Heat flow in the southern Chile forearc controlled by large-scale tectonic processes

Between 33°S and 47°S, the southern Chile forearc is affected by the subduction of the aseismic Juan Fernandez Ridge, several major oceanic fracture zones on the subducting Nazca Plate, the active Chile Ridge spreading centre, and the underthrusting Antarctic Plate. The heat flow through the forearc was estimated using the depth of the bottom simulating reflector obtained from a comprehensive database of reflection seismic profiles. On the upper and middle continental slope along the whole forearc, heat flow is about 30–60 mW m^–2, a range of values common for the continental basement and overlying slope sediments. The actively deforming accretionary wedge on the lower slope, however, in places shows heat flow reaching about 90 mW m^–2. This indicates that advecting pore fluids from deeper in the subduction zone may transport a substantial part of the heat there. The large size of the anomalies suggests that fluid advection and outflow at the seafloor is overall diffuse, rather than being restricted to individual fault structures or mud volcanoes and mud mounds. One large area with very high heat flow is associated with a major tectonic feature. Thus, above the subducting Chile Ridge at 46°S, values of up to 280 mW m^–2 indicate that the overriding South American Plate is effectively heated by subjacent zero-age oceanic plate material.     

Temporal trends of dissolved weathering products released from a high Arctic coal mine waste rock pile in Svalbard (78°N)

It is well known that oxidation of sulphide-containing coal mine waste has considerable environmental impacts due to generation of acid mine drainage (AMD) containing high dissolved metal concentrations. This study is the first to evaluate seasonal trends in the release of AMD from high arctic coal mine waste rock. Runoff from an abandoned coal mine waste pile in Svalbard (78°N) was studied during the entire 3–4 month period with running water in 2005. Temporal variation in concentrations and fluxes of dissolved elements were quantified based on daily water sampling and used to evaluate weathering processes and estimate element budgets on a daily, seasonal and annual basis. Apart from alkali- and alkaline earth metals; Fe, Al, Mn, Zn and Ni were found to be the most abundant metals in the runoff. Element concentrations were highly correlated and suggest that the processes of sulphide oxidation, ion exchange and silicate weathering occurring within the waste pile were linked throughout the measuring period. Observed pH values varied from 2.8 to 5.2 and SO₄ concentrations from 21 to 1463 mg L⁻¹. Manganese and Al concentrations were observed above phytotoxic levels (up to 4 and 23 mg L⁻¹, respectively) and were considered the most critical elements in terms of environmental impact. Throughout the summer a total dissolved quantity of 58 kg Mn, 238 kg Al and 13,700 kg SO₄ was released from the pile containing approximately 200,000 m³ of pyritic waste material (<1% FeS₂). The highest concentrations of metals, lowest pH values and a very high daily release of H₂SO₄ (up to twice as high as the following month) were observed during the first week of thaw. This is considered a result of an accumulation of weathering products, generated within the waste pile during winter and released as a pollution-flush during early spring. Similar accumulation/flush sequences were observed later in the summer where rain events following relatively long dry periods caused high daily metal fluxes and on some occasions also elevated dissolved metal concentrations. Despite highly variable weather/climate conditions during the rest of the summer the investigated waste rock pile acted like a relative constant pollution-source during this period. Future investigations regarding the environmental impact of mine waste in the region should include measurements of bioavailable metals in order to provide further details on the seasonal trends in environmental impact.     

Timing of Uralian orogenic gold mineralization at Kochkar in the evolution of the East Uralian granite-gneiss terrane

Gold mineralization at Kochkar (Urals, Russia) is hosted mainly by quartz lodes, which developed at lithological contacts between mafic dikes and granitoids of the Plast massif during late Carboniferous to early Permian, regional E–W compression in the East Uralian Zone (EUZ). The alteration mineralogy in mafic dikes comprises biotite, actinolite, albite, K-feldspar, quartz, epidote, tourmaline, sericite, pyrite, arsenopyrite, chalcopyrite, sphalerite, fahlores, galena, bismuthinite, and gold, and in Plast granitoids quartz, sericite, calcite, epidote, and ore minerals. Geochemically, an enrichment of Si, K, Rb, Ba, S, base metals, W, and Au can be observed. The ore fluid had δ¹⁸O values between 8.2‰ and 9.5‰ typical for metamorphic or deep magmatic fluids. The tectonometamorphic evolution of the EUZ is marked by peak metamorphic conditions at 635±40°C and 5–6 kbar through 500±20°C during gold mineralization, and 300–350°C and 2–3 kbar. The last event was dated on a late, barren quartz vein formed during greenschist facies metamorphism at 265±3 Ma by the Rb–Sr method. Fluids related to this overprint had a δ¹⁸O value of 5.2‰ and an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70685 indicating that they are largely equilibrated with metamorphic lithologies of the EUZ. The Plast granitoids and the adjacent Borisov granite, which was dated at 358±23 Ma (U–Pb zircon age), have an adakitic character. This, together with the arc-signature of the mafic dikes, supports the setting of the EUZ within the Valerianovsky continental arc. Eastward subduction of the Uralian Ocean below this arc began during the late Devonian to early Carboniferous. Between 320 and 265 Ma, the oblique closure of the ocean resulted in doming of granitoid massifs in a sinistral transpressional regime, subsequent retrograde gold mineralization during E–W compression and a later greenschist facies overprint. This long-lasting retrograde evolution of the EUZ was caused by the lack of postcollisional collapse. Heat for a “deep-later" type of metamorphism and triggering the auriferous fluid system was supplied by radiogenic heating of an overthickened crust. The greenschist facies overprint at Kochkar and coeval crustal melting in the EUZ was additionally initiated by local external heating of the terrane. This could have been caused by syn- to postcollisional slab rollback or delamination resulting in magmatic underplating of the EUZ, which postdates orogenic gold mineralization at Kochkar. The tectonic interpretation of the EUZ indicates that gold mineralization at Kochkar formed in a mid-crustal environment of a continental magmatic arc at the cessation of active subduction predating post orogenic plutonism.     

Rainfall interception in a lower montane forest in Ecuador: effects of canopy properties

Rainfall interception in forests is influenced by properties of the canopy that tend to vary over small distances. Our objectives were: (i) to determine the variables needed to model the interception loss of the canopy of a lower montane forest in south Ecuador, i.e. the storage capacity of the leaves S and of the trunks and branches S_t, and the fractions of direct throughfall p and stemflow p_t; (ii) to assess the influence of canopy density and epiphyte coverage of trees on the interception of rainfall and subsequent evaporation losses. The study site was located on the eastern slope of the eastern cordillera in the south Ecuadorian Andes at 1900–2000 m above sea level. We monitored incident rainfall, throughfall, and stemflow between April 1998 and April 2001. In 2001, the leaf area index (LAI), inferred from light transmission, and epiphyte coverage was determined. The mean annual incident rainfall at three gauging stations ranged between 2319 and 2561 mm. The mean annual interception loss at five study transects in the forest varied between 591 and 1321 mm, i.e. between 25 and 52% of the incident rainfall. Mean S was estimated at 1·91 mm for relatively dry weeks with a regression model and at 2·46 mm for all weeks with the analytical Gash model; the respective estimates of mean S_t were 0·04 mm and 0·09 mm, of mean p were 0·42 and 0·63, and of mean p_t were 0·003 and 0·012. The LAI ranged from 5·19 to 9·32. Epiphytes, mostly bryophytes, covered up to 80% of the trunk and branch surfaces. The fraction of direct throughfall p and the LAI correlated significantly with interception loss (Pearson's correlation coefficient r = −0·77 and 0·35 respectively, n = 40). Bryophyte and lichen coverage tended to decrease S_t and vascular epiphytes tended to increase it, although there was no significant correlation between epiphyte coverage and interception loss. Our results demonstrate that canopy density influences interception loss but only explains part of the total variation in interception loss. Copyright © 2004 John Wiley & Sons, Ltd.     

Time dependence of organic matter decay and mixing processes in Framvaren, a permanently anoxic fjord in South Norway

Three different layers have been identified in Framvaren, which has a maximum water depth of 184 m. One oxic layer above the redoxcline at 18–20 m. One anoxic layer from 20 to 100 m which is occasionally ventilated by a flow over the sill (which has a depth of 2.5 m), and finally a stagnant layer below 100 m. Using the release rate of silica from the bottom and measurements of the concentration of HTO it is possible to make some calculations on the annual volume of interleaving in the layers 25–50 m, 50–75 m, and 75–100 m together with the advective flows. Reliable values of the sulfide concentration were obtained by precipitating and weighing HgS together with careful protection of all anoxic water samples with argon. The light yellow color of the precipitate in the depth range 25 to 80 m indicates that the occasional ventilation will cause such reactions as 0.50₂ + H₂S S(colloidal) + H₂O. The elemental sulfur, being stabilized with HS^–, is set free upon the precipitation of HgS. The new data for the concentration of sulfide give an acceptable stoichiometry for the decay reaction of organic matter. This is not the case with the data of Yao and Millero. The mean values for the concentrations of ammonium and phosphate agree with the new data of Yao and Millero. The mol/mol C/N ratio of 10.1 found in trapped material by Naess and coworkers (1988) agrees with the stoichiometry of the dissolved constituents, i.e. C/N = 9.92 ± 0.45. A denitrification reaction is suggested to explain the high values of C/N. The vertical diffusion coefficient at 100 m calculated from the depth profile of silica was 0.92 × 10^–6 m² s^–1 which lies in the range of values given by Fröyland. Finally, the ¹⁴C age of the total dissolved inorganic carbon (Ct) in the water below 90 m was about 1600 years indicating a bioproduction in the period 8000 years B.P. to A.D. 1853 when a channel was opened between the fjord outside (Helvikfjord) and Framvaren.     

Double-layer structure in the boundary layer over the baltic sea

Double-layered structures found over the Baltic Sea are investigated using radiosoundings and lidar measurements. Situations with double-layer structures are also simulated with the regional model REMO in a realistic manner. The double layer consists of two adjacent well-mixed layers, with a sharp inversion in between.Results from radiosoundings show that the double-layer structure over the Baltic Sea mainly occurs during the autumn with thermally unstable stratification near the surface. The structure is present in about 50 % of the radiosoundings performed during autumn. The presence of the double-layer structure cannot be related to any specific wind direction, wind speed or sea surface temperature.The lidar measurements give a more continuous picture of the time evolution of the double-layer structure, and show that the top of the lower layer is not a rigid lid for vertical transport. Two possible explanations of the double-layer structure are given, (i) the structure is caused by `advection' of land boundary-layer air over the convective marine boundary layer or, (ii) by development of Sc clouds in weak frontal zones connected to low pressure systems. Also the forming of Cu clouds is found to be important for the development of a double-layer structure.     

El Niño–Southern Oscillation diversity and Southern Africa teleconnections during Austral Summer

Climate Dynamics - A wide range of sea surface temperature (SST) expressions have been observed during the El Niño–Southern Oscillation events of 1950–2010, which have occurred...     

Seismotectonics of south-west Dominican Republic using recent data

The Dominican Republic has a high level of seismic activity, and a new seismic network has been installed to improve the detection of earthquakes. The network has been operated by Instituto Politécnico Loyola since 2012. It uses six new stations of its own, as well as 17 other stations publically available. In this study, we investigate in particular the south-west of the country where no seismic stations have been operating before. We find an area, SE of the Enriquillo Plantain Garden fault (responsible for the 2010 Haiti M7.0 earthquake), with a high seismic activity (M?=?2–4) compared to the surrounding area. This shallow seismicity (except two events around 40 km depth) is not seen in any global catalogs, and it does not seem to be associated with any known faults. However, the region has been under rapid recent uplift since margins between hills and valleys are filled with massive alluvial fans. We made 24 new fault plane solutions using P-polarities and S/P amplitude ratios. The solutions show mainly reverse mechanisms and the P-axis directions are mainly NNE oriented, which is in agreement with a published strain direction from GPS measurements. We conclude that the main cause of the seismicity in our study area is the push of the Beata Ridge against Enriquillo basin and the rest of the Gonave microplate, reflected in the mainly reverse focal mechanisms.     

Bedload transport measurements with impact plate geophones: comparison of sensor calibration in different gravel‐bed streams

Indirect bedload transport measurements have been made with the Swiss plate geophone system in five gravel‐bed mountain streams. These geophone sensors record the motion of bedload particles transported over a steel plate mounted flush with the channel bed. To calibrate the geophone system, direct bedload transport measurements were undertaken simultaneously. At the Erlenbach in Switzerland, a moving‐basket sampler was used. At the Fischbach and Ruetz streams in Austria, a Helley–Smith type bedload sampler provided the calibration measurements. A Bunte‐type bedload trap was used at the Rofenache stream in Austria. At the Nahal Eshtemoa in Israel, Reid‐type slot bedload samplers were used. To characterize the response of the geophone signal to bedload particles impacting on the plate, geophone summary values were calculated from the raw signal and stored at one second intervals. The number of impulses, i.e. the number of peaks above a pre‐defined threshold value of the geophone output signal, correlated well with field measured gravel transport loads and was found to be a robust parameter. The relations of impulses to gravel transport loads were generally near‐linear, but the steepness of the calibration relations differed from site to site. By comparing the calibration measurements from the different field sites and utilizing insights gained during preliminary flume experiments, it has been possible to identify the main factors that are responsible for site specific differences in the calibration coefficient. The analysis of these calibration measurements indicates that the geophone signal also contains some information about the grain size distribution of bedload. Copyright © 2013 John Wiley & Sons, Ltd.