Conductivity model for pyrite-bearing laminated and dispersed shaly sands based on a differential equation and the generalized Archie equation

The conductance of pyrite-bearing laminated and dispersed shaly sands is not well understood and resistivity models for pyrite-bearing shaly sands are nonexistent. Thus, we first synthesize clean pyrite-matrix samples, and quartz-matrix samples with variable laminated shale, dispersed shale, and pyrite content and then perform petrophysics experiments to assess the effect of pyrite content on the conductivity of pyrite-bearing shaly sands. Second, based on the differences in conductivity and conduction pathways and geometries because of the variable composition of the pyrite-bearing laminated and dispersed shaly sands, we divide the shaly sands into their components, i.e., laminated shale, quartz grains, pyrite grains, hydrocarbon, dispersed shale, microscopic capillary water, and mobile water. A generalized resistivity model is proposed to describe the conductivity of pyrite-bearing laminated and dispersed shaly sands, based on the combined conductivity differential equation and generalized Archie equation. In the generalized resistivity model, the conductivity differential equation is used to describe the conductivity of dispersed inclusions in a host, whereas the generalized Archie equation is used to describe the conductivity of two conducting phases. Moreover, parallel conductance theory is used to describe the conductivity of dispersed shaly sands and laminated shale. Theoretical analysis suggests that the proposed model satisfies the physical constraints and the model and experimental results agree. The resistivity and resistivity index of shaly sands decrease with increasing conductivity and pyrite. Finally, the accuracy of the resistivity model is assessed based on experimental data from 46 synthetic core samples with different oil saturation. The model can describe the conductivity of clean pyrite-matrix samples, and quartz-matrix samples with different volumes of laminated shale, dispersed shale, and pyrite. An accurate saturation model of pyrite-bearing laminated and dispersed shaly sands is thus obtained and the log data interpretation in complex shaly sands can improve with the proposed model.     

Regeneration and utilization of nutrients during collapse of a <Emphasis Type="Italic">Mesodinium rubrum</Emphasis> red tide and its influence on phytoplankton species composition

High-biomass red tides occur frequently in some semi-enclosed bays of Hong Kong where ambient nutrients are not high enough to support such a high phytoplankton biomass. These high-biomass red tides release massive inorganic nutrients into local waters during their collapse. We hypothesized that the massive inorganic nutrients released from the collapse of red tides would fuel growth of other phytoplankton species. This could influence phytoplankton species composition. We tested the hypothesis using a red tide event caused by Mesodinium rubrum (M. rubrum) in a semi-enclosed bay, Port Shelter. The red tide patch had a cell density as high as 5.0×10⁵ cells L^?1, and high chlorophyll a (63.71 μg L^?1). Ambient inorganic nutrients (nitrate: \(\rm{NO}_3^-\), ammonium: \(\rm{NH}_4^+\), phosphate: \(\rm{PO}_4^{3-}\), silicate: \(\rm{SiO}_4^{3-}\)) were low both in the red tide patch and the non-red-tide patch (clear waters outside the red tide patch). Nutrient addition experiments were conducted by adding all the inorganic nutrients to water samples from the two patches followed by incubation for 9 days. The results showed that the addition of inorganic nutrients did not sustain high M. rubrum cell density, which collapsed after day 1, and did not drive M. rubrum in the non-red-tide patch sample to the same high-cell density in the red tide patch sample. This confirmed that nutrients were not the driving factor for the formation of this red tide event, or for its collapse. The death of M. rubrum after day 1 released high concentrations of \(\rm{NO}_3^-\), \(\rm{PO}_4^{3-}\), \(\rm{SiO}_4^{3-}\), \(\rm{NH}_4^+\), and urea. Bacterial abundance and heterotrophic activity increased, reaching the highest on day 3 or 4, and decreased as cell density of M. rubrum declined. The released nutrients stimulated growth of diatoms, such as Chaetoceros affinis var. circinalis, Thalassiothrix frauenfeldii, and Nitzschia sp., particularly with additions of \(\rm{SiO}_4^{3-}\) treatments, and other species. These results demonstrated that initiation of M. rubrum red tides in the bay was not directly driven by nutrients. However, the massive inorganic nutrients released from the collapse of the red tide could induce a second bloom in low-ambient nutrient water, influencing phytoplankton species composition.     

Carbon pools and fluxes in the China Seas and adjacent oceans

The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km~2 from tropical to northern temperate zones, and including a variety of continental margins/basins and depths, the China Seas provide typical cases for carbon budget studies. The South China Sea being a deep basin and part of the Western Pacific Warm Pool is characterized by oceanic features; the East China Sea with a wide continental shelf, enormous terrestrial discharges and open margins to the West Pacific, is featured by strong cross-shelf materials transport; the Yellow Sea is featured by the confluence of cold and warm waters; and the Bohai Sea is a shallow semiclosed gulf with strong impacts of human activities. Three large rivers, the Yangtze River, Yellow River, and Pearl River, flow into the East China Sea, the Bohai Sea, and the South China Sea, respectively. The Kuroshio Current at the outer margin of the Chinese continental shelf is one of the two major western boundary currents of the world oceans and its strength and position directly affect the regional climate of China. These characteristics make the China Seas a typical case of marginal seas to study carbon storage and fluxes. This paper systematically analyzes the literature data on the carbon pools and fluxes of the Bohai Sea,Yellow Sea, East China Sea, and South China Sea, including different interfaces(land-sea, sea-air, sediment-water, and marginal sea-open ocean) and different ecosystems(mangroves, wetland, seagrass beds, macroalgae mariculture, coral reefs, euphotic zones, and water column). Among the four seas, the Bohai Sea and South China Sea are acting as CO_2 sources, releasing about0.22 and 13.86–33.60 Tg C yr~(-1) into the atmosphere, respectively, whereas the Yellow Sea and East China Sea are acting as carbon sinks, absorbing about 1.15 and 6.92–23.30 Tg C yr~(-1) of atmospheric CO_2, respectively. Overall, if only the CO_2 exchange at the sea-air interface is considered, the Chinese marginal seas appear to be a source of atmospheric CO_2, with a net release of 6.01–9.33 Tg C yr~(-1), mainly from the inputs of rivers and adjacent oceans. The riverine dissolved inorganic carbon (DIC) input into the Bohai Sea and Yellow Sea, East China Sea, and South China Sea are 5.04, 14.60, and 40.14 Tg C yr~(-1),respectively. The DIC input from adjacent oceans is as high as 144.81 Tg C yr~(-1), significantly exceeding the carbon released from the seas to the atmosphere. In terms of output, the depositional fluxes of organic carbon in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea are 2.00, 3.60, 7.40, and 5.92 Tg C yr~(-1), respectively. The fluxes of organic carbon from the East China Sea and South China Sea to the adjacent oceans are 15.25–36.70 and 43.93 Tg C yr~(-1), respectively. The annual carbon storage of mangroves, wetlands, and seagrass in Chinese coastal waters is 0.36–1.75 Tg C yr~(-1), with a dissolved organic carbon(DOC) output from seagrass beds of up to 0.59 Tg C yr~(-1). Removable organic carbon flux by Chinese macroalgae mariculture account for 0.68 Tg C yr~(-1) and the associated POC depositional and DOC releasing fluxes are 0.14 and 0.82 Tg C yr~(-1), respectively. Thus, in total, the annual output of organic carbon, which is mainly DOC, in the China Seas is 81.72–104.56 Tg C yr~(-1). The DOC efflux from the East China Sea to the adjacent oceans is 15.00–35.00 Tg C yr~(-1). The DOC efflux from the South China Sea is 31.39 Tg C yr~(-1). Although the marginal China Seas seem to be a source of atmospheric CO_2 based on the CO_2 flux at the sea-air interface, the combined effects of the riverine input in the area, oceanic input, depositional export,and microbial carbon pump(DOC conversion and output) indicate that the China Seas represent an important carbon storage area.     

全张量磁梯度数据的斜导数特征值边界识别方法研究

本文提出了一种全张量磁梯度数据的斜导数边界识别方法,该方法利用全张量磁梯度数据定义了北向斜导数、东向斜导数和垂向斜导数.模型试验表明,北向和东向斜导数无法有效识别磁性异常体边界,异常形态复杂虚假异常较多,而垂向斜导数在高纬度斜磁化或者垂直磁化条件下可以清晰而准确得识别地质体的边界,具有一定的深度识别能力.与现有磁张量梯度的边界识别方法相比,识别效果好,可以有效均衡不同深度地质体的响应.将上述方法应用于大兴安岭地区实测航磁三分量数据转换得到的全张量数据,获得了研究区浅部磁性体的分布,并与三分量数据进行联合解释,取得良好的地质效果.     

罗斯海难言岛地区近地面层风场特征分析及数值模拟

本文介绍了中国第3座南极常年考察站新站址候选地——罗斯海难言岛的基本信息。通过对设在其上的自动气象站的观测数据分析表明,近地面风场主要由下降风控制,西-西北风是6级以上大风的主要风向,最大风力可达12级以上,1月、11月、12月是平均风力较小的三个月份。通过分析基于CFSR海冰资料的Polar-WRF模式模拟结果发现:Polar-WRF模式能模拟出和实测资料十分一致的下降风风场,分辨率越高越能更好的模拟出下降风的特点。难言岛附近强劲的西-西北向下降风是地形强迫的结果;来自Reeves冰川的气流是下降风的主要来源。大风的水平分布范围约为50 km。海拔1 400—300 m为下降风的加速关键区,风速最大的地方在海拔300 m高度的陡坡附近,下降风在抵达难言岛时,由于地面摩擦作用,风力已经有一定的衰减。模拟风场可以对观测资料做出有益的补充。     

Water quality assessment of the Huaihe River segment of Bengbu (China) using multivariate statistical techniques

In the study, multivariate statistical methods including principal component analysis (PCA)/factor analysis (FA) and cluster analysis (CA) were applied to analyze surface water quality data sets obtained from the Huaihe River segment of Bengbu (HRSB) and generated during 2 years (2011–2012) monitoring of 19 parameters at 7 sampling sites. The results of PCA for 7 sampling sites revealed that the first four components of PCA showed 94.89% of the total variance in the data sets of HRSB. The Principal components (Factors) obtained from FA indicated that the parameters for water quality variations were mainly related to heavy metals (Pb, Mn, Zn and Fe) and organic related parameters (COD, PI and DO). The results revealed that the major causes of water quality deterioration were related to inflow of industrial, domestic and agricultural effluents into the Huaihe River. Three significant sampling locations—(sites 2, 3 and 4), (sites 1 and 5) and (sites 6 and 7)—were detected on the basis of similarity of their water quality. Thus, these methods were believed to be valuable to help water resources managers understand complex nature of water quality issues and determine the priorities to improve water quality.     

Discussion on research advances and hot issues in diagenesis of clastic-rock reservoirs

The research on diagenesis of clastic-rock reservoir is developing rapidly in recent ten years. Thus, it is of great significance in academic and scientific exploration to summarize the domestic and international research progress and the key issues of frontier research on diagenesis. The research progress, main achievement and recognition in diagenesis of clastic-rock reservoirs in recent years is discussed, and the hot issues or developing trend of diagenesis in the future is probed in this paper, on the basis of summarizing the previous research results and understanding, combined with the typical research examples at home and abroad. It is believed that great progress was obtained in provenance and parent rock constraints on sandstone types and their diagenetic evolution pathways, impact of fluid-rock interaction and its product on diagenesis, influence of thermodynamics and overpressure background on diagenesis and pore development, the timing sequence between hydrocarbon accumulation and filling process and the sandstone reservoir becoming low permeability-densification. At present, diagenetic research is developing in direction of the spatial and temporal dynamics and quantitative evolution mechanistic and diagenetic system controlled by the basin fluid dynamics, thermal dynamic processes, combining the micro-scale diagenesis research with the basin macroscopic background such as sedimentation from the source to the basin, burial history, hydrocarbon maturity and charge into reservoirs, tectonic evolution and fluid activity, and fluid and rock interaction.The aim of this paper is to induce the academic peers and experts in diagenesis and the related research fields to come forward with their valuable contributions, to cooperate and work together and joint efforts on the research exquisite, profundity and breadth of diagenesis, and application of the most advanced analytical measurement techniques and methods, as well as integration and infiltration of multidisciplinary, in order to promote the course of the clastic-rock reservoir diagenetic research in China.     

Modelling rainfall interception losses of three plantations in the Loess Plateau

The forest canopy affects the water entering the forest ecosystem by intercepting rainfall. This is especially pertinent in forests that depend on rainfall for their ecological water needs, quantifying and simulating interception losses provide critical insights into their ecological hydrological processes. In the semi-arid areas of the Loess Plateau, afforestation has become an effective ecological restoration measure. However, the rainfall interception process of these plantations is still unclear. To quantify and model the canopy interception of these plantations, we conducted a two-year rainfall redistribution measurement experiment in three typical plantations, including a deciduous broadleaf plantation (Robinia pseudoacacia) and two evergreen coniferous plantations (Platycladus orientalis and Pinus tabuliformis). Based on this, the revised Gash model was used to simulate their interception losses, and the model applicability across varying rainfall types was further compared and verified. The experiment clarified the rainfall redistribution in the three plantations, and the proportions of throughfall to gross rainfall in Robinia pseudoacacia, Platycladus orientalis, and Pinus tabuliformis were 84.8%, 70.4%, and 75.6%; corresponding, the stemflow proportions were 2.0%, 2.2%, and 1.8%; the interception losses were 13.2%, 27.4%, and 22.6%, respectively. The dominant rainfall pattern during the experiment was characterized by low-amounts, moderate-intensity, and short-duration, during which the highest interception proportions across the three plantations were observed. We used the Penman-Monteith equation and the regression method, respectively, to estimate the canopy average evaporation rate of the revised Gash model, finding that the latter provides a closer match to the measured cumulative interception (NSE >0.7). When simulating interception under the three rainfall patterns, the model with the regression method better simulated the cumulative interception and event-scale interception for Platycladus orientalis and Pinus tabuliformis plantations under the dominant rainfall pattern. The results contribute valuable information to assess the impact of forest rainfall interception on regional hydrologic processes.     

Color correction of texture images for true photorealistic visualization

Photorealistic visualization combines 3-D geometric models with their texture images to render the virtual world. This paper points out that the texture images should be radiometrically corrected to achieve a true realistic appearance. Such a correction should include not only the color adjustment among images of the same object, but also the shade variation caused by the illumination change. The objective of this study is to correct the input texture images such that their shade varies when being rendered under different illumination directions. To achieve this goal we first apply the specular-to-diffuse mechanism based on the dichromatic reflection model to remove the specular component from the texture image. The resultant diffusion-only image then undergoes a shade correction to produce a normalized shade-free texture image. In the final step, shades under any illumination are produced to achieve a true photorealistic effect. Presented in the paper are the principles and methods for such corrections, along with a performance evaluation based on the graphic and numerical results for roof texture images.     

南海成因及其演化模式探讨

尽管南海已进行深入的调查与研究,提出多种成因模型,包括挤出模型、弧后扩张模型、古南海俯冲拖曳模型等,但因其所处构造位置特殊,周边构造环境经历了复杂的改造,所有成因模式均未能得到广泛的认可。本文从三大板块相互作用入手,结合南海实测数据,提出南海形成的弧后扩张—左旋剪切模型。认为南海是古南海往北俯冲的弧后盆地,菲律宾海板块往北漂移形成的大规模左旋走滑是南海扩张的触发因素。印度—欧亚碰撞产生中南半岛挤出主要影响西南海盆扩张方向,使得扩张轴从近东西向转为北东向。南海及邻区晚中生代以来的演化可以分为以下阶段：1）早白垩世开始澳大利亚板块往北漂移,新特提斯洋往北俯冲消亡,导致弧后扩张,形成古南海;2）晚白垩世末—始新世,古南海往北俯冲,导致弧后拉张形成陆缘裂谷;3）早渐新世,受菲律宾海板块西缘大型左旋走滑影响,在原有裂谷的基础上从东往西海底扩张,形成南海;4）渐新世末,受俯冲后撤的影响,扩张中心往南跃迁,同时受西缘断裂左旋活动的影响,扩张轴从近东西西逐步转为北东向;5）早中新世晚期,南沙地块—北巴拉望地块与卡加延脊碰撞,南海扩张停止。