Major and trace element chemistry of Boulder 1 at Station 2, Apollo 17

Twenty-seven samples of matrix and clast materials from Boulder 1 at Station 2, Apollo 17 have been analyzed for major and trace elements as part of the study of this boulder by Consortium Indomitabile. Both unusual and common types of material have been characterized. Gray and black competent breccia (GCBx and BCBx) and anorthositic breccia (AnBx) have compositions which are common at the Apollo 17 site and were common at the site of boulder formation. Light friable breccias (LFBx) have compositions which are not found at the Apollo 17 site other than in the boulder. Pigeonite basalt is a new type of lunar rock and has characteristics that would be expected of a highland volcanic rock. It is associated with LFBx material, and like LFBx material it is exotic to the Apollo 17 site. Coarse norite is an old primitive rock which is no longer (if ever) found as millimeter fragments at the Apollo 17 site. It was, however, present as millimeter fragments associated with GCBx and BCBx materials at the site and time of boulder formation. Therefore the boulder-forming process combined materials from at least two different localities or vertical strata; at least one of these (LFBx) has not been previously sampled and analyzed.     

Laboratory simulations of Mars aqueous geochemistry

We report on laboratory experiments in which we allowed an SNC-derived mineral mix to react with pure water under a simulated Mars atmosphere for 7 months. These experiments were performed at one bar and at three different temperatures in order to simulate the subsurface conditions that most likely exist where liquid water and rock interact on Mars today. The dominant cations dissolved in the solutions we produced, which may be characterized as dilute brines, are Ca²⁺, Mg²⁺, Al³⁺, and Na⁺, while the major anions are dissolved C, F⁻, SO²⁻₄ and Cl⁻. Typical solution pH was in the range of 4.2-6.0. Abundance patterns of elements in our synthetic sulfate-chloride brines are distinctly unlike those of terrestrial ocean water or continental waters, however, they are quite similar to those measured in the martian fines at the Mars Pathfinder and Viking 1 and 2 Landing sites. This suggests that salts present in the martian regolith may have formed over time as a result of the interaction of surface or subsurface liquid water with basalts in the presence of a martian atmosphere similar in composition to that of today. If most of the mobile surface layer was formed during the Noachian when erosion rates were much higher than at present, and if this layer is homogeneous in salt composition, the total amount of salt in the martian fines is approximately the same as in the Earth's oceans. The minimum quantity of circulating water necessary to deposit this amount of salt is approximately equivalent to a global layer 625 m deep.     

Microtopography in tidal marshes: Ecosystem engineering by vegetation?

Hummock-hollow microtopography is characteristic of many freshwater wetland systems. It is comprised of elevated, vegetated hummocks and lower elevation hollows; the latter are usually unvegetated, with reducing conditions in sediments unfavorable for plant growth. This microtopography is also often found in interior regions of brackish marshes, where flood duration is high and salinity fluctuations are prominent. Previous investigation showed this spatial patterning to be relatively stable over time and suggested that these microenvironments are produced by the plants themselves. This study investigates the possible mechanisms and controlling factors of this microtopography and considers the effect of different salinity regimes. We examined microtopographic variability of vegetation and sediment biogeochemistry in two interior tidal marshes, a freshwater-oligohaline marsh and a mesohaline marsh, both of which exhibited fine-scale spatial variability. Within a 2-yr period, the freshwater-oligohaline site demonstrated a labile response of both vegetation and sediment chemistry to interannual variability in salinity and sulfide concentrations, whereas the microscale spatial variability of the mesohaline system persisted. Geochronological assessment of the mesohaline marsh, where microtopographic variability was relatively stable, supported the hypothesis that the formation of the hummock-hollow topography is driven by the plants, rather than developing as a result of underlying physical variability. We propose that brackish marsh vegetation alters the sedimentary environment in such a way as to maximize growth under high-stress, variable conditions. The adaptive advantage of this strategy was illustrated in the accretion rates measured at the higher salinity marsh, which were indistinguishable between the interior hummock sediments and those of an adjacent homogeneous bank marsh.     

The formation of peridotitic suite inclusions in diamonds

Olivine, orthopyroxene and garnet grains belonging to the peridotitic suite of mineral inclusions in natural diamonds typically show compositions poorer in Ca and Al and richer in Mg and Cr than the same minerals in peridotite nodules in kimberlite. Other features suggest the crystallisation of diamonds from magmas of kimberlitic affinities, and it is suggested that the genesis of peridotitic suite diamonds is linked with that of a CO₂-bearing magma. It is shown that the generation of kimberlitic magma from common garnet-peridotite (with 5 wt.% clinopyroxene) in the presence of CO₂ may rapidly remove by melting all Ca-rich solid phases (clinopyroxene and/or carbonate). Further melting may form liquids in equilibrium with olivine, orthopyroxene, and garnet with the distinctive compositions of the diamond inclusions. The amount of melting and CO₂ necessary for the loss of clinopyroxene (and/or carbonate) are estimated at approximately 5.0 wt.% and 0.5 wt.% respectively.     

Suspended sediment load in the Amazon basin: An overview

In this report the state of knowledge of sediment transport by rivers of the Amazon drainage basin is reviewed. On an annual basis the Amazon river transports about 1200×10⁶ tons of sediment from the South American continent to the ocean, which puts it among the world's largest rivers in this respect. The main source of sediment is erosion in the Andes mountains and this material is progressively diluted with sediment poor runoff from lowland draining tributaries. Almost half of the Amazon river transport is attributable to one tributary, the Rio Madeira (488×10⁶ t/y). The Rio Negro, which drains the N crystalline shield, has a comparable water discharge to the Rio Madeira, but only contributes 7×10⁶ t/y. In general the sediments in transport are about 1% organic carbon by weight and this results in an annual particulate carbon to the oceans of 13×10⁶ t/y. Total carbon transport, particulate plus dissolved, is about twice this amount.     

The kinematics and pattern of escarpment retreat across the rifted continental margin of SE Australia

Rifted continental margins generally display an interior, low-relief, highly weathered upland area and a deeply incised, high-relief coastal area. The boundary between the two zones is commonly demarcated by an abrupt, seaward-facing escarpment. We investigate the rate and pattern of escarpment erosion and landscape evolution along the passive margin of south-east Australia, in the region of the New England Tableland. The process of rifting is shown to initiate an escarpment across which rivers flow, resulting in an escarpment that takes the form of dramatic, elongated gorges. Using a mass balance approach, we estimate the volume/unit length of continental material eroded seaward of the escarpment to be between 41 and 68 km², approximately an order of magnitude less than the 339 km² of terrigenous sediments calculated to have been deposited offshore, but consistent with earlier denudation estimates based on apatite fission track data. On the bedrock rivers draining the New England Tableland region, the escarpment is manifested as a series of sharp knickpoints punctuating the river longitudinal profiles. The knickpoints are situated the same distance upstream along the different channels and uniform escarpment retreat rates on the order of 2 km Myr⁻¹ are estimated, despite some differences in bedrock lithologies. Gorge head migration appears to be very important as a bedrock incision mechanism. Field observations indicate a coupling between escarpment retreat and knickpoint propagation, bedrock channel incision, and hillslope development.     

Bioremediation of oil-contaminated sediments on an inter-tidal shoreline using a slow-release fertilizer and chitosan

A 95-day field trial on the bioremediation of oil in beach sediment using Osmocote and chitosan was conducted on an inter-tidal foreshore in Singapore. Osmocote was the key factor in enhancing nutrient levels in sediments, the metabolic activity of the indigenous microbial biomass, and the biodegradation of aliphatics and polycyclic aromatic hydrocarbons (PAHs) with ring number of 2 and 3. In contrast, chitosan did not enhance these parameters in the presence of Osmocote. However, the addition of chitosan to Osmocote amended sediments significantly enhanced biodegradation of recalcitrant 4–6-ring PAHs. This is most likely due to the high oil adsorbancy capacity of chitosan, which enhances the bioavailability of high ring number PAHs to the microbial biomass.     

Environmental impacts of sequestering carbon through forestation

An issue that arises when considering the potential damages of climate change is whether it is possible to slow or stop human caused climate change. One suggestion to reduce the threat of global warming is to change our management of forests to offset carbon emissions. This study examines the impacts of such a policy on environmental amenities in existing Douglas-fir forests. In this analysis Douglas-fir forest management is modelled in a Faustmann framework, where the forest produces three goods: timber, carbon sequestration and amenities. Using this framework, the level of amenities under profit-maximizing and carbon-sequestration management regimes are compared. The change in the level of seven specific amenities is modelled. These amenities include trout, wildlife diversity, visual aesthetics, soil stability, deer populations, elk populations, and water yield. The study finds that the effect of a carbon sequestration policy will depend on the discount rate chosen. In most situations externalities vary less than plus or minus ten percent. However, those externalities that exhibit discontinuities in their relationship to forest age may vary a hundred percent or more depending on the discount rate used.