 11B) in nature (especially in bio-carbonates) and controlling factors of the δ 11B-pH proxy, such as the dissociation constant of B(OH)3 in seawater (pKa), the δ 11B of seawater (δ 11BSW), the boron isotopic fractionation factor between B(OH) 4 ? and B(OH)3 (α 4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pKa, δ 11Bsw, and α 4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) 4 ? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ 11Bcarb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ 11B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ 11B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present. 相似文献
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为获得古罗糖醛酸(Guluronate)含量高的细菌胞外褐藻多糖,利用PCR从海洋细菌Pseudomonassp.QDA中克隆了其甘露糖醛酸C-5差向异构酶基因(algG),连接入质粒pMF 54Km,构建了重组表达载体pMF54 Km-algG。利用三亲接合法将pMF54 Km-algG转入菌株QDA中,获得algG过量表达重组菌株QDA-G1。H-NMR测定结果表明,QDA-G所产的褐藻多糖中β-D-甘露糖醛酸(M)与它的C-5差向异构体α-L-古罗糖醛酸(G)的比值为0.38,G的质量分数达到74.2%,比野生菌株QDA提高了26.4%。且重组菌株遗传稳定性良好,连续传代20代后,M/G的比值无明显变化。 相似文献
96.
Yan‐Dong Ma Jing‐Bo Zhao Xiao‐Qing Luo Tian‐Jie Shao Zhi‐Bao Dong Qi Zhou 《水文研究》2017,31(18):3255-3268
The hydrology and water balance of megadunes and lakes have been investigated in the Badain Jaran Desert of China. Field observations and analyses of sand layer water content, field capacity, secondary salt content, and grain size reveal 3 types of important natural phenomenon: (a) vegetation bands on the leeward slope of the megadunes reflect the hydrological regime within the sandy vadose zone; (b) seepage, wet sand deposits, and secondary salt deposits indicate the pattern of water movement within the sandy vadose zone; (c) zones of groundwater seeps and descending springs around the lakes reflect the influence of the local topography on the hydrological regime of the megadunes. The seepage exposed on the sloping surface of the megadunes and gravity water contained within the sand layer confirm the occurrence of preferential flow within the vadose zone of the megadunes. Alternating layers of coarse and fine sand create the conditions for the formation of preferential flows. The preferential flows promote movement of water within the sand layer water that leads to deep penetration of water within the megadunes and ultimately to the recharging of groundwater and lake water. Our results indicate that a positive water balance promotes recharge of the megadunes, which depends on the high permeability of the megadune material, the shallow depth of the surface sand layer affected by evaporation, the occurrence of rainfall events exceeding 15 mm, and the sparse vegetation cover. Water balance estimates indicate that the annual water storage of the megadunes is about 7.5 mm, accounting for only 8% of annual precipitation; however, the shallow groundwater per unit area under the megadunes receives only 3.6% of annual precipitation, but it is still able to maintain a dynamic balance of the lake water. From a water budget perspective, the annual water storage in the megadunes is sufficient to serve as a recharge source for lake water, thereby enabling the long‐term persistence of the lakes. Overall, our findings demonstrate that precipitation is a significant component of the hydrological cycle in arid deserts. 相似文献
97.
针对参数回归技术制作概率预报存在拟合好、但预报结果不稳定的现象, 提出了用K近邻非参数回归技术制作概率预报的新途径。K 近邻非参数回归技术包括历史样本数据库、近邻子集生成和优化以及预报量估计4 个主要部分。利用该技术进行了单要素概率预报(主要包括云量和降水)和多维联合概率预报(降水、总云量、风速和气温)试验, 并对试验结果进行了检验。实例研究结果表明:该文所给出的计算方案预报稳定性好, 准确率较高,具有良好的业务应用价值。 相似文献
98.
利用河南省区域地震台网的近震波形资料,采用近震时间域方法,反演2010年10月24日16点58分太康 MS 4.6地震的地震矩张量,结果显示,该地震为走滑型地震。结合震后灾害考察,认为太康地震发生在周口-太康断裂上。 相似文献
99.
通过X射线衍射、红外光谱、热分析、理化性能测试和镜下观察等手段,确定了贵州大方猫场含黄铁矿粘土岩中主要粘土矿物为伊/蒙不规则间层矿物,其间层作用类型为R=1,即累托石型有序间层。 相似文献
100.