CO2-Laser Extraction-Static Mass Spectrometry Analysis of Ultra-Low Concentrations of Nitrogen in Silicates

A new installation for the analysis of picomole quantities of nitrogen has been designed and constructed. It permits the simultaneous analysis of N and rare gases extracted from silicates by heating. The extraction procedure involves the use of a CO₂ laser as a heater, and the analysis is made by static mass spectrometry using a high sensitivity, high resolution mass spectrometer. Procedural blanks of 2 picomoles N₂ (60 picogram N) allow us to analyse routinely N in mg-sized samples such as mantle-derived and meteoritic minerals, and Lunar soil grains.     

Ck-Reconstruction of Surfaces from Partial Data

In this paper, we study the problem of constructing a smooth approximant of a surface defined by the equation z = f(x ₁, x ₂), the data being a finite set of patches on this surface. This problem occurs, for example, after geophysical processing such as migration of time-maps or depth-maps. The usual algorithms to solve this problem are picking points on the patches to get Lagrange's data or trying to get local junctions on patches. But the first method does not use the continuous aspect of the data and the second one does not perform well to get a global regular approximant (C ¹ or more). As an approximant of f, a discrete smoothing spline belonging to a suitable piecewise polynomial space is proposed. The originality of the method consists in the fidelity criterion used to fit the data, which takes into account their particular aspect (surface's patches): the idea is to define a function that minimizes the volume located between the data patches and the function, and which is globally C ^k. We first demonstrate the new method on a theoretical aspect and numerical results on real data are given.     

Evidence for different scaling of earthquake source parameters for large earthquakes depending on faulting mechanism

Scaling relationships between seismic moment, rupture length, and rupture width have been examined. For this purpose, the data from several previous studies have been merged into a database containing more than 550 events. For large earthquakes, a dependence of scaling on faulting mechanism has been found. Whereas small and large dip-slip earthquakes scale in the same way, the self-similarity of earthquakes breaks down for large strike-slip events. Furthermore, no significant differences in scaling could be found between normal and reverse earthquakes and between earthquakes from different regions. Since the thickness of the seismogenic layer limits fault widths, most strike-slip earthquakes are limited to rupture widths of between 15 and 30 km while the rupture length is not limited. The aspect ratio of dip-slip earthquakes is similar for all earthquake sizes. Hence, the limitation in rupture width seems to control the maximum possible rupture length for these events. The different behaviour of strike-slip and dip-slip earthquakes can be explained by rupture dynamics and geological fault growth. If faults are segmented, with the thickness of the seismogenic layer controlling the length of each segment, strike-slip earthquakes might rupture connected segments more easily than dip-slip events, and thus could produce longer ruptures than dip-slip events of the same width     

Macro and microstructures as indicators of the development of syntectonic granitoids and host rocks in the Camboriú region,Santa Catarina,Brazil

In the northeastern Dom Feliciano Belt, Santa Catarina/Brazil, Paleoproterozoic rocks (mainly the Camboriú Complex) and Neoproterozoic granitoids – with the older Itapema Granite and the younger Corre-mar, Rio Pequeno and Serra dos Macacos granites – experienced a deformation history from magmatic to greenschist facies temperatures, under different rheological conditions. The concordance of flat amphibolite facies structures of the Camboriú Complex and magmatic and subsolidus structures in the Itapema Granite indicate the late-tectonic character of the latter. Based on tectonic features, the Corre-mar Granite is interpreted as older than the Rio Pequeno Granite and as related to transcurrent tectonics of the Southern Brazilian Shear Belt.In all granites, microstructures point to widespread magmatic alignment, followed by weak subsolidus and, locally, amphibolite to greenschist facies deformation. Magmatic foliations are progressively weaker in the younger granites. Synmagmatic shear zones in the Rio Pequeno Granite are possibly concentrated at the intrusive contact. The weak solid-state deformation at late-magmatic conditions argues for magmatism within a low-strain zone, which is compatible with the location of the area relative to the Major Gercino and Itajaí shear zones. The amphibolite to greenschist facies deformation structures are attributed to continuous deformation within the same low-strain zone during decreasing temperatures.     

The Cretaceous–Palaeogene boundary at Gorgonilla Island,Colombia, South America

The discovery of a new Cretaceous/Palaeogene (K/Pg) bathyal marine sequence on Gorgonilla Island, SW Colombia, extends the presence of Chicxulub impact spherule deposits to the Pacific region of northern South America and to the Eastern Pacific Ocean. The Gorgonilla spherule layer is approximately 20 mm thick and consists of extraordinarily well‐preserved glass spherules up to 1.1 mm in diameter. About 70–90% of the spherules are vitrified, and their chemical composition is consistent with Haiti (Beloc) impact glass spherules. Normal size‐grading, delicate spherule textures, welded melt components and an absence of bioturbation or traction transport suggest that the Gorgonilla spherule layer represents an almost undisturbed settling deposit.     

El Niño–Southern Oscillation diversity and Southern Africa teleconnections during Austral Summer

Climate Dynamics - A wide range of sea surface temperature (SST) expressions have been observed during the El Niño–Southern Oscillation events of 1950–2010, which have occurred...